Experimental study on green deacidification technology of straight-run diesel
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Experimental study on green deacidification technology of straight-run diesel
CIESC JournalIssue 5, Pages: 1204-1208(2009)
作者机构:
1. 西南石油大学油气藏地质及开发工程国家重点实验室
2. 西南石油大学化学化工学院
3. 中海油能源发展股份有限公司石化分公司
作者简介:
基金信息:
DOI:
CLC:
Online First:05 May 2009,
Published:05 May 2009
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TANG Xiaodong, YANG Wenqian, WANG Hao, et al. Experimental study on green deacidification technology of straight-run diesel[J]. CIESC Journal, 2009, (5): 1204-1208.
DOI:
TANG Xiaodong, YANG Wenqian, WANG Hao, et al. Experimental study on green deacidification technology of straight-run diesel[J]. CIESC Journal, 2009, (5): 1204-1208.DOI:
Experimental study on green deacidification technology of straight-run diesel
The green deacidification technology of diesel by the ammonia-alcohol method without using strong acid and strong base can achieve zero-emission.But it has some problems
such as requiring larger amounts of ammonia and solvent
and higher energy consumption of regeneration solvent.To overcome the shortcomings of the ammonia-alcohol method
this paper experimentally studied the green deacidification technology of diesel by the ammonia-alcohol method
which used low-temperature coalescence filtration in a self-made experimental device.The effects of coalescence filtration temperature
amount of ammonia
alcohol consumption
volume ratio of solvent to oil on the deacidification process
material regeneration of coalescence filtration
deacidification’s turndown ratio and the product quality of naphthenic acid were studied.The results showed that under the optimum operation condition
the acidity of straight-run diesel could decrease from 62.9 mg KOH·(100 ml)-1 to 4.2 mg KOH·(100 ml)-1
the acid removal rate was as high as 93.3%
and product recovery could reach 98.6%.After refining
the quality of diesel could meet industry requirements [acidity X<7.0 mg KOH·(100 ml)-1]
and raw acid value of naphthenic acid could meet No.2 acid standards of SH/T 0530—92.This method had the advantages of simple technological process
low operating temperature of deacidification
less ammonia and solvent consumption
low solvent regeneration energy consumption and higher turndown ratio.