Blends of PVC and lignin treated with emulsion of ethyl acrylate-maleic anhydride copolymer
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Blends of PVC and lignin treated with emulsion of ethyl acrylate-maleic anhydride copolymer
CIESC JournalIssue 9, Pages: 2372-2376(2009)
作者机构:
1. 中国科学院广州化学研究所
2. 中国科学院研究生院
作者简介:
基金信息:
DOI:
CLC:
Online First:05 September 2009,
Published:05 September 2009
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LIU Feiyue, XU Linli, ZHENG Qiukai, et al. Blends of PVC and lignin treated with emulsion of ethyl acrylate-maleic anhydride copolymer[J]. CIESC Journal, 2009, (9): 2372-2376.
DOI:
LIU Feiyue, XU Linli, ZHENG Qiukai, et al. Blends of PVC and lignin treated with emulsion of ethyl acrylate-maleic anhydride copolymer[J]. CIESC Journal, 2009, (9): 2372-2376.DOI:
Blends of PVC and lignin treated with emulsion of ethyl acrylate-maleic anhydride copolymer
Lignin was treated with emulsion of ethyl acrylate(EA)-maleic anhydride(MA)copolymer,then blended with poly(vinyl chloride)(PVC).The rheological property,thermal stability and mechanical performance of the blends were investigated.When PVC is blended with lignin,the torque obviously increases in the first part of the rheological profile,while the equilibrium torque and process stability are not visibly distinguished from PVC without lignin
and the thermal stability is better than PVC without lignin.There is little change in rheological property or thermal stability of the blends when lignin is treated with emulsion of EA-MA copolymer,but the mechanical performance increases obviously.The best mechanical performance was found when lignin was treated with 1%(mass) of the copolymer emulsion,where the impact strength of the blend is 37.7% higher than that of the PVC control,while the tensile strength was not found visible change.Micrographs of the blend samples fractured at low temperature obtained by SEM illustrated a better compatibility between PVC and the lignin treated with the copolymer emulsion.