STUDIES ON DIRECT HYDROLYSIS OF METHYL FORMATE INTO FORMIC ACID(Ⅱ)──PROCESS SIMULATION

Zhang Kecheng; Lu Naichen; He Lisheng; Zhang Songbin; Wang Li（Shandong Research Institute of Chemical Industry

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STUDIES ON DIRECT HYDROLYSIS OF METHYL FORMATE INTO FORMIC ACID(Ⅱ)──PROCESS SIMULATION

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- STUDIES ON DIRECT HYDROLYSIS OF METHYL FORMATE INTO FORMIC ACID(Ⅱ)──PROCESS SIMULATION
- CIESC Journal Issue 3, (1998)
- 作者机构：
  
  山东省化工研究院!济南250014,山东省化工研究院!济南250014,山东省化工研究院!济南250014,山东省化工研究院!济南250014,山东省化工研究院,济南,250014
- 作者简介：
- 基金信息：
- DOI：
  CLC： Q031
- Online First：25 June 1998，
  
  Published：25 June 1998
- 稿件说明：
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Zhang Kecheng, Lu Naichen, He Lisheng, et al. STUDIES ON DIRECT HYDROLYSIS OF METHYL FORMATE INTO FORMIC ACID(Ⅱ)──PROCESS SIMULATION[J]. CIESC Journal, 1998, (3).
DOI：

Zhang Kecheng, Lu Naichen, He Lisheng, et al. STUDIES ON DIRECT HYDROLYSIS OF METHYL FORMATE INTO FORMIC ACID(Ⅱ)──PROCESS SIMULATION[J]. CIESC Journal, 1998, (3). DOI：

摘要

对文献发表的几种甲酸甲酯直接水解法制甲酸的工艺流程进行了讨论，提出了一种改进的工艺流程．在本文（Ⅰ）报动力学研究的基础上，用数学模拟方法研究了酯水摩尔比β对装置年产量和能耗的影响．结果表明，在β=1:3～1:2时最为有利．

Abstract

Some variations of the process for direct hydrolysis of methyl formate into formic claimed in the literatures have been discussed and an improved process has been proposed.Based on the studies for reaction kinetics in part(1)of this paper

the effect of methyl formate water molar ratio β on space-time yield and energy consumption of the improved process has been studied by mathematical simulation.The results indicate that the reaction process is more favorable at β=1:3～l:2.

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