Synthesis and electrical conductivity of dialkylimidazolium tetraphenylborate
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Synthesis and electrical conductivity of dialkylimidazolium tetraphenylborate
CIESC JournalIssue 11, Pages: 2251-2255(2005)
作者机构:
鲁东大学化学与材料科学学院,山东,烟台,264025
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DOI:
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Online First:25 November 2005,
Published:25 November 2005
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LIU Chunping, WANG Minghua, HU Yucai, et al. Synthesis and electrical conductivity of dialkylimidazolium tetraphenylborate[J]. CIESC Journal, 2005, (11): 2251-2255.
DOI:
LIU Chunping, WANG Minghua, HU Yucai, et al. Synthesis and electrical conductivity of dialkylimidazolium tetraphenylborate[J]. CIESC Journal, 2005, (11): 2251-2255.DOI:
Synthesis and electrical conductivity of dialkylimidazolium tetraphenylborate
Owing to their unique chemical and physical properties
ionic liquids have caught attention for applications in diverse areas ranging from synthetic and catalytic chemistry to biotechnology
electrochemistry and material science. For fully using it in reaction
understanding of the physical and chemical properties of the ionic liquids is very important.The ionic liquid 1-butyl-3-methyl imidazolium tetraphenylborate ([BMIm][BPh4]) was synthesized in this study.Its structure and stability were determined by 1H NMR,UV and DSC. The melting point,solubilities and conductivities in different solvents and under different conditions were studied as well.The results showed that 1-butyl-3-methyl imidazolium tetraphenylborate was stable and was characterized as a strong electrolyte. The limiting molar conductivity values of the compound in acetone
acetonitrile
DMF
ethanol and ethyl acetate were 157.53
171.38
58.87
42.04 and 15.02 S8226;cm28226;mol-1
respectively.[BMIm][BPh4] had definite catalytic activity in the synthesis of isopentyl acetate.