MacMillan D W C . The advent and development of organocatalysis [J ] . Nature , 2008 , 455 ( 7211 ): 304 - 308 .

Bell E L , Finnigan W , France S P , et al . Biocatalysis [J ] . Nature Reviews Methods Primers , 2021 , 1 : 46 .

Wang H J , Wang M D , Liang X , et al . Organic molecular sieve membranes for chemical separations [J ] . Chemical Society Reviews , 2021 , 50 ( 9 ): 5468 - 5516 .

Park H B , Kamcev J , Robeson L M , et al . Maximizing the right stuff: The trade-off between membrane permeability and selectivity [J ] . Science , 2017 , 356 ( 6343 ): eaab0530 .

Freeman B D . Basis of permeability/selectivity tradeoff relations in polymeric gas separation membranes [J ] . Macromolecules , 1999 , 32 ( 2 ): 375 - 380 .

Robeson L M . Correlation of separation factor versus permeability for polymeric membranes [J ] . Journal of Membrane Science , 1991 , 62 ( 2 ): 165 - 185 .

Caro J , Noack M , Kölsch P , et al . Zeolite membranes–state of their development and perspective [J ] . Microporous and Mesoporous Materials , 2000 , 38 ( 1 ): 3 - 24 .

Tsapatsis M . Toward high-throughput zeolite membranes [J ] . Science , 2011 , 334 ( 6057 ): 767 - 768 .

Tavolaro A , Drioli E . Zeolite membranes [J ] . Advanced Materials , 1999 , 11 ( 12 ): 975 - 996 .

Bux H , Liang F Y , Li Y S , et al . Zeolitic imidazolate framework membrane with molecular sieving properties by microwave-assisted solvothermal synthesis [J ] . Journal of the American Chemical Society , 2009 , 131( 44 ) 16000 - 16001

Lai Z P , Bonilla G , Diaz I , et al . Microstructural optimization of a zeolite membrane for organic vapor separation [J ] . Science , 2003 , 300 ( 5618 ): 456 - 460 .

Caro J . Are MOF membranes better in gas separation than those made of zeolites [J ] . Current Opinion in Chemical Engineering , 2011 , 1 ( 1 ): 77 - 83 .

Liu G Z , Guo Y N , Chen C L , et al . Eliminating lattice defects in metal–organic framework molecular-sieving membranes [J ] . Nature Materials , 2023 , 22 ( 6 ): 769 - 776 .

Brown A J , Brunelli N A , Eum K , et al . Interfacial microfluidic processing of metal-organic framework hollow fiber membranes [J ] . Science , 2014 , 345 ( 6192 ): 72 - 75 .

Liu X L , Demir N K , Wu Z T , et al . Highly water-stable zirconium metal–organic framework UiO-66 membranes supported on alumina hollow fibers for desalination [J ] . Journal of the American Chemical Society , 2015 , 137 ( 22 ): 6999 - 7002 .

Jiang H , Alezi D , Eddaoudi M . A reticular chemistry guide for the design of periodic solids [J ] . Nature Reviews Materials , 2021 , 6 ( 6 ): 466 - 487 .

Yaghi O M . Reticular chemistry in all dimensions [J ] . ACS Central Science , 2019 , 5 ( 8 ): 1295 - 1300 .

Sezgin P , Keskin S . The transformative role of machine learning in advancing MOF membranes for gas separations [J ] . Chemical Physics Reviews , 2025 , 6 ( 3 ): 031303 .

Qiu Y , Wang L , Liu C , et al . The evolution of MOF discovery for CO 2 capture: From high-throughput screening to AI design and automated laboratories [J ] . Materials Today , 2025 , 91 : 103 - 123 .

Qiu Y , Chen L T , Zhang X , et al . A universal machine learning framework to automatically identify high-performance covalent organic framework membranes for CH 4 /H 2 separation [J ] . AIChE Journal , 2024 , 70 ( 12 ): e18575 .

Budd P M , McKeown N B , Fritsch D . Free volume and intrinsic microporosity in polymers [J ] . Journal of Materials Chemistry , 2005 , 15 ( 20 ): 1977 .

Park K S , Ni Z , Côté A P , et al . Exceptional chemical and thermal stability of zeolitic imidazolate frameworks [J ] . Proceedings of the National Academy of Sciences of the United States of America , 2006 , 103 ( 27 ): 10186 - 10191 .

He Y B , Xiang S C , Chen B L . A microporous hydrogen-bonded organic framework for highly selective C 2 H 2 /C 2 H 4 separation at ambient temperature [J ] . Journal of the American Chemical Society , 2011 , 133 ( 37 ): 14570 - 14573 .

Ding S Y , Gao J , Wang Q , et al . Construction of covalent organic framework for catalysis: Pd/COF-LZU1 in suzuki–miyaura coupling reaction [J ] . Journal of the American Chemical Society , 2011 , 133( 49 ) 19816 - 19822

Li J Q , Liu Q , Shen J , et al . High-strength conjugated polymer framework membranes for ultrafast and precise separations [J ] . Nature Sustainability , 2026 , 9 ( 2 ): 271 - 282 .

Ben T , Ren H , Ma S Q , et al . Targeted synthesis of a porous aromatic framework with high stability and exceptionally high surface area [J ] . Angewandte Chemie (International Ed. in English) , 2009 , 48 ( 50 ): 9457 - 9460 .

He A , Jiang Z W , Wu Y , et al . A smart and responsive crystalline porous organic cage membrane with switchable pore apertures for graded molecular sieving [J ] . Nature Materials , 2022 , 21 ( 4 ): 463 - 470 .

McKeown N B . Polymers of intrinsic microporosity [J ] . ISRN Materials Science , 2012 , 2012 : 513986 .

McKeown N B , Budd P M . Polymers of intrinsic microporosity (PIMs): organic materials for membrane separations, heterogeneous catalysis and hydrogen storage [J ] . Chemical Society Reviews , 2006 , 35 ( 8 ): 675 .

Budd P M , Elabas E S , Ghanem B S , et al . Solution-processed, organophilic membrane derived from a polymer of intrinsic microporosity [J ] . Advanced Materials , 2004 , 16 ( 5 ): 456 - 459 .

Wang Y G , Ghanem B S , Han Y , et al . State-of-the-art polymers of intrinsic microporosity for high-performance gas separation membranes [J ] . Current Opinion in Chemical Engineering , 2022 , 35 : 100755 .

Outreach N P . Scientific Background to the Nobel Prize in Chemistry 2025: Metal-Organic Frameworks . NobelPrize.org , 2025 .

Zhou H , Kitagawa S . Metal–organic frameworks (MOFs) [J ] . Chemical Society Reviews , 2014 , 43 ( 16 ): 5415 - 5418 .

Li H L , Eddaoudi M , O’Keeffe M , et al . Design and synthesis of an exceptionally stable and highly porous metal-organic framework [J ] . Nature , 1999 , 402 ( 6759 ): 276 - 279 .

Wang K C , Li Y P , Xie L H , et al . Construction and application of base-stable MOFs: a critical review [J ] . Chemical Society Reviews , 2022 , 51 ( 15 ): 6417 - 6441 .

Zhou S , Shekhah O , Jia J T , et al . Electrochemical synthesis of continuous metal–organic framework membranes for separation of hydrocarbons [J ] . Nature Energy , 2021 , 6 ( 9 ): 882 - 891 .

Shi X S , Li H , Chen T , et al . Selective liquid-phase molecular sieving via thin metal–organic framework membranes with topological defects [J ] . Nature Chemical Engineering , 2024 , 1 ( 7 ): 483 - 493 .

Lu J , Zhang H C , Hou J , et al . Efficient metal ion sieving in rectifying subnanochannels enabled by metal–organic frameworks [J ] . Nature Materials , 2020 , 19 ( 7 ): 767 - 774 .

Lu J , Jiang G P , Zhang H C , et al . An artificial sodium-selective subnanochannel [J ] . Science Advances , 2023 , 9 ( 4 ): eabq1369 .

Sun W J , Yang K C , Zhao Y F , et al . Precise modulation of MOF pore structures via functional group dimensions and spatial configuration for membrane separation [J ] . Science Advances , 2026 , 12 ( 8 ): eadz7972 .

Zhang C , Wu B H , Ma M Q , et al . Ultrathin metal/covalent–organic framework membranes towards ultimate separation [J ] . Chemical Society Reviews , 2019 , 48 ( 14 ): 3811 - 3841 .

Cheng Y D , Datta S J , Zhou S , et al . Advances in metal–organic framework-based membranes [J ] . Chemical Society Reviews , 2022 , 51 ( 19 ): 8300 - 8350 .

Lin R B , Chen B L . Hydrogen-bonded organic frameworks: Chemistry and functions [J ] . Chem , 2022 , 8 ( 8 ): 2114 - 2135 .

Yin Q , Pang K , Feng Y N , et al . Hydrogen-bonded organic frameworks in solution enables continuous and high-crystalline membranes [J ] . Nature Communications , 2024 , 15 : 634 .

Chen C , Shen L G , Lin H J , et al . Hydrogen-bonded organic frameworks for membrane separation [J ] . Chemical Society Reviews , 2024 , 53 ( 5 ): 2738 - 2760 .

Côté A P , Benin A I , Ockwig N W , et al . Porous, crystalline, covalent organic frameworks [J ] . Science , 2005 , 310 ( 5751 ): 1166 - 1170 .

Qian C , Feng L L , Teo W L , et al . Imine and imine-derived linkages in two-dimensional covalent organic frameworks [J ] . Nature Reviews Chemistry , 2022 , 6 ( 12 ): 881 - 898 .

Tan K T , Ghosh S , Wang Z Y , et al . Covalent organic frameworks [J ] . Nature Reviews Methods Primers , 2023 , 3 : 1 .

Huang N , Wang P , Jiang D L . Covalent organic frameworks: a materials platform for structural and functional designs [J ] . Nature Reviews Materials , 2016 , 1 ( 10 ): 16068 .

He G W , Zhang R N , Jiang Z Y . Engineering covalent organic framework membranes [J ] . Accounts of Materials Research , 2021 , 2( 8 ) 630 - 643 .

Yuan S S , Li X , Zhu J Y , et al . Covalent organic frameworks for membrane separation [J ] . Chemical Society Reviews , 2019 , 48 ( 10 ): 2665 - 2681 .

Kuhn P , Antonietti M , Thomas A . Porous, covalent triazine-based frameworks prepared by ionothermal synthesis [J ] . Angewandte Chemie (International Ed. in English) , 2008 , 47 ( 18 ): 3450 - 3453 .

Liu C J , Hou J J , Yan M Z , et al . Regulating the layered stacking of a covalent triazine framework membrane for aromatic/aliphatic separation [J ] . Angewandte Chemie , 2024 , 136 ( 15 ): e202320137 .

Wang Y , Li J P , Yang Q Y , et al . Two-dimensional covalent triazine framework membrane for helium separation and hydrogen purification [J ] . ACS Applied Materials & Interfaces , 2016 , 8( 13 ) 8694 - 8701 .

Zhuang X D , Zhao W X , Zhang F , et al . A two-dimensional conjugated polymer framework with fully sp 2 -bonded carbon skeleton [J ] . Polymer Chemistry , 2016 , 7 ( 25 ): 4176 - 4181 .

Shen J , Cai Y C , Zhang C H , et al . Fast water transport and molecular sieving through ultrathin ordered conjugated-polymer-framework membranes [J ] . Nature Materials , 2022 , 21 ( 10 ): 1183 - 1190 .

Tian Y Y , Zhu G S . Porous aromatic frameworks (PAFs) [J ] . Chemical Reviews , 2020 , 120 ( 16 ): 8934 - 8986 .

Lau C H , Konstas K , Thornton A W , et al . Gas-separation membranes loaded with porous aromatic frameworks that improve with age [J ] . Angewandte Chemie , 2015 , 127 ( 9 ): 2707 - 2711 .

Uliana A A , Bui N T , Kamcev J , et al . Ion-capture electrodialysis using multifunctional adsorptive membranes [J ] . Science , 2021 , 372 ( 6539 ): 296 - 299 .

Tozawa T , Jones J T A , Swamy S I , et al . Porous organic cages [J ] . Nature Materials , 2009 , 8 ( 12 ): 973 - 978 .

Song Q L , Jiang S , Hasell T , et al . Porous organic cage thin films and molecular-sieving membranes [J ] . Advanced Materials , 2016 , 28 ( 13 ): 2629 - 2637 .

Li Y F , Liu Z , Zhu D J , et al . Porous organic cage mixed matrix membranes for efficient enantioseparation [J ] . Nature Communications , 2025 , 16 : 11699 .

Wang M D , Wang Y T , Zhao J Y , et al . Electrochemical interfacial polymerization toward ultrathin COF membranes for brine desalination [J ] . Angewandte Chemie International Edition , 2023 , 62 ( 13 ): e202219084 .

Zhou S , Wei Y Y , Li L B , et al . Paralyzed membrane: Current-driven synthesis of a metal-organic framework with sharpened propene/propane separation [J ] . Science Advances , 2018 , 4 ( 10 ): eaau1393 .

Zhou Z Y , Guo D , Shinde D B , et al . Precise sub-angstrom ion separation using conjugated microporous polymer membranes [J ] . ACS Nano , 2021 , 15 ( 7 ): 11970 - 11980 .

Cao L , Chen C L , An S H , et al . Covalent organic framework membranes with patterned high-density through-pores for ultrafast molecular sieving [J ] . Journal of the American Chemical Society , 2024 , 146( 31 ) 21989 - 21998 .

Wang R , Zhou Y S , Zhang Y , et al . Ultrathin covalent organic framework membranes prepared by rapid electrophoretic deposition [J ] . Advanced Materials , 2022 , 34 ( 44 ): 2204894 .

Liu Y T , Wu H , Li R L , et al . MOF–COF “alloy” membranes for efficient propylene/propane separation [J ] . Advanced Materials , 2022 , 34 ( 24 ): 2201423 .

Yuan J Q , You X D , Ali Khan N , et al . Photo-tailored heterocrystalline covalent organic framework membranes for organics separation [J ] . Nature Communications , 2022 , 13 : 3826 .

Fan H W , Mundstock A , Feldhoff A , et al . Covalent organic framework–covalent organic framework bilayer membranes for highly selective gas separation [J ] . Journal of the American Chemical Society , 2018 , 140( 32 ) 10094 - 10098 .

Sholl D S . Quantum sieving for isotopic separations of gases using porous Materials─30 years of progress [J ] . The Journal of Physical Chemistry C , 2025 , 129 ( 24 ): 10793 - 10801 .

Noguchi D , Tanaka H , Kondo A , et al . Quantum sieving effect of three-dimensional Cu-based organic framework for H 2 and D 2 [J ] . Journal of the American Chemical Society , 2008 , 130( 20 ) 6367 - 6372 .

Oh H , Kalidindi S B , Um Y , et al . A cryogenically flexible covalent organic framework for efficient hydrogen isotope separation by quantum sieving [J ] . Angewandte Chemie International Edition in English , 2013 , 52 ( 50 ): 13219 - 13222 .

Won J , Kim D B , Kang Y S , et al . An ab initio study of ionic liquid silver complexes as carriers in facilitated olefin transport membranes [J ] . Journal of Membrane Science , 2005 , 260 ( 1/2 ): 37 - 44 .

Wang M D , Pan F S , Yang H , et al . Constructing channel-mediated facilitated transport membranes by incorporating covalent organic framework nanosheets with tunable microenvironments [J ] . Journal of Materials Chemistry A , 2019 , 7 ( 16 ): 9912 - 9923 .

Guo Z Y , Wu H , Chen Y , et al . Missing-linker defects in covalent organic framework membranes for efficient CO2 separation [J ] . Angewandte Chemie , 2022 , 134 ( 41 ): e202210466 .

Bocquet L . Nanofluidics coming of age [J ] . Nature Materials , 2020 , 19 ( 3 ): 254 - 256 .

Li R L , Yang Y J , Chen J J , et al . Channel–molecule attraction mediated molecule transport in confined nanochannels of COF membranes for nanofiltration [J ] . AIChE Journal , 2025 , 71 ( 4 ): e18719 .

Zhao S , Jiang C H , Fan J C , et al . Hydrophilicity gradient in covalent organic frameworks for membrane distillation [J ] . Nature Materials , 2021 , 20 ( 11 ): 1551 - 1558 .

Yang J W , Wang B , Feng X . Mass transport based on covalent organic frameworks [J ] . Accounts of Chemical Research , 2025 , 58( 9 ) 1447 - 1460 .

Secchi E , Marbach S , Niguès A , et al . Massive radius-dependent flow slippage in carbon nanotubes [J ] . Nature , 2016 , 537 ( 7619 ): 210 - 213 .

Holt J K , Park H G , Wang Y M , et al . Fast mass transport through sub-2-nanometer carbon nanotubes [J ] . Science , 2006 , 312 ( 5776 ): 1034 - 1037 .

Shinde D B , Sheng G , Li X , et al . Crystalline 2D covalent organic framework membranes for high-flux organic solvent nanofiltration [J ] . Journal of the American Chemical Society , 2018 , 140 ( 43 ): 14342 - 14349 .

Ji Y L , Gu B X , Xie S J , et al . Superfast water transport zwitterionic polymeric nanofluidic membrane reinforced by metal-organic frameworks [J ] . Advanced Materials , 2021 , 33 ( 38 ): e2102292 .

Hess P , Tsien R W . Mechanism of ion permeation through calcium channels [J ] . Nature , 1984 , 309 ( 5967 ): 453 - 456 .

Du Y Q , Lei D , Zhang L C , et al . Ion trap membrane with confined bind-jump strategy for high-efficiency direct lithium extraction [J ] . Science Advances , 2026 , 12 ( 16 ): eaea5077 .

Friel D D , Tsien R W . Voltage-gated calcium channels: direct observation of the anomalous mole fraction effect at the single-channel level [J ] . Proceedings of the National Academy of Sciences of the United States of America , 1989 , 86 ( 13 ): 5207 - 5211 .

Zhao Y Y , Gao H F , Yu L , et al . Versatile heavy metal ion separation via biological ion-channel-inspired membranes [J ] . Nature Nanotechnology , 2026 , 21 ( 5 ): 680 - 688 .

Marbach S , Bocquet L . Osmosis, from molecular insights to large-scale applications [J ] . Chemical Society Reviews , 2019 , 48 ( 11 ): 3102 - 3144 .

Marbach S , Yoshida H , Bocquet L . Osmotic and diffusio-osmotic flow generation at high solute concentration. I. Mechanical approaches [J ] . The Journal of Chemical Physics , 2017 , 146 ( 19 ): 194701 .

Siria A , Poncharal P , Biance A L , et al . Giant osmotic energy conversion measured in a single transmembrane boron nitride nanotube [J ] . Nature , 2013 , 494 ( 7438 ): 455 - 458 .

Siria A , Bocquet M L , Bocquet L . New avenues for the large-scale harvesting of blue energy [J ] . Nature Reviews Chemistry , 2017 , 1 : 91 .

Pan S F , Li Q , Fu Q Q , et al . Defect-tolerant and scalable diffusio–osmotic power generation with sulfonated covalent organic framework membrane [J ] . Angewandte Chemie International Edition , 2025 , 64 ( 49 ): e202514637 .

Liang X , Wu H , Huang H L , et al . Efficient ethylene/ethane separation through ionic liquid-confined covalent organic framework membranes [J ] . Journal of Materials Chemistry A , 2022 , 10 ( 10 ): 5420 - 5429 .

Jiang H F , Chen Y , Song S Q , et al . Confined facilitated transport within covalent organic frameworks for propylene/propane membrane separation [J ] . Chemical Engineering Journal , 2022 , 439 : 135657 .

Ren Y X , Chong B Y , Xu W , et al . Coordination-driven structure reconstruction in polymer of intrinsic microporosity membranes for efficient propylene/propane separation [J ] . The Innovation , 2022 , 3 ( 6 ): 100334 .

Chen B W C , O’Brien C P . Highly selective propylene/propane separation using amine-modified PIM-1 (PIM-NH2) [J ] . Journal of Membrane Science , 2025 , 731 : 124229 .

Ying Y P , Tong M M , Ning S C , et al . Ultrathin two-dimensional membranes assembled by ionic covalent organic nanosheets with reduced apertures for gas separation [J ] . Journal of the American Chemical Society , 2020 , 142 ( 9 ): 4472 - 4480 .

Ma Y , Cui F C , Rong H Z , et al . Continuous porous aromatic framework membranes with modifiable sites for optimized gas separation [J ] . Angewandte Chemie International Edition , 2022 , 61 : e202113682 .

Sun Q , Du J C , Yao A Y , et al . Tunable hydrated channels in covalent organic framework membrane for seawater desalination [J ] . ACS Nano , 2025 , 19 ( 19 ): 18409 - 18420 .

Wang M D , Zhang P H , Liang X , et al . Ultrafast seawater desalination with covalent organic framework membranes [J ] . Nature Sustainability , 2022 , 5 ( 6 ): 518 - 526 .

Zhou Y Q , Hu G S , Yuan J S , et al . Ultramicroporous covalent organic framework membranes with fortified hydrogen-bond networks for high-performance desalination [J ] . Nature Communications , 2026 , 17 : 3272 .

Shi X S , Zhang Z P , Yin C C , et al . Design of three-dimensional covalent organic framework membranes for fast and robust organic solvent nanofiltration [J ] . Angewandte Chemie International Edition , 2022 , 61 ( 36 ): e202207559 .

Wang R , Shi X S , Xiao A K , et al . Interfacial polymerization of covalent organic frameworks (COFs) on polymeric substrates for molecular separations [J ] . Journal of Membrane Science , 2018 , 566 : 197 - 204 .

Yin C C , Wang Y . Ordering covalent–organic frameworks toward next-generation nanofiltration [J ] . Accounts of Chemical Research , 2026 , 59 ( 5 ): 617 - 629 .

Huang D S , Wang Y , Tang Y , et al . Embedding a self-supporting MOF-based molecular sieve membrane into an electrolyzer for boosting electroreduction of CO 2 in air and flue gas to HCOOH [J ] . National Science Review , 2025 , 12 ( 10 ): nwaf329 .

Dong X , Zhu S Y , Pang X , et al . Proton exchange membranes from microemulsion-synthesized COF nanosheets for water electrolysis [J ] . Angewandte Chemie International Edition , 2026 , 65 ( 11 ): e3468299 .

Zou W H , Tang G G , Peng K , et al . Quinuclidinium-based microporous anion exchange membranes for water electrolysis [J ] . Angewandte Chemie , 2025 , 137 ( 45 ): e202514264 .

Zhu L Y , Cao Y , Xu T , et al . Covalent organic framework membranes for energy storage and conversion [J ] . Energy & Environmental Science , 2025 , 18 ( 12 ): 5675 - 5739 .

Chen X , Liu J Y , Li W M , et al . Permselective covalent organic framework membrane as self-extinguishing separator for high-safety lithium-ion battery [J ] . Angewandte Chemie International Edition , 2025 , 64 ( 48 ): e202512591 .

Cao L , Wu H , Cao Y , et al . Weakly humidity-dependent proton-conducting COF membranes [J ] . Advanced Materials , 2020 , 32 ( 52 ): 2005565 .

Shi B B , Pang X , Li S N , et al . Short hydrogen-bond network confined on COF surfaces enables ultrahigh proton conductivity [J ] . Nature Communications , 2022 , 13 : 6666 .

Tan R , Wang A Q , Malpass-Evans R , et al . Hydrophilic microporous membranes for selective ion separation and flow-battery energy storage [J ] . Nature Materials , 2020 , 19 ( 2 ): 195 - 202 .

Zuo P P , Ye C C , Jiao Z R , et al . Near-frictionless ion transport within triazine framework membranes [J ] . Nature , 2023 , 617 ( 7960 ): 299 - 305 .

Wei S Y , Pan W C , Liu J , et al . High-performance perovskite solar cells via 3D covalent organic frameworks: enhanced efficiency through precision interface engineering [J ] . Angewandte Chemie International Edition , 2025 , 64 ( 28 ): e202500163 .

Jiang W X , Zhou J L , Zhong X W , et al . Axial alignment of covalent organic framework membranes for giant osmotic energy harvesting [J ] . Nature Sustainability , 2025 , 8 ( 4 ): 446 - 455 .

Bao S W , Ma Z Y , Yu L , et al . Randomly oriented covalent organic framework membrane for selective Li+ sieving from other ions [J ] . Nature Communications , 2025 , 16 : 3896 .

Liu Q H , Liu M , Zhang Z , et al . Covalent organic framework membranes with vertically aligned nanorods for efficient separation of rare metal ions [J ] . Nature Communications , 2024 , 15 : 9221 .

Hao Y X , Gao Q F , Mao X N , et al . Interlayer-bridged dual-channel 2D MOF membranes for ultra-stable ion sieving in extreme environments [J ] . Chemical Science , 2025 , 16 ( 45 ): 21346 - 21358 .

Gao B J , Gong Y X , Zhang Z , et al . Turing-structured covalent organic framework membranes for fast and precise peptide separations [J ] . Angewandte Chemie , 2025 , 137 ( 28 ): e202503090 .

Xu T , Cao L , An S H , et al . A homochiral covalent organic framework membrane for the enantioseparation and fractionation of amino acids [J ] . Nature Communications , 2025 , 16 : 7803 .

Xu J H , Zhang J Y , Zhang W M , et al . A chiral MOF membrane for enantioselective amino acid separation [J ] . Chemical Communications , 2025 , 61 ( 44 ): 8015 - 8018 .

Abejón R , Garea A , Irabien A . Ultrapurification of hydrogen peroxide solution from ionic metals impurities to semiconductor grade by reverse osmosis [J ] . Separation and Purification Technology , 2010 , 76 ( 1 ): 44 - 51 .

Miao X Y , Zhang J , Shi J J , et al . Synthesis of UiO-66-NH2@PSF hollow fiber membrane with enhanced simultaneous adsorption of Pb 2+ and phosphate for hydrogen peroxide purification [J ] . ACS Applied Materials & Interfaces , 2025 , 17( 5 ) 8537 - 8549 .

Jin E Q , Asada M , Xu Q , et al . Two-dimensional sp 2 carbon–conjugated covalent organic frameworks [J ] . Science , 2017 , 357 ( 6352 ): 673 - 676 .

Ghouse S , Guo Z A , Gámez-Valenzuela S , et al . Towards single-crystalline two-dimensional poly(arylene vinylene) covalent organic frameworks [J ] . Nature Chemistry , 2026 , 18 ( 5 ): 853 - 862 .

Yang H , Zhang H Y , Kang C J , et al . Solvent-responsive covalent organic framework membranes for precise and tunable molecular sieving [J ] . Science Advances , 2024 , 10 ( 51 ): eads0260 .

Shi X S , Li H , Chen T , et al . Precise separation of complex ultrafine molecules through solvating two-dimensional covalent organic framework membranes [J ] . Angewandte Chemie International Edition , 2025 , 64 ( 11 ): e202421661 .

Cook M , Gaffney P R J , Peeva L G , et al . Roll-to-roll dip coating of three different PIMs for Organic Solvent Nanofiltration [J ] . Journal of Membrane Science , 2018 , 558 : 52 - 63 .

Fritsch D , Merten P , Heinrich K , et al . High performance organic solvent nanofiltration membranes: Development and thorough testing of thin film composite membranes made of polymers of intrinsic microporosity (PIMs) [J ] . Journal of Membrane Science , 2012 , 401 : 222 - 231 .

Thompson K A , Mathias R , Kim D , et al . N-Aryl: linked spirocyclic polymers for membrane separations of complex hydrocarbon mixtures [J ] . Science , 2020 , 369 ( 6501 ): 310 - 315 .

Jue M L , Breedveld V , Lively R P . Defect-free PIM-1 hollow fiber membranes [J ] . Journal of Membrane Science , 2017 , 530 : 33 - 41 .

Yu M , Foster A B , Kentish S E , et al . Recent progress in thin film composite membranes based on the polymer of intrinsic microporosity PIM-1: Preparation, properties and performance [J ] . Journal of Membrane Science , 2025 , 722 : 123844 .

Dey K , Pal M , Rout K C , et al . Selective molecular separation by interfacially crystallized covalent organic framework thin films [J ] . Journal of the American Chemical Society , 2017 , 139 ( 37 ): 13083 - 13091 .

Ying Y P , Peh S B , Yang H , et al . Ultrathin covalent organic framework membranes via a multi-interfacial engineering strategy for gas separation [J ] . Advanced Materials , 2022 , 34 ( 25 ): 2104946 .

Pan Y , Yu G Q , Gao L T , et al . Ultra-rapid preparation of large-area high-crystallinity covalent organic framework membranes [J ] . Nature Communications , 2026 , 17 : 857 .

Wang R , Ding L , Xue J , et al . Green and large-scale production of covalent organic framework nanofiltration membranes [J ] . Communications Materials , 2025 , 6 : 61 .

李向凯 , 梁芷晴 , 韦修源 , 等 . COF/6FDA-ODA混合基质膜的制备及气体分离性能研究 [J ] . 功能材料 . 2025 , 56 ( 12 ): 12116 - 12121 .

Li X K , Liang Z Q , Wei X Y , et al . Preparation of COF/6FDA-ODA mixed matrix membrane and its gas separation performance [J ] . Journal of Functional Materials . 2025 , 56 ( 12 ): 12116 - 12121 .

叶诗洋 , 程敏 , 吉旭 ， 等 . 高性能COF材料的高通量筛选策略：己烷异构体分离 [J ] . 化工学报 , 2022 , 73 ( 11 ): 5138 - 5149 .

Ye S Y , Cheng M , Ji X , et al . High-throughput computational screening strategy for high-performance COF materials: separation of hexane isomers [J ] . CIESC Journal , 2022 , 73 ( 11 ): 5138 - 5149 .

Cao L , Liu X W , Shinde D B , et al . Oriented two-dimensional covalent organic framework membranes with high ion flux and smart gating nanofluidic transport [J ] . Angewandte Chemie , 2022 , 134 ( 6 ): e202113141 .

Zhai L Y , Gao S Q , Guo L L , et al . Highly efficient light-gated COF membrane for precise multistage molecular separation [J ] . Science Advances , 2026 , 12 ( 11 ): eadz1929 .

Jia Y W , Du J G , Lu Y Q , et al . Voltage-controlled organic solvent nanofiltration using conjugated microporous polymer membranes [J ] . Nature Communications , 2026 , 17 : 236 .

Morth J P , Pedersen B P , Toustrup-Jensen M S , et al . Crystal structure of the sodium–potassium pump [J ] . Nature , 2007 , 450 ( 7172 ): 1043 - 1049 .

Xian W P , Xu X Y , Ge Y X , et al . Efficient light-driven ion pumping for deep desalination via the vertical gradient protonation of covalent organic framework membranes [J ] . Journal of the American Chemical Society , 2024 , 146 ( 49 ): 33973 - 33982 .

Jiang X Y , Zhang Q X , Zhao N J , et al . 2D conjugated metal–organic framework-based composite membranes for nanofluidic ionic photoelectric conversion [J ] . Advanced Materials , 2025 , 37 ( 12 ): 2416093 .

王苗苗 , 曹蕴青 , 武鹏超 , 等 . 二维超薄聚合物基纳米片的制备与光响应行为研究 [J ] . 高分子学报 , 2026 , 57 ( 3 ): 776 - 785 .

Wang M M , Cao Y Q , Wu , P C , et al . Fabrication and photo-responsive behavior of two-dimensional ultrathin polymeric nanosheets [J ] . Acta Polymerica Sinica (in Chinese) , 2026 , 57 ( 3 ): 776 - 785 .