MEASUREMENT AND CALCULATION OF HYDRATE FORMATION CONDITIONS FOR GAS MIXTURES CONTAINING HYDROGEN

ZHANG Shixi; CHEN Guangjin; YANG Lanying; MA Changfeng; GUO Tianmin

您当前的位置：

首页 >

文章列表页 >

MEASUREMENT AND CALCULATION OF HYDRATE FORMATION CONDITIONS FOR GAS MIXTURES CONTAINING HYDROGEN

更新时间：2025-12-10

- MEASUREMENT AND CALCULATION OF HYDRATE FORMATION CONDITIONS FOR GAS MIXTURES CONTAINING HYDROGEN
- CIESC Journal Issue 1, Pages: 24-28(2003)
- 作者机构：
  
  石油大学流体高压相态及物性研究室
- 作者简介：
- 基金信息：
- DOI：
  CLC：
- Online First：25 January 2003，
  
  Published：25 January 2003
- 稿件说明：
移动端阅览
ZHANG Shixi, CHEN Guangjin, YANG Lanying, et al. MEASUREMENT AND CALCULATION OF HYDRATE FORMATION CONDITIONS FOR GAS MIXTURES CONTAINING HYDROGEN[J]. CIESC Journal, 2003, (1): 24-28.
DOI：

ZHANG Shixi, CHEN Guangjin, YANG Lanying, et al. MEASUREMENT AND CALCULATION OF HYDRATE FORMATION CONDITIONS FOR GAS MIXTURES CONTAINING HYDROGEN[J]. CIESC Journal, 2003, (1): 24-28. DOI：

摘要

利用全透明蓝宝石水合物静力学实验装置测定了12组含氢气体混合物（包括5个二元系、4个三元系和3个四元系）在纯水中的水合物生成条件.将Chen-Guo水合物模型应用于含氢体系水合物生成条件的计算，计算中选用PR状态方程以及刘昆元和汪文川提出的混合规则计算含氢气体混合物的组分逸度系数，并对混合规则中的二元交互作用参数进行了重新回归.实验测定的12组含氢气体混合物水合物生成条件的计算结果和实验结果符合得很好.

Abstract

Hydrate formation conditions of twelve synthetic hydrogen + hydrocarbon gas mixtures (H2 + CH4

H2 + C3H8

H2 + CH4 + C3H8

H2 + CH4 + C2H6 + C3H8) were measured in a sapphire cell using the “pressure search” method. The experimental temperature range was 274―280 K

and the pressure range was 0.65―7.0 MPa. The hydrogen content in the gas mixtures varied from 22% to 92%（mol）.By using PR equation of state and suitable mixing rule

the Chen-Guo’s hydrate model was extended to calculate the hydrate formation conditions of the hydrogen-containing systems. Satisfactory agreement between experimental data and calculated results were achieved.

关键词

Keywords

references

Views

120

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Evaluation of vapor-liquid equilibrium prediction methods  for related binary systems of Fischer-Tropsch synthesis oil syst

Calculation of phase equilibrium of alkanolamines systems with CPA equation of state based on Shield-Sticky model

Design method of heat integrated water networks considering non-isothermal mixing

Hydrogen production from reform of bio-oil aqueous phase over Z204 catalyst using two-stage fixed bed reactor

Bimodal polyethylene produced by oscillating operation of hydrogen in single gas-phase polymerization reactor

Related Author

HAO Xu

DONG Lihua

CAO Liren

LI Yongwang

HU Ying

LI Jinlong

PENG Changjun

LIU Honglai

Related Institution

中国科学院研究生院

中国科学院山西煤炭化学研究所煤转化国家重点实验室

华东理工大学化学工程国家重点实验室，化学系

化学工程联合国家重点实验室（天津大学），天津大学化学工程研究所，

中国科学院广州能源研究所

⁰