Degradation of perfluorobutyric acid in aqueous solution by ultrasound irradiation
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Degradation of perfluorobutyric acid in aqueous solution by ultrasound irradiation
CIESC JournalIssue 2, Pages: 502-506(2011)
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Online First:05 February 2011,
Published:05 February 2011
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ZHAO Deming, HAN Taiping, Hoffmann Michael R., et al. Degradation of perfluorobutyric acid in aqueous solution by ultrasound irradiation[J]. CIESC Journal, 2011, (2): 502-506.
DOI:
ZHAO Deming, HAN Taiping, Hoffmann Michael R., et al. Degradation of perfluorobutyric acid in aqueous solution by ultrasound irradiation[J]. CIESC Journal, 2011, (2): 502-506.DOI:
Degradation of perfluorobutyric acid in aqueous solution by ultrasound irradiation
The feasibility of perfluorobutyric acid (PFBA)degradation by ultrasound irradiation was investigated and the influential factors such as ultrasonic frequency
initial PFBA concentration
sorts of saturated gas and reaction temperature were also evaluated.The experimental results showed that PFBA degradation followed the apparent pseudo-first order kinetic reaction.The sonolysis was completed over a range of frequency from 20 kHz to 1060 kHz at the initial PFBA concentration of 0.47×10-6 mol·L-1. However
the PFBA degradation rate constants had an apparent maximum at 610 kHz.Under the 610 kHz ultrasound irradiation
the initial PFBA concentration and the sorts of saturated gas affected greatly the PFBA degradation
and the reaction temperature had a slight effect on the PFBA degradation.In addition
the PFBA degradation in the manufacture wastewater was also evaluated under 610 kHz ultrasound.