CATALYTIC DEGRADATION OF MACROMOLECULAR CONSTITUENTS OF ASPHALTIC SANDS IN IONIC LIQUIDS
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CATALYTIC DEGRADATION OF MACROMOLECULAR CONSTITUENTS OF ASPHALTIC SANDS IN IONIC LIQUIDS
CIESC JournalIssue 12, Pages: 2095-2098(2004)
作者机构:
1. 西南石油学院化学化工学院,四川,成都,610500
2. 油气藏地质及开发工程国家重点实验室,四川,成都,610500
作者简介:
基金信息:
DOI:
CLC:
Online First:25 December 2004,
Published:25 December 2004
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ZOU Changjun, LIU Chao, HUANG Zhiyu, et al. CATALYTIC DEGRADATION OF MACROMOLECULAR CONSTITUENTS OF ASPHALTIC SANDS IN IONIC LIQUIDS[J]. CIESC Journal, 2004, (12): 2095-2098.
DOI:
ZOU Changjun, LIU Chao, HUANG Zhiyu, et al. CATALYTIC DEGRADATION OF MACROMOLECULAR CONSTITUENTS OF ASPHALTIC SANDS IN IONIC LIQUIDS[J]. CIESC Journal, 2004, (12): 2095-2098.DOI:
CATALYTIC DEGRADATION OF MACROMOLECULAR CONSTITUENTS OF ASPHALTIC SANDS IN IONIC LIQUIDS
This paper illustrates the reaction pattern of catalytic degradation of macromolecules in asphaltic sands.Such parameters as ionic liquid catalyst system and H+ proton donor
that affect the change of the organic phase and the mass of organic matter in residual phase of asphaltic sands
were investigated.It was found that chloroaluminate (Ⅲ) ionic liquid/H3PO4 systems as reaction medium was an effective catalyst system for asphaltic sands degradation.The catalytic degradation of asphaltic sands was related to the kinds of chloroaluminate (Ⅲ) ionic liquids and H+ proton donor. In [BMIM][AlCl4]/H3PO4 reaction catalytic medium
the degradation of asphaltenes in the organic phase reached 16.44%
the degradation of asphaltenes in the residual phase reached 30.74%.TLC-FID analysis of asphaltic sands showed that the main degradation products were saturates and aromatics
and resin fractions as well.At a temperature close to oil-bearing formation and with absense of oxygen
the yield of H2S reached 74%
which indicated that catalytic degradation of sulphur-containing compounds was easier.