周庆荣, 张泽廷, 朱美文, et al. STUDY ON SOLUBILITY OF SOLID SOLUTES IN A SUPERCRITICAL FLUID WITH ENTRAINERS(Ⅰ) CHEMICAL ASSOCIATION MODEL[J]. CIESC Journal, 1995, (3).
DOI:
周庆荣, 张泽廷, 朱美文, et al. STUDY ON SOLUBILITY OF SOLID SOLUTES IN A SUPERCRITICAL FLUID WITH ENTRAINERS(Ⅰ) CHEMICAL ASSOCIATION MODEL[J]. CIESC Journal, 1995, (3).DOI:
STUDY ON SOLUBILITY OF SOLID SOLUTES IN A SUPERCRITICAL FLUID WITH ENTRAINERS(Ⅰ) CHEMICAL ASSOCIATION MODEL
Based on the theory of chemical association equilibria
a general model for calculating solubilities of solid solutes in a supercritical fluid (SCF) with entrainers was derived asThis model could be modified and simplified into the following two semi - empirical correlationsModel 1:(No entrainer)(With entrainer)Model 2:where E is an enhancement factor of solubilities. The two models for predicting solubilities of solid solutes in a SCF with entrainers correlate the experimental data from literature and this work satisfactorily.