KINETICS OF FISCHER - TROPSCH SYNTHESIS OVER Fe - Cu - K CATALYST ( Ⅰ )KINETIC MODEL ON THE BASIS OF MECHANISM

马文平; 李永旺; 赵玉龙; 徐元源; 周敬来

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KINETICS OF FISCHER - TROPSCH SYNTHESIS OVER Fe - Cu - K CATALYST ( Ⅰ )KINETIC MODEL ON THE BASIS OF MECHANISM

更新时间：2025-12-16

- KINETICS OF FISCHER - TROPSCH SYNTHESIS OVER Fe - Cu - K CATALYST ( Ⅰ )KINETIC MODEL ON THE BASIS OF MECHANISM
- CIESC Journal Issue 2, (1999)
- 作者机构：
  
  中国科学院山西煤炭化学研究所煤转化国家重点实验室,中国科学院山西煤炭化学研究所煤转化国家重点实验室,中国科学院山西煤炭化学研究所煤转化国家重点实验室,中国科学院山西煤炭化学研究所煤转化国家重点实验室,中国科学院山西煤炭化学研究所煤转化国家重点实验室太原 030001,太原 030001,太原 030001,太原 030001,太原,030001
- 作者简介：
- 基金信息：
- DOI：
  CLC： Q032
- Online First：25 April 1999，
  
  Published：25 April 1999
- 稿件说明：
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马文平, 李永旺, 赵玉龙, et al. KINETICS OF FISCHER - TROPSCH SYNTHESIS OVER Fe - Cu - K CATALYST ( Ⅰ )KINETIC MODEL ON THE BASIS OF MECHANISM[J]. CIESC Journal, 1999, (2).
DOI：

马文平, 李永旺, 赵玉龙, et al. KINETICS OF FISCHER - TROPSCH SYNTHESIS OVER Fe - Cu - K CATALYST ( Ⅰ )KINETIC MODEL ON THE BASIS OF MECHANISM[J]. CIESC Journal, 1999, (2). DOI：

摘要

由费托合成反应碳化物机理出发

考虑费托合成产物中烯烃再吸附对反应产物分布影响的事实

首次导出了费托合成反应动力学模型。该模型中由于引入烯烃再吸附项链增长几率不再是一个常数

因而更适合于解释铁基催化剂上非理想Anderson-Schulz-Flory产物分布.

Abstract

Kinetics model of Fischer - Tropsch synthesis ( FTS) was derived on the basis of carbide mechanism in which the readsorption of olefins was taken into account. Chain growth factor in the derived models was no long a constant. Hence the new model is suitable for interpreting non - ideal Anderson -Schulz - Flory (ASF) distribution on iron based catalyst.

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