STATISTICAL THERMODYNAMIC MODEL OF SURFACE TENSION FOR NONELECTROLYTE LIQUID MIXTURES

Li Zhibao; Li Chunxi; Lu Jiufang; Li Yigui; Song Hongyan(Department of Chemical Engineering

您当前的位置：

首页 >

文章列表页 >

STATISTICAL THERMODYNAMIC MODEL OF SURFACE TENSION FOR NONELECTROLYTE LIQUID MIXTURES

更新时间：2025-12-16

- STATISTICAL THERMODYNAMIC MODEL OF SURFACE TENSION FOR NONELECTROLYTE LIQUID MIXTURES
- CIESC Journal Issue 6, (1996)
- 作者机构：
  
  清华大学化学工程系!北京100084,清华大学化学工程系!北京100084,清华大学化学工程系!北京100084,清华大学化学工程系!北京100084,山东建材学院应化系,济南,250022
- 作者简介：
- 基金信息：
- DOI：
  CLC： 647
- Online First：25 December 1996，
  
  Published：25 December 1996
- 稿件说明：
移动端阅览
Li Zhibao, Li Chunxi, Lu Jiufang, et al. STATISTICAL THERMODYNAMIC MODEL OF SURFACE TENSION FOR NONELECTROLYTE LIQUID MIXTURES[J]. CIESC Journal, 1996, (6).
DOI：

Li Zhibao, Li Chunxi, Lu Jiufang, et al. STATISTICAL THERMODYNAMIC MODEL OF SURFACE TENSION FOR NONELECTROLYTE LIQUID MIXTURES[J]. CIESC Journal, 1996, (6). DOI：

摘要

运用Davis模型导出一个统计热力学的表面张力模型．对22个双组分体系的表面张力作了推算和关联，总平均相对偏差分别为5.45％和1.95％.并利用关联双组分体系得到的参数值，直接推测了三组分体系的表面张力，平均相对偏差为2.21％.结果令人满意.表明该方法简单、精确，便于工程应用．

Abstract

A New statistical thermodynamic model of surface tension for liquid mixtures is developed by using Davis model.When molecular energy parameter is considered as temperature dependent

the calculation results of surface tension for one-component system have been greatly improved.The total average relative deviation for 29 different pure liquids is less than 1.0%.The surface tension for 22 binary liquid mixtures has been also predicted and correlated

and the calculation deviations are 5.48% and 1.95% respectively.Using the adjustable parameters obtained from relevant binary systems

this equation can predict the surface tension of multicomponent liquid mixtures with good accuracy.The calculation results show that the model proposed is reliable and convenient for engineering application not only for pure liquids but also for multicomponent systems.

关键词

Keywords

references

Views

794

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Research progress of ionic liquids in separation of aromatics/alkanes and olefins/alkanes

Thermo-gas-elastic coupling performance analysis of high-speed and high-temperature foil face seals

Study on entropy wave production and dissipation in partially premixed swirl flames subject to inlet perturbations

Exothermic characteristics of energy carrier for calcium looping thermo-chemical energy storage

Experimental study of heat transfer enhancement by pressure waves in cross flow tube bundles

Related Author

No data

Related Institution

No data

⁰