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安徽师范大学化学与材料科学学院
Online First:05 June 2007,
Published:05 June 2007
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CHU Daobao, CHEN Zhongping, WU Hezhen, et al. Preparation and electrochemical properties of carbon nanotube/nanocrystalline TiO2-polyaniline complex film electrode[J]. CIESC Journal, 2007, (6): 1568-1574.
DOI:
CHU Daobao, CHEN Zhongping, WU Hezhen, et al. Preparation and electrochemical properties of carbon nanotube/nanocrystalline TiO2-polyaniline complex film electrode[J]. CIESC Journal, 2007, (6): 1568-1574. DOI:
在含有0.2 mol·L-1苯胺的0.5 mol·L-1 H2SO4溶液中;采用循环伏安法(CV);以扫描速度50 mV·s-1;扫描电位为-0.1~0.9 V;在碳纳米管/纳米TiO2(CNT/nanoTiO2)膜电极上实现了苯胺的电化学聚合;通过CV法和电化学阻抗谱(EIS)并结合电子扫描显微镜和红外谱图对制备的碳纳米管/纳米TiO2-聚苯胺(CNT/nanoTiO2-PAn)复合膜电极的电化学性质和结构进行了表征;同时研究了复合膜电极对抗坏血酸(AH2)的电催化性能;发现该复合膜电极对抗坏血酸的氧化具有较高的电催化活性。
Polymerization of aniline on carbon nanotube/nanocrystalline TiO2(CNT/nanoTiO2)film electrode performed in 0.5 mol·L-1 sulfuric acid including 0.2 mol·L-1 aniline with scanning voltage -0.1V—0.9V at scanning rate 50 mV·s-1.
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