STUDY OF VAPOR-LIQUID EQUILIBIUM ON N-METHYLPIPERAZINE-PIPERAZINE AND WATER-N-METHYLPIPERAZINE BINARY SYSTEMS
|更新时间:2025-12-16
|
STUDY OF VAPOR-LIQUID EQUILIBIUM ON N-METHYLPIPERAZINE-PIPERAZINE AND WATER-N-METHYLPIPERAZINE BINARY SYSTEMS
CIESC JournalIssue 3, (1998)
作者机构:
浙江大学化工系!杭州310027,浙江大学化工系,杭州,310027
作者简介:
基金信息:
DOI:
CLC:642
Online First:25 June 1998,
Published:25 June 1998
稿件说明:
移动端阅览
Gu Feiyan, Zhang Zhimeng(Department of Chemical Engineering. STUDY OF VAPOR-LIQUID EQUILIBIUM ON N-METHYLPIPERAZINE-PIPERAZINE AND WATER-N-METHYLPIPERAZINE BINARY SYSTEMS[J]. CIESC Journal, 1998, (3).
DOI:
Gu Feiyan, Zhang Zhimeng(Department of Chemical Engineering. STUDY OF VAPOR-LIQUID EQUILIBIUM ON N-METHYLPIPERAZINE-PIPERAZINE AND WATER-N-METHYLPIPERAZINE BINARY SYSTEMS[J]. CIESC Journal, 1998, (3).DOI:
STUDY OF VAPOR-LIQUID EQUILIBIUM ON N-METHYLPIPERAZINE-PIPERAZINE AND WATER-N-METHYLPIPERAZINE BINARY SYSTEMS
The VLE data for binary systems of N-methylpiperazine-piperazine and water-N- methylpiperazine were measured at pressure of 0.1013 MPa by using an improved Rose still.The experimental data of the systems were tested for thermodynamic consistency and correlated satisfactorily with Wilson equation.The critical properties
pc
Tc
V_c
and acentric factors
ω
of both N-methylpiperazine and piperazine have been estimated by group contribution method.The UNIFAC model was successfully used to correlate and predict VLE data of N-methylpiperazine-piperazine system.