KINETICS OF OXIDATIVE DEH YDROGEN ATION OF BUTENE TO BUTADIENE OVER B02 CATALYST BY SEQUENTIAL EXPERIMENT DESIGN
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KINETICS OF OXIDATIVE DEH YDROGEN ATION OF BUTENE TO BUTADIENE OVER B02 CATALYST BY SEQUENTIAL EXPERIMENT DESIGN
CIESC JournalIssue 2, (1994)
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DOI:
CLC:643.3
Online First:25 April 1994,
Published:25 April 1994
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柏志军, 杜迎春, 张吉瑞. KINETICS OF OXIDATIVE DEH YDROGEN ATION OF BUTENE TO BUTADIENE OVER B02 CATALYST BY SEQUENTIAL EXPERIMENT DESIGN[J]. CIESC Journal, 1994, (2).
DOI:
柏志军, 杜迎春, 张吉瑞. KINETICS OF OXIDATIVE DEH YDROGEN ATION OF BUTENE TO BUTADIENE OVER B02 CATALYST BY SEQUENTIAL EXPERIMENT DESIGN[J]. CIESC Journal, 1994, (2).DOI:
KINETICS OF OXIDATIVE DEH YDROGEN ATION OF BUTENE TO BUTADIENE OVER B02 CATALYST BY SEQUENTIAL EXPERIMENT DESIGN
The intrinsic kinetic model for oxidative dehydrogenation of butene to butadiene over B02 catalyst was studied in an internal recirculation gradientless reactor by the sequential experiment design method
Hook -Jeeve and maximum likelihood method. Among 28 possible models based on a consecutive - parallel reaction network a model with the best fit was obtained as follows Where Dependence of selectivity with respect to butadiene on the partial pressures of oxygen
butene
butadiene and reaction temperature is as follows significance test indicated that reaction temperature was the main factor.