The catalytic combustion of the individual components and the mixtures of carbon monoxide

propylene and propane were investigated by using an integral microreactor under the conditions of no diffusion limitations. The adsorption properties of the reactants were probed by the temperature-programmed desorption (TPD) technique to distinguish the probable reaction mechanism. The Eley-Rideal kinetic models were selected to fit the experimental data of individual components conversion

and the parameters of the models were estimated by the partial least-square (PLS) method and simplex search optimization. The calculated conversion values of every component were in good agreement with the experimental data. Also

it was found that the conversions predicted by the individual component kinetic models were consistent with the experimental results of the mixture catalytic combustion.