Thermal stability of 13% acetic hydroperoxide

PEI Bei; JIANG Huiling; YU Shuijun; LIU Hua

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Thermal stability of 13% acetic hydroperoxide

更新时间：2025-12-10

- Thermal stability of 13% acetic hydroperoxide
- CIESC Journal Issue 9, Pages: 2260-2262(2008)
- 作者机构：
  
  1. 河南理工大学安全科学与工程学院
  2. 中国人民武装警察部队学院消防工程系
  3. 中原油气高新股份有限公司天然气产销厂
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Online First：05 September 2008，
  
  Published：05 September 2008
- 稿件说明：
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PEI Bei, JIANG Huiling, YU Shuijun, et al. Thermal stability of 13% acetic hydroperoxide[J]. CIESC Journal, 2008, (9): 2260-2262.
DOI：

PEI Bei, JIANG Huiling, YU Shuijun, et al. Thermal stability of 13% acetic hydroperoxide[J]. CIESC Journal, 2008, (9): 2260-2262. DOI：

摘要

为了研究过氧乙酸的爆炸危险性，采用绝热加速量热仪对13%过氧乙酸溶液进行了热危险性测试。通过数据校正和分析，得到了绝热条件下13%过氧乙酸溶液的初始放热温度为45.25℃，最大压力为1.31MPa，最高温升速率温度为113.10℃。结果表明，过氧乙酸溶液的热分解温度很低，在安全生产和储运过程中有一定的爆炸危险性。针对过氧乙酸的热危险性，提出采取适当措施，例如加强冷却，采用合理的泄放方式，以避免事故的发生。

Abstract

13% Acetic hydroperoxide was investigated by accelerating rate calorimeter (ARC).From ARC test

the initial exothermic temperature was 45.25℃

the maximum pressure was 1.31 MPa

and the maximum self-heating rate temperature was 113.10℃.The measured results indicated that the acetic hydroperoxide was easy to decompose and had obvious explosive hazard.In the end

the paper discusses related prevention measures

such as cooling and reasonable relief method

to avoid hazard.

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