Density, refractive index and viscosity of binary mixture of ethyl acetate and 1,2-propanediol
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Density, refractive index and viscosity of binary mixture of ethyl acetate and 1,2-propanediol
CIESC JournalIssue 5, Pages: 1191-1196(2011)
作者机构:
湖州师范学院生命科学学院,浙江,湖州,313000
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Online First:05 May 2011,
Published:05 May 2011
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LING Jinlong, CAO Feng, XU Minhong, et al. Density, refractive index and viscosity of binary mixture of ethyl acetate and 1,2-propanediol[J]. CIESC Journal, 2011, (5): 1191-1196.
DOI:
LING Jinlong, CAO Feng, XU Minhong, et al. Density, refractive index and viscosity of binary mixture of ethyl acetate and 1,2-propanediol[J]. CIESC Journal, 2011, (5): 1191-1196.DOI:
Density, refractive index and viscosity of binary mixture of ethyl acetate and 1,2-propanediol
2-propanediol binary mixture were measured at temperatures in the range of 298.15—323.15 K and atmospheric pressure using pycnometer
ABBE refractometer and Ubbelohde viscometer respectively.The density and viscosity data are fitted as a function of composition and temperature.Excess molar volumes(VE)
refractive index deviations(ΔnD)
viscosity deviations(Δη)and excess Gibbs energy of activation of viscous flow(ΔG*E)are calculated from the experimental data.The results show that the excess molar volumes are negative at 298.15 K and 303.15 K
but they turn to be positive in the rich ester region with rising of temperature.The refractive index deviations are negative except in the rich alcohol region.Both Δη and ΔG*E are negative over the whole mole fraction range in the temperature range studied
and the deviations is greater as temperature decreases.