Electro-oxidation of oxalic acid with polypyrrole prepared in 1-ethylimidazolium trifluoroacetate
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Electro-oxidation of oxalic acid with polypyrrole prepared in 1-ethylimidazolium trifluoroacetate
CIESC JournalIssue 7, Pages: 1588-1590(2006)
作者机构:
浙江工业大学化材学院
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Online First:25 July 2006,
Published:25 July 2006
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LI Meichao, SHEN Zhenlu, MA Chun’an, et al. Electro-oxidation of oxalic acid with polypyrrole prepared in 1-ethylimidazolium trifluoroacetate[J]. CIESC Journal, 2006, (7): 1588-1590.
DOI:
LI Meichao, SHEN Zhenlu, MA Chun’an, et al. Electro-oxidation of oxalic acid with polypyrrole prepared in 1-ethylimidazolium trifluoroacetate[J]. CIESC Journal, 2006, (7): 1588-1590.DOI:
Electro-oxidation of oxalic acid with polypyrrole prepared in 1-ethylimidazolium trifluoroacetate
The electrochemical oxidation of oxalic acid is important in environmental engineering.In this paper,polypyrrole(PPy)was prepared galvanostatically in an ionic liquid 1-ethylimidazolium trifluoroacetate(HEImTfa)and its electro-catalysis function for the electrochemical oxidation of oxalic acid was investigated by using cyclic voltammetry.The results showed that the electro-catalytic activity of PPy prepared in HEImTfa(PPy-HEImTfa)was greatly improved as compared with that prepared in conventional H2SO4 aqueous solution.Therefore,the use of HEImTfa as growth electrolyte and solvent for electro-polymerization of pyrrole resulted in an electrochemically catalytic film of PPy for the electro-oxidation of oxalic acid.