SADT calculation of solid organic peroxides based on small sample mass of heterogeneous reaction

DING Li; ZHANG Lijing; SHENG Yingxia; YAN Shihua

您当前的位置：

首页 >

文章列表页 >

SADT calculation of solid organic peroxides based on small sample mass of heterogeneous reaction

更新时间：2025-12-10

- SADT calculation of solid organic peroxides based on small sample mass of heterogeneous reaction
- CIESC Journal Issue 4, Pages: 1062-1067(2009)
- 作者机构：
  
  1. 江苏省城市与工业安全重点实验室，南京工业大学安全工程研究所,江苏,南京,210009
  2. 南京金凌石化工程设计有限公司,江苏,南京,210033
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Online First：05 April 2009，
  
  Published：05 April 2009
- 稿件说明：
移动端阅览
DING Li, ZHANG Lijing, SHENG Yingxia, et al. SADT calculation of solid organic peroxides based on small sample mass of heterogeneous reaction[J]. CIESC Journal, 2009, (4): 1062-1067.
DOI：

DING Li, ZHANG Lijing, SHENG Yingxia, et al. SADT calculation of solid organic peroxides based on small sample mass of heterogeneous reaction[J]. CIESC Journal, 2009, (4): 1062-1067. DOI：

摘要

Abstract

Three solid organic peroxides

benzoyl peroxide (BPO)

dicumyl peroxide (DCP) and cyclohexanone peroxide (CCP) were tested by using simultaneous TG-DSC analyzer (SDT Q600) with small sample mass

and the thermal data obtained from different scanning rate were analyzed by the Popescu multiple scanning rate method for the first time.Then

the values of self-accelerating decomposition temperature (SADT) of 25 kg standard package were computed according to the thermal explosion theory.The results showed that the values of activation energy and pre-exponential factor of these three solid organic peroxides by using the Popescu multiple scanning rate method were more precise and more credible than that by using the single scanning rate method.Based on correct calculation of these kinetic parameters

SADT can be accurately safely

easily

quickly evaluated with thermodynamic parameters based on thermal explosion theory.

关键词

Keywords

references

Views

192

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Hydrolysis reaction mechanism of CNCl on the surface of composite metal CuCr2O4

Prediction of biomass pyrolysis product yield based on machine learning algorithms

Optimization of heat storage and release cycle performance of Ca(OH)2/CaO indirect reactor

Mixed matrix membranes based on nitrogen-rich Schiff base network polymer and their CO2 separation performance

Thermodynamic performance of tower-type solar-assisted supercritical compression CO2 energy storage system

Related Author

No data

Related Institution

No data

⁰