Electrolysis-generated ferrate at porous cylindrical cast iron anode and its application to degradation of organic wastewater
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Electrolysis-generated ferrate at porous cylindrical cast iron anode and its application to degradation of organic wastewater
CIESC JournalIssue 1, Pages: 151-154(2006)
作者机构:
福建师范大学化学与材料学院,福建,福州,350007
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Online First:25 January 2006,
Published:25 January 2006
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FANG Yi, ZHENG Xi, CHEN Riyao, et al. Electrolysis-generated ferrate at porous cylindrical cast iron anode and its application to degradation of organic wastewater[J]. CIESC Journal, 2006, (1): 151-154.
DOI:
FANG Yi, ZHENG Xi, CHEN Riyao, et al. Electrolysis-generated ferrate at porous cylindrical cast iron anode and its application to degradation of organic wastewater[J]. CIESC Journal, 2006, (1): 151-154.DOI:
Electrolysis-generated ferrate at porous cylindrical cast iron anode and its application to degradation of organic wastewater
Electrolysis-generated water treatment FeO2-4 was prepared in a diaphram cell with double cathodic chamber and porous cylindrical cast iron anode.The experiment result showed that current efficiency and FeO2-4 concentration were higher by using double cylinder cast iron anode.Optimum result was obtained at J=30 mA8226;cm-2
30℃
14 mol8226;L-1 NaOH.70 mmol8226;L-1 FeO2-4 was produced and current efficiency was 36.8% for 5.5 h electrolysis. The result of ferrate oxidative degradation of benzidine wastewater showed removal rate of CODCr about 85% and the final products were small molecule inorganic compounds.