THERMODYNAMIC MODEL FOR SYSTEMS CONTAINING STRONG ASSOCIATED HYDROGEN FLUORIDE

郑大庆; HelmutKnapp

您当前的位置：

首页 >

文章列表页 >

THERMODYNAMIC MODEL FOR SYSTEMS CONTAINING STRONG ASSOCIATED HYDROGEN FLUORIDE

更新时间：2025-12-16

- THERMODYNAMIC MODEL FOR SYSTEMS CONTAINING STRONG ASSOCIATED HYDROGEN FLUORIDE
- CIESC Journal Issue 1, (1997)
- 作者机构：
  
  石油大学化工系,Department of Chemical Engineering,Technical University Berlin,北京,102200
- 作者简介：
- 基金信息：
- DOI：
  CLC： 642
- Online First：25 February 1997，
  
  Published：25 February 1997
- 稿件说明：
移动端阅览
郑大庆, HelmutKnapp. THERMODYNAMIC MODEL FOR SYSTEMS CONTAINING STRONG ASSOCIATED HYDROGEN FLUORIDE[J]. CIESC Journal, 1997, (1).
DOI：

郑大庆, HelmutKnapp. THERMODYNAMIC MODEL FOR SYSTEMS CONTAINING STRONG ASSOCIATED HYDROGEN FLUORIDE[J]. CIESC Journal, 1997, (1). DOI：

摘要

由于氢键的作用

氟化氢分子会形成多聚体

造成其热力学性质大大的偏离理想气体的性质.作者提出一个适合于含有强缔合物质氟化氢体系的热力学模型.此模型即考虑了由于氢键作用而形成多聚物的化学平衡

同时又考虑到了单体及多聚体之间的物理作用.改进了SRK方程

用以描述含氟化氢体系的相态行为.

Abstract

Due to hydrogen bond

strong association exists in the hydrogen fluoride vapor which causes the thermodynamic properties deviate largely from ideal gas behavior. A thermodynamic model was proposed for systems containing strongly associated hydrogen fluoride. This model considers both chemical and physical interactions between monomer and oligomers. SRK equation of state was modified to describe the phase behavior of systems containing hydrogen fluoride.

关键词

Keywords

references

Views

225

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

New universal corresponding state equation for correlation and extrapolation of saturated vapor-liquid density

Prediction model for COD in petrochemical wastewater influent based on temporal-spatial dual-stream convolutional neural network

Advantages and risks of swirling cooling granulation towers

Study on the residence time distribution characteristics of the TPMS-Diamond static mixer

The impact of novel flow channel structure with sudden-expansion ratio on seawater-activated battery

Related Author

No data

Related Institution

No data

⁰