Structural characteristics of sodium lignosulfonates and its use as dispersant of dimethomorph water-dispersible granules
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Structural characteristics of sodium lignosulfonates and its use as dispersant of dimethomorph water-dispersible granules
CIESC JournalIssue 8, Pages: 2127-2133(2008)
作者机构:
制浆造纸工程国家重点实验室,华南理工大学化学与化工学院,广东,广州,510640
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Online First:05 August 2008,
Published:05 August 2008
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LI Zhili, PANG Yuxia, LI Xiaona, et al. Structural characteristics of sodium lignosulfonates and its use as dispersant of dimethomorph water-dispersible granules[J]. CIESC Journal, 2008, (8): 2127-2133.
DOI:
LI Zhili, PANG Yuxia, LI Xiaona, et al. Structural characteristics of sodium lignosulfonates and its use as dispersant of dimethomorph water-dispersible granules[J]. CIESC Journal, 2008, (8): 2127-2133.DOI:
Structural characteristics of sodium lignosulfonates and its use as dispersant of dimethomorph water-dispersible granules
Structural characteristics of different sodium lignosulfonates (SLs)
Kinsperse126
Ultrazine Na
Borresperse Na
GZMN
and SXMN were investigated with ultraviolet spectrum
gel chromatography and chemical titration.The total hydrophilic groups content of Ultrazine Na was 5.46 mmol8226;g-1
which was the highest among these SLs.The sulfonic groups content of Kinsperse126 was 2.05 mmol8226;g-1
which was the highest among these SLs.The weight-mean relative molecular weight (Mw) of GZMN was 13000
which was the largest of these SLs.Mw of SXMN was 10000.Each SL was used as dispersant of dimethomorph water-dispersible granules (WG) respectively.The properties of dimethomorph WG were also investigated.The suspending rate of the WG with Kinsperse126 was as high as 95.03%.The suspending rate of the WG with SXMN was 89.70%.The dispersion ability of SL increased with increasing content of sulfonic groups and increasing Mw.Moreover
the sulfonic groups content was more important than Mw.Turbiscan LabExpert was initially used to estimate the stability of dimethomorph WG’s suspension.The suspension with Kinsperse126 had the best stability
in which deposition did not appear until 15 min and the height of sediment was only 0.38 mm.Particle size increase in the WG’s suspension with GZMN was only 0.59 μm which was the lowest.The stability depended on the dispersion ability of SL; furthermore