Kinetics of advanced treatment of high-viscosity petrochemical wastewater with oxidation by Fenton’s reagent
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Kinetics of advanced treatment of high-viscosity petrochemical wastewater with oxidation by Fenton’s reagent
CIESC JournalIssue 2, Pages: 490-494(2011)
作者机构:
哈尔滨工业大学城市水资源与水环境国家重点实验室
作者简介:
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DOI:
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Online First:05 February 2011,
Published:05 February 2011
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QI Peishi, ZHAO Junjie, LIU Yunzhi, et al. Kinetics of advanced treatment of high-viscosity petrochemical wastewater with oxidation by Fenton’s reagent[J]. CIESC Journal, 2011, (2): 490-494.
DOI:
QI Peishi, ZHAO Junjie, LIU Yunzhi, et al. Kinetics of advanced treatment of high-viscosity petrochemical wastewater with oxidation by Fenton’s reagent[J]. CIESC Journal, 2011, (2): 490-494.DOI:
Kinetics of advanced treatment of high-viscosity petrochemical wastewater with oxidation by Fenton’s reagent
Advanced treatment of high-viscosity petrochemical wastewater was studied with the oxidation method by Fenton’s reagent as oxidant and the oxidation mechanism and kinetics were analyzed.According to the results from a series of single-factor experiments
it was observed that the control parameters in the oxidation process had different effects on COD removal rate.Through comparing those experimental results
a desirable COD removal rate of 62.00% was obtained at initial mass ratio R(=H2O2/COD)=1.52
molar ratio M(=H2O2/Fe2+)=10∶1
initial pH 3.0 and temperature of 25℃.A kinetic study was carried out by using a modified pseudo-first-order model with the reaction constant of k computed by multiple regression analysis.The experiments performed at different temperatures allowed the calculation of the Arrhenius equation parameters and the global activation energy Ea (25.5 kJ·mol-1)for the pseudo-first-order reaction.