Synthesis and catalytic dehydrogenation properties of MoO3/TiO2 complex nanocatalyst

CAI Bingxin; ZHAN Yonggong; YANG Yingying; GUO Dongcai; LIU Yuzhang

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Synthesis and catalytic dehydrogenation properties of MoO3/TiO2 complex nanocatalyst

更新时间：2025-12-10

- Synthesis and catalytic dehydrogenation properties of MoO3/TiO2 complex nanocatalyst
- CIESC Journal Issue 6, Pages: 1451-1456(2007)
- 作者机构：
  
  湖南大学化学化工学院
- 作者简介：
- 基金信息：
- DOI：
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- Online First：05 June 2007，
  
  Published：05 June 2007
- 稿件说明：
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CAI Bingxin, ZHAN Yonggong, YANG Yingying, et al. Synthesis and catalytic dehydrogenation properties of MoO3/TiO2 complex nanocatalyst[J]. CIESC Journal, 2007, (6): 1451-1456.
DOI：

CAI Bingxin, ZHAN Yonggong, YANG Yingying, et al. Synthesis and catalytic dehydrogenation properties of MoO3/TiO2 complex nanocatalyst[J]. CIESC Journal, 2007, (6): 1451-1456. DOI：

摘要

采用溶胶-凝胶法合成MoO3/TiO2、K2O-MoO3/TiO2、V2O5-MoO3/TiO2、Al2O3-MoO3/TiO2、K2O-V2O5-MoO3/TiO2系列纳米催化剂。借助TEM、XRD、IR等技术对催化剂进行了表征，并利用环己烷催化氧化脱氢成环己烯的反应进行活性测试。结果表明，MoO3在载体TiO2呈单层和多层分布，单层分布时发生了Mo与O—Ti的键合作用，同时使TiO2表面水分子发生解离反应，活化时脱去—OH产生Mo6+和Mo—O-活性中心;多层分布时以Mo[FY=，1]O、Mo—O-活性物种为主。脱氢中心和供氧中心之间存在协同作用，K、Al、V均能影响其协同作用。

Abstract

A series of MoO3/TiO2，K2O-MoO3/TiO2，V2O5-MoO3/TiO2，Al2O3-MoO3/TiO2 and K2O-V2O5-MoO3/TiO2 were prepared by the sol-gel method，and characterized with TEM，XRD and IR.The catalytic activity of oxydehydrogenation of cyclohexane to cyclohexene was tested.The results showed that MoO3 was distributed on the carrier of TiO2 with monolayer or/and multilayer.The Mo in the monolayer was bonded with O—Ti structure，and caused dissociation of the water molecules on the surface of TiO2，and the activity centre of Mo6+ and Mo—O- species were formed by means of activation to eliminate the hydroxyl group.For the multilayer structure the main active species were Mo[FY=，1]O and Mo—O-.A synergetic effect existed between the dehydrogenation centre and the oxygen-supply centre，and was affected by the addition of K，Al or V.

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