离子液体相行为(Ⅰ)胶团化特性

XIA Hansong; YU Jiang; HU Xuesheng; LIU Qingfen; LIU Huizhou

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离子液体相行为(Ⅰ)胶团化特性

更新时间：2025-12-10

- 离子液体相行为(Ⅰ)胶团化特性
- CIESC Journal Issue 9, (2006)
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- Online First：25 September 2006，
  
  Published：25 September 2006
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XIA Hansong, YU Jiang, HU Xuesheng, et al. 离子液体相行为(Ⅰ)胶团化特性[J]. CIESC Journal, 2006, (9).
DOI：

XIA Hansong, YU Jiang, HU Xuesheng, et al. 离子液体相行为(Ⅰ)胶团化特性[J]. CIESC Journal, 2006, (9). DOI：

摘要

研究了离子液体在水相中的自聚规律，从侧链、头部及阴离子类型等方面比较了影响胶团聚集的主要因素.实验发现，增加侧链长度有利于胶团形成，降低阴离子水合性以及采用甲基化头部也利于形成胶团，碳链长度变化的作用最明显，升高温度不利于离子液体形成胶团.

Abstract

The aggregation behavior of ionic liquids into micelle was studied.It was found that the micellization of ionic liquids was governed by its side-chain length

head structure and anion species

which could be promoted by increasing hydrophobicity

such as a long side-chain length

a hydrophobic anion or C2-methylated head.The side-chain length played the most active role in comparison with head group and anion.The micellization of ionic liquids would be weakened with increasing temperature.

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