Surface modification of sugar cane bagasse with aluminate ester strengthened by mechanical activation
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Surface modification of sugar cane bagasse with aluminate ester strengthened by mechanical activation
CIESC JournalIssue 7, Pages: 1983-1988(2011)
作者机构:
广西大学化学化工学院
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Online First:05 July 2011,
Published:05 July 2011
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HUANG Zuqiang, WANG Nan, HU Huayu, et al. Surface modification of sugar cane bagasse with aluminate ester strengthened by mechanical activation[J]. CIESC Journal, 2011, (7): 1983-1988.
DOI:
HUANG Zuqiang, WANG Nan, HU Huayu, et al. Surface modification of sugar cane bagasse with aluminate ester strengthened by mechanical activation[J]. CIESC Journal, 2011, (7): 1983-1988.DOI:
Surface modification of sugar cane bagasse with aluminate ester strengthened by mechanical activation
Sugar can bagasse(SCB)was mechanically activated by a self-made stirring-type ball mill. The effects of dosage of aluminate ester and activation time on the activation grade
contact angle of modified SCB and viscosity of SCB/paraffin oil system were investigated. In addition
the crystal structure and functional groups of bagasse were characterized by X-ray diffraction(XRD)and Fourier transform infrared spectroscopy(FTIR).The results showed that after modification with aluminate ester
the activation grade and contact angle of SCB increased
while viscosity of SCB/paraffin oil system decreased. The optimal effect was achieved when the dosage of aluminate ester was 3% of SCB. It was found that the reaction of SCB and aluminate ester was strengthened obviously by mechanical activation. The activation grade and contact angle of mechanically activated SCB increased obviously
and the viscosity of activated SCB/paraffin oil system decreased greatly after modification with aluminate ester. The optimal mechanical activation time was 120 min. After modification with aluminate ester
the dispersion of SCB in organic phase increased greatly
and the effect of mechanically activated SCB modified with aluminate ester became more remarkable. XRD analysis showed that mechanical activation decreased the degree of crystallinity of cellulose
made it more accessible to aluminate ester
and improved the reactivity of cellulose. FTIR analysis showed that chemical reaction of the hydroxy group on the surface of SCB and the alkoxyl group of aluminate ester took place during the modification
forming a new chemical bond Al—O—C
and a molecule layer of aluminate ester was also formed on the surface of SCB.