ACTIVITY TEST FOR COMMERCIAL AMMONIA SYNTHESIS CATALYST A301 IN SINGLE TUBE REACTOR
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ACTIVITY TEST FOR COMMERCIAL AMMONIA SYNTHESIS CATALYST A301 IN SINGLE TUBE REACTOR
CIESC JournalIssue 11, (2001)
作者机构:
浙江工业大学催化研究所浙江省多相催化重点实验室
作者简介:
基金信息:
DOI:
CLC:
Online First:25 November 2001,
Published:25 November 2001
稿件说明:
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LIU Huazhang, LI Xiaonian, HU Zhangneng, et al. ACTIVITY TEST FOR COMMERCIAL AMMONIA SYNTHESIS CATALYST A301 IN SINGLE TUBE REACTOR[J]. CIESC Journal, 2001, (11).
DOI:
LIU Huazhang, LI Xiaonian, HU Zhangneng, et al. ACTIVITY TEST FOR COMMERCIAL AMMONIA SYNTHESIS CATALYST A301 IN SINGLE TUBE REACTOR[J]. CIESC Journal, 2001, (11).DOI:
ACTIVITY TEST FOR COMMERCIAL AMMONIA SYNTHESIS CATALYST A301 IN SINGLE TUBE REACTOR
specific rate of reaction and usable ratio of inner surface (URIS) for commercial A301 ammonia catalyst were measured in a tube packed bed reactor. The reaction conditions were: pressure of 7.0
10.0 and 15.0MPa
temperature of 325—450℃
space velocity of 6000
8000 and 10000h -1 and particle size of 0.6—0.9
1.6—2.5
2.5—3.0
3.0—4.0 and 4.0—6.7 mm. The outlet ammonia concentration
specific rate and URIS decreased with increasing particle size. URIS of commercial catalyst depended not only on particle size
but also on temperature and catalyst efficiency. Particle size was the most important factor for URIS. With increasing particle size from 0.6—0.9mm to 4.0—6.7mm
URIS of catalyst decreased from 1 to 0.74—0.80. For the same size range of catalyst
URIS depended on temperature and catalyst efficiency. Above the temperature of 350℃
catalyst efficiency and URIS increased with rising temperature. But below 350℃