ON-BOARD HYDROGEN GENERATION BY METHANOL PARTIAL OXIDATION(Ⅱ) EFFECT OF REACTOR CONSTRUCTION AND TECHNICAL PARAMETERS ON THE HYDROGEN PRODUCING PROCESS
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ON-BOARD HYDROGEN GENERATION BY METHANOL PARTIAL OXIDATION(Ⅱ) EFFECT OF REACTOR CONSTRUCTION AND TECHNICAL PARAMETERS ON THE HYDROGEN PRODUCING PROCESS
CIESC JournalIssue 12, (2001)
作者机构:
中国科学院大连化学物理研究所
作者简介:
基金信息:
DOI:
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Online First:25 December 2001,
Published:25 December 2001
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QI Aidu, WANG Shudong, HONG Xuelun, et al. ON-BOARD HYDROGEN GENERATION BY METHANOL PARTIAL OXIDATION(Ⅱ) EFFECT OF REACTOR CONSTRUCTION AND TECHNICAL PARAMETERS ON THE HYDROGEN PRODUCING PROCESS[J]. CIESC Journal, 2001, (12).
DOI:
QI Aidu, WANG Shudong, HONG Xuelun, et al. ON-BOARD HYDROGEN GENERATION BY METHANOL PARTIAL OXIDATION(Ⅱ) EFFECT OF REACTOR CONSTRUCTION AND TECHNICAL PARAMETERS ON THE HYDROGEN PRODUCING PROCESS[J]. CIESC Journal, 2001, (12).DOI:
ON-BOARD HYDROGEN GENERATION BY METHANOL PARTIAL OXIDATION(Ⅱ) EFFECT OF REACTOR CONSTRUCTION AND TECHNICAL PARAMETERS ON THE HYDROGEN PRODUCING PROCESS
The effect of reactor configuration and technical parameters on the gross heat efficiency and "hot spot" temperature was investigated in an autothermal operation process of methanol partial oxidation based on the balance of mass and energy balance as well as kinetics of the reactor. The conversion of methanol
productivity of hydrogen and the gross heat efficiency increased with the decrease of height/diameter ratio of the reactor when the same amount of catalyst was used
so the catalyst effective index was enhanced by this means. Furthermore
for the same gross heat efficiency
a lower amount of oxygen or air was needed when the height/diameter ratio was relatively small
which lead to the decrease of "hot spot" temperature. In order to make the "hot spot" temperature even lower
a reactor with multi-inlets could be used.The "hot spot" temperature dropped greatly when oxygen was input by two inlets or more
and only trivial loss of conversion and hydrogen productivity was observed. Therefore
the principle of reactor design was obtained
and the suitable configuration of the reactor
such as radial flow reactor and inorganic reactor was proposed.