Si speciation analysis of inorganic high polymer flocculant PFSS
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Si speciation analysis of inorganic high polymer flocculant PFSS
CIESC JournalIssue 11, Pages: 2937-2942(2007)
作者机构:
1. 重庆大学三峡库区生态环境教育部重点实验室
2. 重庆大学城市建设与环境工程学院
3. 重庆大学化学化工学院
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Online First:05 November 2007,
Published:05 November 2007
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ZHENG Huaili, WANG Baixue, ZHANG Zhanmei, et al. Si speciation analysis of inorganic high polymer flocculant PFSS[J]. CIESC Journal, 2007, (11): 2937-2942.
DOI:
ZHENG Huaili, WANG Baixue, ZHANG Zhanmei, et al. Si speciation analysis of inorganic high polymer flocculant PFSS[J]. CIESC Journal, 2007, (11): 2937-2942.DOI:
Si speciation analysis of inorganic high polymer flocculant PFSS
The Si species distribution of inorganic polymer flocculant polyferric silicate sulfate (PFSS) was studied by chemical Si-Mo assay.The study included reaction rate characteristics and standard work curve of SiO2
polysilicic acid (PSi) species distribution characteristics at different pH values
and comparison of Si species distribution characteristics of PFSS and PSi at different pH values .The experimental results showed that Si species distribution characteristics in PFSS were variable at different pH values.The content of Sib of silicic acid in PFSS at pH values 1.46 and 1.70 was higher than that of silicic acid in PFSS at pH value 0.64
while the contents of high polymer state and gelatinous state in PFSS at pH value 0.64 were obviously higher than those in PFSS at pH values 1.46 and 1.70.Simultaneously
the study results also showed that PFSS at pH values 1.46 and 1.70 had better flocculability and stability than PFSS at pH value 0.64
therefore the superior state of silicic acid in PFSS was Sib.