KINETIC MODEL OF CATALYTIC CRACKING BASED ON OLEFIN REACTION MECHANISM
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KINETIC MODEL OF CATALYTIC CRACKING BASED ON OLEFIN REACTION MECHANISM
CIESC JournalIssue 11, Pages: 1793-1798(2004)
作者机构:
1. 中国石化九江分公司,江西,九江,320004
2. 石油化工科学研究院,北京,100083
作者简介:
基金信息:
DOI:
CLC:
Online First:25 November 2004,
Published:25 November 2004
稿件说明:
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ZOU Shengwu, HOU Shuandi, LONG Jun, et al. KINETIC MODEL OF CATALYTIC CRACKING BASED ON OLEFIN REACTION MECHANISM[J]. CIESC Journal, 2004, (11): 1793-1798.
DOI:
ZOU Shengwu, HOU Shuandi, LONG Jun, et al. KINETIC MODEL OF CATALYTIC CRACKING BASED ON OLEFIN REACTION MECHANISM[J]. CIESC Journal, 2004, (11): 1793-1798.DOI:
KINETIC MODEL OF CATALYTIC CRACKING BASED ON OLEFIN REACTION MECHANISM
A molecular kinetic model was derived on the basis of FCC reaction mechanism to represent the cracking reactions.Lumps were defined not only by their boiling range but also by their chemical compositions.A molecular lumped approach was then proposed for the FCC reaction in which H transfer
aromatization and yield of fuel gas were taken into account.In order to predict chemical composition of gasoline
eighteen kinetic parameters in the lumped reaction kinetic model were determined by the parameter estimation method.This work showed that the proposed model simulation results were coincident with the experiment data.The proposed model not only could predict successfully the yields
but also could provide more information of the chemical component of gasoline
which is useful in the study on how to reduce the olefins content of gasoline.