煤临氢加压热解研究进展

王志恒; 肖幸幸; 闻育新; 靳立军; 杨赫; 李扬; 胡浩权

doi:10.11949/0438-1157.20260523

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煤临氢加压热解研究进展

综述与专论 | 更新时间：2026-10-14

- 煤临氢加压热解研究进展
- Research progress on pressurized hydropyrolysis of coal
- 化工学报 2026年77卷第9期页码：5034-5055
- 作者机构：
  
  大连理工大学化工学院，煤化工研究设计所，精细化工全国重点实验室，辽宁大连116024
- 作者简介：
  
  王志恒（2001—），男，博士研究生，wangzhiheng@mail.dlut.edu.cn
  胡浩权（1961—），男，博士，教授，hhu@dlut.edu.cn
- 基金信息：
  
  国家重点研发计划项目(2023YFB4103801);新疆维吾尔自治区重大科技专项(2024A01007-1)
- DOI：10.11949/0438-1157.20260523
  中图分类号： TQ 530.2
- 收稿：2026-04-14，
  
  修回：2026-07-08，
  
  纸质出版：2026-09-25
- 稿件说明：
移动端阅览
王志恒, 肖幸幸, 闻育新, 靳立军, 杨赫, 李扬, 胡浩权. 煤临氢加压热解研究进展[J]. 化工学报, 2026, 77(9): 5034-5055

WANG Zhiheng, XIAO Xingxing, WEN Yuxin, JIN Lijun, YANG He, LI Yang, HU Haoquan. Research progress on pressurized hydropyrolysis of coal[J]. CIESC Journal, 2026, 77(9): 5034-5055
王志恒, 肖幸幸, 闻育新, 靳立军, 杨赫, 李扬, 胡浩权. 煤临氢加压热解研究进展[J]. 化工学报, 2026, 77(9): 5034-5055 DOI： 10.11949/0438-1157.20260523.

WANG Zhiheng, XIAO Xingxing, WEN Yuxin, JIN Lijun, YANG He, LI Yang, HU Haoquan. Research progress on pressurized hydropyrolysis of coal[J]. CIESC Journal, 2026, 77(9): 5034-5055 DOI： 10.11949/0438-1157.20260523.

摘要

在“双碳”目标和我国“富煤贫油少气”的能源资源禀赋背景下，热解是实现低阶煤分质转化与高值利用的重要途径，尤其是加氢热解被认为是最有效提高热解焦油产率和品质的方法，受到广泛关注。本文围绕煤加氢热解的发展历程、反应机理及其影响因素进行系统综述，介绍煤加氢热解的基本概念及研究进展，总结煤加氢热解机理，分析惰性气氛压力作用下挥发分迁移受限与二次反应程度增强之间的关系，进一步讨论不同富氢气氛与压力对煤加氢热解的耦合作用，阐述煤阶和反应器类型对煤临氢加压热解压力窗口的影响。最后，对目前煤临氢加压热解研究存在的问题及今后发展方向进行展望。

Abstract

Under the backdrop of the "dual carbon" target and China's energy resource endowment of "rich coal

poor oil

and scarce gas". pyrolysis is an important pathway to achieve the graded conversion and high-value utilization of low-rank coal. Hydropyrolysis

in particular

is considered the most effective method to improve the yield and quality of pyrolysis tar and has attracted widespread attention. This paper systematically reviewed the development history

reaction mechanisms

and influencing factors of coal pressurized hydropyrolysis. The basic concept and development history of coal hydropyrolysis were introduced

and the research progress on its reaction mechanisms was summarized. Then

the correlations between the restricted volatile release and enhanced secondary reactions under a pressurized inert atmosphere were analyzed

and the coupled effects of different hydrogen-rich atmospheres and pressure on coal pressurized hydropyrolysis were further discussed. The effects of coal rank and reactor type on the pressure window for coal pressurized hydropyrolysis were explained. Finally

the challenges and future research directions in coal pressurized hydropyrolysis were proposed.

关键词

Keywords

references

谢克昌 . 新型能源体系发展思考与建议 [J ] . 中国工程科学 , 2024 , 26 ( 4 ): 1 - 8 .

Xie K C . Strategic thinking and suggestions on new energy system [J ] . Strategic Study of CAE , 2024 , 26 ( 4 ): 1 - 8 .

Dong X C , Gong Q , Li Y , et al . The process and trends of China's energy transition and the strategic repositioning of natural gas [J ] . Natural Gas Industry B , 2025 , 12 ( 6 ): 750 - 765 .

Dong K Y , Sun R J , Li H , et al . A review of China's energy consumption structure and outlook based on a long-range energy alternatives modeling tool [J ] . Petroleum Science , 2017 , 14 ( 1 ): 214 - 227 .

谢克昌 . 新型能源体系发展背景下煤炭清洁高效转化的挑战及途径 [J ] . 煤炭学报 , 2024 , 49 ( 1 ): 47 - 56 .

Xie K C . Develop new energy system and promote clean and efficient conversion of coal [J ] . Journal of China Coal Society , 2024 , 49 ( 1 ): 47 - 56 .

Xue F F , Li D , Guo Y T , et al . Technical progress and the prospect of low-rank coal pyrolysis in China [J ] . Energy Technology , 2017 , 5 ( 11 ): 1897 - 1907 .

Solomon P R , Serio M A , Suuberg E M . Coal pyrolysis: experiments, kinetic rates and mechanisms [J ] . Progress in Energy and Combustion Science , 1992 , 18 ( 2 ): 133 - 220 .

Arenillas A , Rubiera F , Pis J J . Simultaneous thermogravimetric-mass spectrometric study on the pyrolysis behaviour of different rank coals [J ] . Journal of Analytical and Applied Pyrolysis , 1999 , 50 ( 1 ): 31 - 46 .

van Krevelen D W . Coal: Typology-Physics-Chemistry-Constitution [M ] . Amsterdam : Elsevier , 1993 .

Han Z N , Jia X , Song X F , et al . Engineering thermochemistry to cope with challenges in carbon neutrality [J ] . Journal of Cleaner Production , 2023 , 416 : 137943 .

Zhang S L , Wang F , Zhao F T , et al . Liquid fuel production via catalytic hydropyrolysis and cohydropyrolysis of agricultural residues and used engine oil [J ] . Journal of Analytical and Applied Pyrolysis , 2021 , 154 : 104988 .

Wiatowski M , Basa W , Pankiewicz-Sperka M , et al . Experimental study on tar formation during underground coal gasification: effect of coal rank and gasification pressure on tar yield and chemical composition [J ] . Fuel , 2024 , 357 : 130034 .

Lv T , Fang M X , Li H X , et al . Pyrolysis of a typical low-rank coal: application and modification of the chemical percolation devolatilization model [J ] . RSC Advances , 2021 , 11 ( 29 ): 17993 - 18002 .

Zhu W K , Song W L , Lin W G . Effect of the coal particle size on pyrolysis and char reactivity for two types of coal and demineralized coal [J ] . Energy & Fuels , 2008 , 22 ( 4 ): 2482 - 2487 .

Fu Z P , Qiu L L , Huang Y B , et al . Pyrolysis behaviors of lump sub-bituminous coal (Part 2): Effect of particle size [J ] . Fuel , 2026 , 405 : 136724 .

Hanson S , Patrick J W , Walker A . The effect of coal particle size on pyrolysis and steam gasification [J ] . Fuel , 2002 , 81 ( 5 ): 531 - 537 .

Xu K , Hu S , Zhang L P , et al . Effect of temperature on Shenfu coal pyrolysis process related to its chemical structure transformation [J ] . Fuel Processing Technology , 2021 , 213 : 106662 .

Chen J H , Li J , Li Y , et al . Study on lightening of coal tar with metal oxide supported γ-Al 2 O 3 catalyst [J ] . Scientific Reports , 2023 , 13 : 18366 .

Ning X , Huang X L , Xue X Y , et al . Experimental study on yield and quality of tar from tar-rich coal under the simulated in-situ conditions [J ] . Journal of the Energy Institute , 2025 , 118 : 101912 .

Zheng X Y , Wang F , Wang J J , et al . Study on the influence of particle size and heating rate on pyrolysis characteristics and kinetics of Xinjiang high-chlorine coal [J ] . Fuel Processing Technology , 2025 , 280 : 108376 .

Luo C H , Nakamura M , Toyoda M , et al . Influence of heating rate during pyrolysis on gasification reactivity of coal chars at high temperatures [J ] . Journal of the Japan Institute of Energy , 2000 , 79 ( 11 ): 1078 - 1087 .

Gu C K , Jin J , Li Y , et al . Effects of CO 2 atmosphere on low-rank coal pyrolysis based on ReaxFF molecular dynamics [J ] . RSC Advances , 2023 , 13 ( 3 ): 1935 - 1942 .

Ma C , Wang R Y , Zhao Y Z , et al . Pyrolysis of low-rank coal under a CH 4 -rich atmosphere and combustion characteristics of derived char [J ] . Thermal Science and Engineering Progress , 2026 , 70 : 104512 .

Wu Y N , Tao S , Wang Z H , et al . Effect of pyrolysis atmospheres on gaseous products evolution of coal pyrolysis at high temperature [J ] . Fuel , 2024 , 366 : 131336 .

Wu F J , Huang S Y , Jiang Q , et al . Effects of pressure and heating rate on coal pyrolysis: a study in simulated underground coal gasification [J ] . Journal of Analytical and Applied Pyrolysis , 2023 , 175 : 106179 .

Zhang W D , Zhao Y J , Sun S Z , et al . Effects of pressure on the characteristics of bituminous coal pyrolysis char formed in a pressurized drop tube furnace [J ] . Energy & Fuels , 2019 , 33 ( 12 ): 12219 - 12226 .

Ko G H , Peters W A , Howard J B . Correlation of tar yields from rapid pyrolysis with coal type and pressure [J ] . Fuel , 1987 , 66 ( 8 ): 1118 - 1122 .

Xu W C , Tomita A . The effects of temperature and residence time on the secondary reactions of volatiles from coal pyrolysis [J ] . Fuel Processing Technology , 1989 , 21 ( 1 ): 25 - 37 .

敦启孟 , 陈兆辉 , 皇甫林 , 等 . 温度和停留时间对煤热解挥发分二次反应的影响 [J ] . 过程工程学报 , 2018 , 18 ( 1 ): 140 - 147 .

Dun Q M , Chen Z H , Huangfu L , et al . Influences of temperature and residence time on secondary reactions of volatiles from coal pyrolysis [J ] . The Chinese Journal of Process Engineering , 2018 , 18 ( 1 ): 140 - 147 .

杨盼曦 , 郭伟 , 俞尊义 , 等 . 基于二次反应修正的富油煤快速热解过程模拟 [J ] . 煤炭学报 , 2025 , 50 ( 8 ): 4066 - 4078 .

Yang P X , Guo W , Yu Z Y , et al . Simulation of fast pyrolysis process of tar-rich coal based on secondary reaction supplementation [J ] . Journal of China Coal Society , 2025 , 50 ( 8 ): 4066 - 4078 .

Qian Y N , Zhan J H , Yu Y , et al . CFD model of coal pyrolysis in fixed bed reactor [J ] . Chemical Engineering Science , 2019 , 200 : 1 - 11 .

Gao L , Wu L , Paterson N , et al . The use of wire mesh reactors to characterise solid fuels and provide improved understanding of larger scale thermochemical processes [J ] . International Journal of Oil, Gas and Coal Technology , 2008 , 1 ( 1/2 ): 152 .

Hindmarsh C J , Thomas K M , Wang W X , et al . A comparison of the pyrolysis of coal in wire-mesh and entrained-flow reactors [J ] . Fuel , 1995 , 74 ( 8 ): 1185 - 1190 .

Huang J J , Fang Y T , Chen H S , et al . Coal gasification characteristic in a pressurized fluidized bed [J ] . Energy & Fuels , 2003 , 17 ( 6 ): 1474 - 1479 .

Reichel D , Siegl S , Neubert C , et al . Determination of pyrolysis behavior of brown coal in a pressurized drop tube reactor [J ] . Fuel , 2015 , 158 : 983 - 998 .

Chen Z H , Gao S Q , Xu G W . Simultaneous production of CH 4 -rich syngas and high-quality tar from lignite by the coupling of noncatalytic/catalytic pyrolysis and gasification in a pressurized integrated fluidized bed [J ] . Applied Energy , 2017 , 208 : 1527 - 1537 .

Cypres , R , Mingels , W , Lardinois , J P , et al . Feasibility study of the hydropyrolysis of coal [R ] . Luxembourg : Commission of the European Communities , 1992 .

Dent F J , Blackburn W H , Millett H C . Investigation of the use of oxygen and high pressure in gasification. Part II: Synthesis of gaseous hydrocarbons at high pressure [R ] . London : Institution of Gas Engineers , 1937 .

Schroeder W C . Hydrogenation of Coal [P ] . US Patent 3030297 , 1962-04-17 .

Greene M I . Engineering development of a short residence time, coal hydropyrolysis process [J ] . Fuel Processing Technology , 1978 , 1 ( 3 ): 169 - 185 .

Suuberg E M , Peters W A , Howard J B . Product compositions in rapid hydropyrolysis of coal [J ] . Fuel , 1980 , 59 ( 6 ): 405 - 412 .

Fynes G , Ladner W R , Newman J O H . The hydropyrolysis of coal to BTX [J ] . Progress in Energy and Combustion Science , 1980 , 6 ( 3 ): 223 - 232 .

马智华 , 朱子彬 , 金海华 , 等 . 煤炭快速加氢热解的研究现状及发展方向 [J ] . 现代化工 , 1993 , 13 ( 5 ): 10 - 14 .

Ma Z H , Zhu Z B , Jin H H , et al . Research status quo and development trends of coal flash hydropyrolysis [J ] . Modern Chemical Industry , 1993 , 13 ( 5 ): 10 - 14 .

Howard J B . Fundamentals of coal pyrolysis and hydropyrolysis [M ] // Chemistry of Coal Utilization , 2nd Supplementary Volume. New York , USA; John Wiley & Sons, 1981 : 665 - 784 .

Jüntgen H . Review of the kinetics of pyrolysis and hydropyrolysis in relation to the chemical constitution of coal [J ] . Fuel , 1984 , 63 ( 6 ): 731 - 737 .

Gibbins J , Kandiyoti R . Experimental study of coal pyrolysis and hydropyrolysis at elevated pressures using a variable heating rate wire-mesh apparatus [J ] . Energy & Fuels , 1989 , 3 ( 6 ): 670 - 677 .

Strugnell B , Patrick J W . Rapid hydropyrolysis studies on coal and maceral concentrates [J ] . Fuel , 1996 , 75 ( 3 ): 300 - 306 .

李文 , 郭树才 . 煤的加氢热解 [J ] . 煤炭转化 , 1991 , 14 ( 2 ): 47 - 52 .

Li W , Guo S C . Coal hydropyrolysis [J ] . Coal Conversion , 1991 , 14 ( 2 ): 47 - 52 .

李保庆 . 煤加氢热解研究(Ⅰ)宁夏灵武煤加氢热解的研究 [J ] . 燃料化学学报 , 1995 ( 1 ): 57 - 61 .

Li B Q . Hydropyrolysis of Chinese coals (Ⅰ): Hydropyrolysis of Lingwu bituminous coal [J ] . Journal of Fuel Chemistry and Technology , 1995 ( 1 ): 57 - 61 .

李保庆 . 我国煤加氢热解研究(Ⅱ)先锋褐煤加氢及催化加氢热解的热重研究 [J ] . 燃料化学学报 , 1995 , 23 ( 2 ): 186 - 191 .

Li B Q . Hydropyrolysis of Chinese coals (Ⅱ): Thermogravimetric study on catalytic and non-catalytic hydropyrolysis of Xianfeng lignite [J ] . Journal of Fuel Chemistry and Technology , 1995 , 23 ( 2 ): 186 - 191 .

李保庆 . 我国煤加氢热解研究(Ⅲ)神府煤加氢、催化加氢及H2-CH4气氛下热解的研究 [J ] . 燃料化学学报 , 1995 , 23 ( 2 ): 192 - 197 .

Li B Q . Hydropyrolysis of Chinese coals (Ⅲ): Catalytic and non-catalytic hydropyrolysis and pyrolysis under H 2 -CH 4 of Shenfu bituminous coal [J ] . Journal of Fuel Chemistry and Technology , 1995 , 23 ( 2 ): 192 - 197 .

廖洪强 , 李文 , 孙成功 , 等 . 煤热解富产焦油的工艺评述 [J ] . 煤炭转化 , 1996 , 19 ( 4 ): 18 - 23 .

Liao H Q , Li W , Sun C G , et al . Review on the technology for improving tar yields by pyrolysis of coal [J ] . Coal Conversion , 1996 , 19 ( 4 ): 18 - 23 .

廖洪强 , 李文 , 孙成功 , 等 . 提高煤加氢热解焦油产量的途径分析 [J ] . 化工进展 , 1996 , 15 ( 6 ): 19 - 23 .

Liao H Q , Li W , Sun C G , et al . Analysis on how to improve the tar yield during hydropyrolysis of coal [J ] . Chemical Industry and Engineering Progress , 1996 , 15 ( 6 ): 19 - 23 .

周强 . 煤的热解行为及硫的脱除 [D ] . 大连 : 大连理工大学 , 2004 .

Zhou Q . Behavior of coal and sulfur removal during pyrolysis [D ] . Dalian : Dalian University of Technology , 2004 .

方科学 , 冯浩 , 刘维锐 , 等 . 新奥粉煤加氢热解技术在新疆地区推广的机遇与挑战 [J ] . 煤炭加工与综合利用 , 2026 ( 1 ): 63 - 69 .

Fang K X , Feng H , Liu W R , et al . Opportunities and challenges of promoting ENN's pulverized coal hydro-pyrolysis technology in Xinjiang region [J ] . Coal Processing & Comprehensive Utilization , 2026 ( 1 ): 63 - 69 .

刘振宇 . 煤化学的前沿与挑战: 结构与反应 [J ] . 中国科学: 化学 , 2014 , 44 ( 9 ): 1431 - 1439 .

Liu Z Y . Advancement in coal chemistry: structure and reactivity [J ] . Scientia sinica: Chimica , 2014 , 44 ( 9 ): 1431 - 1439 .

黄世平 . 中国西部弱还原性煤热解与加氢热解性质研究 [D ] . 大连 : 大连理工大学 , 2007 .

Huang S P . Pyrolysis and hydropyrolysis of weak reductive coals [D ] . Dalian : Dalian University of Technology , 2007 .

Anthony D B , Howard J B , Hottel H C , et al . Rapid devolatilization and hydrogasification of bituminous coal [J ] . Fuel , 1976 , 55 ( 2 ): 121 - 128 .

Russell W B , Saville D A , Greene M I . A model for short residence time hydropyrolysis of single coal particles [J ] . AIChE Journal , 1979 , 25 ( 1 ): 65 - 80 .

Niu B , Niu M L , Zhang J T , et al . Novel insight into the mechanism of coal hydropyrolysis using deuterium tracer method [J ] . Fuel , 2022 , 321 : 124109 .

Seebauer V , Petek J , Staudinger G . Effects of particle size, heating rate and pressure on measurement of pyrolysis kinetics by thermogravimetric analysis [J ] . Fuel , 1997 , 76 ( 13 ): 1277 - 1282 .

Kou B Y , Shi Q M , Wang S M , et al . Axial pressure impact on pyrolysis behavior of Xinjiang coal: an inspiration for in - situ pyrolysis of tar-rich coal [J ] . Fuel Processing Technology , 2025 , 267 : 108175 .

Chen M J , Wang C A , Yuan T L , et al . Experimental investigation on gas-liquid-solid tri-phase product distributions during the simulated in - situ pyrolysis of tar-rich coal [J ] . Fuel , 2025 , 381 : 133465 .

Zhu Y , Wang Q H , Li K K , et al . Study on pressurized isothermal pyrolysis characteristics of low-rank coal in a pressurized micro-fluidized bed reaction analyzer [J ] . Energy , 2022 , 240 : 122475 .

Lee C W , Jenkins R G , Schobert H H . Mechanisms and kinetics of rapid, elevated pressure pyrolysis of Illinois No. 6 bituminous coal [J ] . Energy & Fuels , 1991 , 5 ( 4 ): 547 - 555 .

Zeng D , Fletcher T H . Effects of pressure on coal pyrolysis and char morphology [J ] . Energy & Fuels , 2005 , 19 ( 5 ): 1828 - 1838 .

Niksa S , Liu G S , Hurt R H . Coal conversion submodels for design applications at elevated pressures. Part I. Devolatilization and char oxidation [J ] . Progress in Energy and Combustion Science , 2003 , 29 ( 5 ): 425 - 477 .

Hao J Y , Qi B J , Wei J J . Experimental and numerical investigation of in - situ pressurized pyrolysis characteristics of tar-rich coal [J ] . ACS Omega , 2026 , 11 ( 8 ): 13652 - 13666 .

Gong X M , Wang Z , Deng S , et al . Impact of the temperature, pressure, and particle size on tar composition from pyrolysis of three ranks of Chinese coals [J ] . Energy & Fuels , 2014 , 28 ( 8 ): 4942 - 4948 .

Tian H , Guo W , Li Q , et al . High-pressure pyrolysis mechanism of tar-rich coal in Taiyuan formation, Ordos Basin [J ] . Energy , 2025 , 337 : 138675 .

王兴刚 , 焦立新 , 曹志雄 , 等 . 反应温度及压力对三塘湖盆地褐煤热解产物分布影响 [J ] . 洁净煤技术 , 2024 , 30 ( 6 ): 114 - 127 .

Wang X G , Jiao L X , Cao Z X , et al . Effects of reaction temperature and pressure on the distribution of lignite pyrolysis products in Santanghu Basin [J ] . Clean Coal Technology , 2024 , 30 ( 6 ): 114 - 127 .

Sathe C , Hayashi J I , Li C Z . Release of volatiles from the pyrolysis of a Victorian lignite at elevated pressures [J ] . Fuel , 2002 , 81 ( 9 ): 1171 - 1178 .

Zhu Y , Wang Q H , Yan J Q , et al . Influence and action mechanism of pressure on pyrolysis process of a low rank Naomaohu coal at different temperatures [J ] . Journal of Analytical and Applied Pyrolysis , 2022 , 167 : 105682 .

Yang H , Pisupati S V , Hu H Q . Modeling char surface area evolution during coal pyrolysis: effect of swelling and gasification at high pressures [J ] . Proceedings of the Combustion Institute , 2021 , 38 ( 3 ): 4151 - 4159 .

Tomeczek J , Gil S . Volatiles release and porosity evolution during high pressure coal pyrolysis [J ] . Fuel , 2003 , 82 ( 3 ): 285 - 292 .

Luo K , Zhang C , Zhu S H , et al . Tar formation during coal pyrolysis under N 2 and CO 2 atmospheres at elevated pressures [J ] . Journal of Analytical and Applied Pyrolysis , 2016 , 118 : 130 - 135 .

Niu M F , Xin L , Cheng W M , et al . Effects of pressurized pyrolysis on the chemical and porous structure evolution of coal core during deep underground coal gasification [J ] . ACS Omega , 2023 , 8 ( 43 ): 40153 - 40161 .

Roy C , de Caumia B , Kalkreuth W . Vacuum pyrolysis of prince mine coal, nova Scotia, Canada [J ] . Fuel , 1985 , 64 ( 12 ): 1662 - 1666 .

Li C Z , Bartle K D , Kandiyoti R . Vacuum pyrolysis of maceral concentrates in a wire-mesh reactor [J ] . Fuel , 1993 , 72 ( 11 ): 1459 - 1468 .

Cheng S , Lai D G , Shi Z , et al . Suppressing secondary reactions of coal pyrolysis by reducing pressure and mounting internals in fixed-bed reactor [J ] . Chinese Journal of Chemical Engineering , 2017 , 25 ( 4 ): 507 - 515 .

常娜 , 陈延信 , 甘艳萍 . 微负压系统中不同粒径煤粉热解半焦特性研究 [J ] . 煤炭转化 , 2014 , 37 ( 1 ): 65 - 68 .

Chang N , Chen Y X , Gan Y P . Characteristics study on semicoke from coal fast pyrolysis with different particle size under micro-negative pressure [J ] . Coal Conversion , 2014 , 37 ( 1 ): 65 - 68 .

Arendt P , van Heek K H . Comparative investigations of coal pyrolysis under inert gas and H 2 at low and high heating rates and pressures up to 10 MPa [J ] . Fuel , 1981 , 60 ( 9 ): 779 - 787 .

Xu W C , Matsuoka K , Akiho H , et al . High pressure hydropyrolysis of coals by using a continuous free-fall reactor [J ] . Fuel , 2003 , 82 ( 6 ): 677 - 685 .

Bolton C , Snape C E , O'Brien R J , et al . Influence of carrier gas flow and heating rates in fixed bed hydropyrolysis of coal [J ] . Fuel , 1987 , 66 ( 10 ): 1413 - 1417 .

Guell A J , Kandiyoti R . Development of a gas-sweep facility for the direct capture of pyrolysis tars in a variable heating rate high-pressure wire-mesh reactor [J ] . Energy & Fuels , 1993 , 7 ( 6 ): 943 - 952 .

管清亮 , 毕大鹏 , 玄伟伟 , 等 . 氢气压力对煤加氢反应影响的热重-气相色谱实验研究 [J ] . 燃料化学学报 , 2015 , 43 ( 8 ): 914 - 922 .

Guan Q L , Bi D P , Xuan W W , et al . Thermogravimetric-gas chromatographic study on effects of hydrogen pressure on coal hydrogenation [J ] . Journal of Fuel Chemistry and Technology , 2015 , 43 ( 8 ): 914 - 922 .

高松平 , 王建飞 , 赵建涛 , 等 . H 2 气氛下褐煤快速热解过程中CH 4 逸出规律的分析 [J ] . 燃料化学学报 , 2015 , 43 ( 5 ): 537 - 545 .

Gao S P , Wang J F , Zhao J T , et al . Analysis of CH 4 evolution in fast pyrolysis of lignite under H 2 atmosphere [J ] . Journal of Fuel Chemistry and Technology , 2015 , 43 ( 5 ): 537 - 545 .

Karcz A , Porada S . Formation of C 1 —C 3 hydrocarbons during pressure pyrolysis and hydrogasification in relation to structural changes in coal [J ] . Fuel , 1995 , 74 ( 6 ): 806 - 809 .

Karcz A , Porada S . Kinetics of the formation of C 1 —C 3 hydrocarbons in pressure pyrolysis of coal [J ] . Fuel Processing Technology , 1990 , 26 ( 1 ): 1 - 13 .

Hong B Q , Wang X J , Zhou Z J , et al . A comparison of the gas-product-release characteristics from coal pyrolysis and hydrogasification [J ] . Energy Technology , 2013 , 1 ( 8 ): 449 - 456 .

Cyprès R , Furfari S . Fixed-bed pyrolysis of coal under hydrogen pressure at low heating rates [J ] . Fuel , 1981 , 60 ( 9 ): 768 - 778 .

刘学智 , 逄进 . 甘肃天祝煤加压热解焦油组成与性质的研究 [J ] . 煤炭转化 , 1994 , 17 ( 1 ): 82 - 88 .

Liu X Z , Pang J . Study on the tar structure and nature of pressurized pyrolysis for Tianzhu coal in Gansu [J ] . Coal Conversion , 1994 , 17 ( 1 ): 82 - 88 .

金海华 , 朱子彬 , 马智华 , 等 . 煤快速热解获得液态烃和气态烃的研究(Ⅱ)热解温度和压力的考察 [J ] . 化工学报 , 1992 , 43 ( 6 ): 726 - 732 .

Jin H H , Zhu Z B , Ma Z H , et al . Flash pyrolysis of brown coal for obtaining liquid and gaseous hydrocarbons (Ⅱ): Flash hydropyrolysis conditions effect of temperature and pressure [J ] . Journal of Chemical Industry and Engineering (China) , 1992 , 43 ( 6 ): 726 - 732 .

朱国荣 , 胡东海 , 曹国强 , 等 . 准东煤加氢热解反应特性研究 [J ] . 煤炭转化 , 2025 , 48 ( 6 ): 41 - 52 .

Zhu G R , Hu D H , Cao G Q , et al . Reaction charactistics of Zhundong coal during hydropyrolysis [J ] . Coal Conversion , 2025 , 48 ( 6 ): 41 - 52 .

郭二光 , 王贵金 , 陈佳奇 , 等 . 淖毛湖煤加氢热解产物特性及半焦气化反应性研究 [J ] . 洁净煤技术 , 2024 , 30 ( 4 ): 196 - 204 .

Guo E G , Wang G J , Chen J Q , et al . Products characteristics and char gasification reactivity of Naomaohu coal hydropyrolysis [J ] . Clean Coal Technology , 2024 , 30 ( 4 ): 196 - 204 .

Noor N S , Gaines A F , Abbott J M . Pyrolysis of Manvers coal in an atmosphere of deuterium [J ] . Fuel , 1986 , 65 ( 1 ): 67 - 74 .

Miura K , Mae K , Nakagawa H , et al . Measurement of the amount of hydrogen transferred during flash hydropyrolysis of coal and solvent swollen coal for examining hydrogen transfer mechanism [J ] . Journal of the Japan Institute of Energy , 1992 , 71 ( 2 ): 107 - 115 .

Sutrisna I P , Ishihara A , Qian W H , et al . Elucidation of hydrogen behavior in coal using a tritium tracer method: hydrogen transfer reaction of coal with tritiated gaseous hydrogen in a flow reactor [J ] . Energy & Fuels , 2001 , 15 ( 5 ): 1129 - 1138 .

Yabe H , Kawamura T , Kozuru H , et al . Development of coal partial hydropyrolysis process [C ] //Nippon Steel Technical Report, 2005 ( 92 ): 8 - 15 .

张君涛 , 石润坤 , 牛犇 , 等 . CH 4 气氛在煤中低温热解阶段对焦油产率和品质的影响 [J ] . 煤炭学报 , 2021 , 46 ( 1 ): 292 - 299 .

Zhang J T , Shi R K , Niu B , et al . Effect of CH 4 atmosphere on tar yield and quality in coal pyrolysis at low-medium pyrolysis temperature [J ] . Journal of China Coal Society , 2021 , 46 ( 1 ): 292 - 299 .

靳立军 , 李扬 , 胡浩权 . 甲烷活化与煤热解耦合过程提高焦油产率研究进展 [J ] . 化工学报 , 2017 , 68 ( 10 ): 3669 - 3677 .

Jin L J , Li Y , Hu H Q . Research progress of integrated methane activation with coal pyrolysis for improving coal tar yield [J ] . CIESC Journal , 2017 , 68 ( 10 ): 3669 - 3677 .

靳立军 , 刘铮铮 , 李扬 , 等 . 耦合富氢小分子催化活化的煤热解提高焦油产率策略与实践 [J ] . 化工进展 , 2024 , 43 ( 7 ): 3613 - 3619 .

Jin L J , Liu Z Z , Li Y , et al . Strategy and its application to improve tar yield by coupling catalytic activation of H-rich small molecule with coal pyrolysis [J ] . Chemical Industry and Engineering Progress , 2024 , 43 ( 7 ): 3613 - 3619 .

刘全润 . 煤的热解转化和脱硫研究 [D ] . 大连 : 大连理工大学 , 2006 .

Liu Q R . Coal conversion and desulfurization during pyrolysis [D ] . Dalian : Dalian University of Technology , 2006 .

廖洪强 , 李保庆 , 张碧江 , 等 . 煤-焦炉气共热解特性研究(Ⅳ)甲烷和一氧化碳对热解的影响 [J ] . 燃料化学学报 , 1998 , 26 ( 1 ): 13 - 17 .

Liao H Q , Li B Q , Zhang B J , et al . Copyrolysis of coal with coke-oven gas (Ⅳ): Influence of CH 4 and CO on pyrolysis yields [J ] . Journal of Fuel Chemistry and Technology , 1998 , 26 ( 1 ): 13 - 17 .

廖洪强 , 孙成功 , 李保庆 , 等 . 煤-焦炉气共热解特性研究(Ⅲ)热解焦油分析 [J ] . 燃料化学学报 , 1998 ( 1 ): 7 - 12 .

Liao H Q , Sun C G , Li B Q . Copyrolysis of coal with coke-oven gas(Ⅲ): Analysis of tar [J ] . Journal of Fuel Chemistry and Technology , 1998 ( 1 ): 7 - 12 .

郭二光 . 淖毛湖煤加氢热解产物特性及半焦气化反应性研究 [D ] . 大连 : 大连理工大学 , 2023 .

Guo E G . Product characteristics and char gasification reactivity of Naomaohu coal hydropyrolysis [D ] . Dalian : Dalian University of Technology , 2023 .

Sharma D K , Sulimma A , van Heek K H . Hydropyrolysis of coal in the presence of steam [J ] . Fuel , 1986 , 65 ( 11 ): 1571 - 1574 .

张永 , 曲旋 , 张荣 , 等 . 反应气氛对碳酸钾催化煤加压热解特性的影响 [J ] . 煤炭转化 , 2018 , 41 ( 1 ): 19 - 26 .

Zhang Y , Qu X , Zhang R , et al . Effects of atmospheres on K 2 CO 3 catalytic pressurized pyrolysis of coal [J ] . Coal Conversion , 2018 , 41 ( 1 ): 19 - 26 .

黄勇 , 刘丹 , 刘巧霞 , 等 . 西湾煤焦在加压条件下的气化反应特性研究 [J ] . 煤炭转化 , 2024 , 47 ( 6 ): 46 - 56 .

Huang Y , Liu D , Liu Q X , et al . Study on pressurized gasification reaction characteristics of Xiwan coal char [J ] . Coal Conversion , 2024 , 47 ( 6 ): 46 - 56 .

Gao S P , Zhai L R , Qin Y H , et al . Investigation into the cleavage of chemical bonds induced by CO 2 and its mechanism during the pressurized pyrolysis of coal [J ] . Energy & Fuels , 2018 , 32 ( 3 ): 3243 - 3253 .

Liu Q X , He L , Huang Y , et al . Pyrolysis characteristics of low-rank coal in pressurized fluidized bed under different atmospheres [J ] . Journal of Analytical and Applied Pyrolysis , 2025 , 191 : 107218 .

王宁波 , 黄勇 , 刘巧霞 , 等 . 热解条件对西湾煤流化床加压热解的影响 [J ] . 煤炭转化 , 2021 , 44 ( 6 ): 34 - 43 .

Wang N B , Huang Y , Liu Q X , et al . Effects of pyrolysis conditions on pressurized pyrolysis of Xiwan coal in fluidized bed [J ] . Coal Conversion , 2021 , 44 ( 6 ): 34 - 43 .

高松平 , 王建飞 , 赵建涛 , 等 . CO气氛下褐煤加压快速热解过程中CH 4 的逸出规律 [J ] . 燃料化学学报 , 2014 , 42 ( 6 ): 641 - 649 .

Gao S P , Wang J F , Zhao J T , et al . CH 4 release character from pressurized fast pyrolysis of lignite in CO atmosphere [J ] . Journal of Fuel Chemistry and Technology , 2014 , 42 ( 6 ): 641 - 649 .

Fidalgo B , van Niekerk D , Millan M . The effect of syngas on tar quality and quantity in pyrolysis of a typical South African inertinite-rich coal [J ] . Fuel , 2014 , 134 : 90 - 96 .

Braekman-Danheux C , Cyprès R , Fontana A , et al . Coal hydromethanolysis with coke-oven gas: 2. Influence of the coke-oven gas components on pyrolysis yields [J ] . Fuel , 1995 , 74 ( 1 ): 17 - 19 .

廖洪强 , 孙成功 , 李保庆 , 等 . 富氢气氛下煤热解特性的研究 [J ] . 燃料化学学报 , 1998 , 26 ( 2 ): 114 - 118 .

Liao H Q , Sun C G , Li B Q . Coal pyrolysis under hydrogen-rich gases [J ] . Journal of Fuel Chemistry and Technology , 1998 , 26 ( 2 ): 114 - 118 .

廖洪强 , 李保庆 , 张碧江 . 煤-焦炉气共热解脱硫脱氮的研究 [J ] . 环境化学 , 1998 , 17 ( 4 ): 332 - 338 .

Liao H Q , Li B Q , Zhang B J . Desulfurization and denitrogenation in co-pyrolysis of coal with coke-oven gas [J ] . Environmental Chemistry , 1998 , 17 ( 4 ): 332 - 338 .

Ariunaa A , Li B Q , Li W , et al . Coal pyrolysis under synthesis gas, hydrogen and nitrogen [J ] . Journal of Fuel Chemistry and Technology , 2007 , 35 ( 1 ): 1 - 4 .

Zhou Q , Hu H Q , Liu Q R , et al . Effect of atmosphere on evolution of sulfur-containing gases during coal pyrolysis [J ] . Energy & Fuels , 2005 , 19 ( 3 ): 892 - 897 .

Tang L H , Zhu Z B , Gu H X , et al . The effect of coal rank on flash hydropyrolysis of Chinese coal [J ] . Fuel Processing Technology , 1999 , 60 ( 3 ): 195 - 202 .

Tahmasebi A , Maliutina K , Matamba T , et al . Pressurized entrained-flow pyrolysis of lignite for enhanced production of hydrogen-rich gas and chemical raw materials [J ] . Journal of Analytical and Applied Pyrolysis , 2020 , 145 : 104741 .

Megaritis A , Zhuo Y , Messenböck R , et al . Pyrolysis and gasification in a bench-scale high-pressure fluidized-bed reactor [J ] . Energy & Fuels , 1998 , 12 ( 1 ): 144 - 151 .

Patisson F , Lebas E , Hanrot F , et al . Coal pyrolysis in a rotary kiln (Part Ⅱ): Overall model of the furnace [J ] . Metallurgical and Materials Transactions B , 2000 , 31 ( 2 ): 391 - 402 .

杨远平 , 黄云 , 宋民航 , 等 . 回转窑低阶煤热解提质工艺及应用技术研究进展 [J ] . 中国电机工程学报 , 2025 , 45 ( 6 ): 2251 - 2264 .

Yang Y P , Huang Y , Song M H , et al . Research progress on upgrading technologies and applications of low-rank coal pyrolysis in a rotary kiln [J ] . Proceedings of the CSEE , 2025 , 45 ( 6 ): 2251 - 2264 .

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