Optimal grade transition based on residence time distribution of catalyst particles in bimodal polyethylene production process
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Optimal grade transition based on residence time distribution of catalyst particles in bimodal polyethylene production process
CIESC JournalIssue 11, Pages: 2847-2853(2009)
作者机构:
1. 化学工程国家重点实验室(浙江大学
2. 浙江大学化学工程与生物工程学系
作者简介:
基金信息:
DOI:
CLC:
Online First:05 November 2009,
Published:05 November 2009
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WEI Geyi, WANG Jingdai, YANG Yongrong. Optimal grade transition based on residence time distribution of catalyst particles in bimodal polyethylene production process[J]. CIESC Journal, 2009, (11): 2847-2853.
DOI:
WEI Geyi, WANG Jingdai, YANG Yongrong. Optimal grade transition based on residence time distribution of catalyst particles in bimodal polyethylene production process[J]. CIESC Journal, 2009, (11): 2847-2853.DOI:
Optimal grade transition based on residence time distribution of catalyst particles in bimodal polyethylene production process
The Borstar technology contains a loop reactor and a fluidized bed reactor connecting in series. Aiming at minimizing the grade transition time and the quantity of off-specification product
a grade transition model involving catalyst changeover was presented for this process. Meanwhile
the models of instantaneous and cumulative polyethylene properties
including melt index and polymer density in each reactor
were presented for the tanks-in-series process involving catalyst changeover. The results showed that if grade transition involved catalyst changeover
the recommended optimal strategy was to feed new catalyst step by step. Further more
it is necessary to consider the respective demands for manipulated variable profiles by old and new catalysts and the effect of old catalyst mass fraction on resin properties in each reactor. In this way
the transition time was remarkably reduced
the sharp fluctuation of manipulated variables was restrained and the profiles of polymer properties were smoothed up.