Detection of alkaline corrosion in 304 stainless steel weld zone by electrochemical noise
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Detection of alkaline corrosion in 304 stainless steel weld zone by electrochemical noise
CIESC JournalIssue 5, Pages: 1216-1222(2008)
作者机构:
1. 天津大学材料学院
2. 金属腐蚀与防护国家重点实验室
作者简介:
基金信息:
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Online First:05 May 2008,
Published:05 May 2008
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ZHAO Ru, DENG Weifeng, SONG Shizhe. Detection of alkaline corrosion in 304 stainless steel weld zone by electrochemical noise[J]. CIESC Journal, 2008, (5): 1216-1222.
DOI:
ZHAO Ru, DENG Weifeng, SONG Shizhe. Detection of alkaline corrosion in 304 stainless steel weld zone by electrochemical noise[J]. CIESC Journal, 2008, (5): 1216-1222.DOI:
Detection of alkaline corrosion in 304 stainless steel weld zone by electrochemical noise
Electrochemical noise was used to detect the corrosion process of the weld zone of 304 stainless steel(SS)in 50% NaOH solution at boiling point
its morphology was observed and its characteristic parameters were analyzed.The result showed that the weld’s corrosion potential dropped from -445 mV to below -560 mV during the experiment.When localized corrosion cracking was initiated
the amplitude was large and termination appeared.A high frequency plateau appeared in the power spectrum by use of the fast fourier transform(FFT)and high frequency roll-off slope K >-20 dB·dec-1 in the power spectral density (PSD) plot.Electrochemical noise of 304SS specimens at room temperature in 50% NaOH solution showed that different specimens had different corrosion potentials and electrochemical potential noise time spectra.The noise was produced by fluctuations in the electrochemical process and larger fluctuations would typically be indicative of a more localized process.Moreover
the use of the roll-off slope K in the PSD plot could detect whether the localized corrosion occurred or not.Further development work is expected to lead to a useful