Effects of ultrasound on adsorption and desorption of chromium(Ⅵ) on activated carbon
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Effects of ultrasound on adsorption and desorption of chromium(Ⅵ) on activated carbon
CIESC JournalIssue 11, Pages: 2805-2812(2009)
作者机构:
华侨大学化工学院
作者简介:
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Online First:05 November 2009,
Published:05 November 2009
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JING Guohua, DONG Meixia, ZHOU Zuoming, et al. Effects of ultrasound on adsorption and desorption of chromium(Ⅵ) on activated carbon[J]. CIESC Journal, 2009, (11): 2805-2812.
DOI:
JING Guohua, DONG Meixia, ZHOU Zuoming, et al. Effects of ultrasound on adsorption and desorption of chromium(Ⅵ) on activated carbon[J]. CIESC Journal, 2009, (11): 2805-2812.DOI:
Effects of ultrasound on adsorption and desorption of chromium(Ⅵ) on activated carbon
Effects of ultrasound on the adsorption and desorption of chromium (Ⅵ) on activated carbon were studied. Results showed that within the range of experiment concerned
the adsorption ratio of chromium(Ⅵ) decreases with pH increasing regardless ultrasound application. However
with ultrasound
the equilibrium of the system moves to the direction in the decrease of adsorption
which becomes severe with the increase in pH. With ultrasound
as the initial Cr(Ⅵ) concentration increases from 20 mg·L-1 to 110 mg·L-1
the removal efficiency of Cr(Ⅵ) drops from 99.9% to 79.8%
while the equilibrium adsorption capacity increases from 3. 3 mg·g-1 to 15. 0 mg·g-1
which is similar to that without ultrasound. The adsorption ratio continuously increases until to an equilibrium without ultrasound
while
it appears a slight decrease after being quickly to the equilibrium
and then gradually increases to the equilibrium again in case with ultrasound. The desorption ratio of Cr(Ⅵ) is very small in distilled water regardless ultrasound application. While
the desorption can be greatly improved by the addition of NaOH
and this promotion effect is remarkable for the ultrasonic system.