Model for etherification kinetics of pyrocatechol and methallyl chloride
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Model for etherification kinetics of pyrocatechol and methallyl chloride
CIESC JournalIssue 10, Pages: 1892-1896(2005)
作者机构:
湘潭大学化工学院,湖南,湘潭,411105
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基金信息:
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Online First:25 October 2005,
Published:25 October 2005
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WEI Xiaobo, WANG Liangjie, LUO He’an. Model for etherification kinetics of pyrocatechol and methallyl chloride[J]. CIESC Journal, 2005, (10): 1892-1896.
DOI:
WEI Xiaobo, WANG Liangjie, LUO He’an. Model for etherification kinetics of pyrocatechol and methallyl chloride[J]. CIESC Journal, 2005, (10): 1892-1896.DOI:
Model for etherification kinetics of pyrocatechol and methallyl chloride
This work measured the kinetic data for the etherification of pyrocatechol with methallyl chloride and proposed a kinetic model for the reaction process according to the factor analysis of the reaction process and the data. The model included a desirable main reaction with two concomitant side reactions. The activation energy values of the main and side reactions were obtained
and the optimal reaction conditions such as reaction temperature
time
feeding time of methallyl chloride were discussed based on the reaction model. While a concomitant reaction was intensified at a lower temperature
another concomitant reaction was intensified at a higher temperature.