太原理工大学省部共建煤基能源清洁高效利用国家重点实验室,山西 太原 030024
程浩冉(2002—),女,硕士研究生,2024510576@link.tyut.edu.cn
徐兴堂(1993—),男,副教授,xuxingtang@tyut.edu.cn
李文英(1968—),女,教授,ying@tyut.edu.cn
收稿:2026-04-14,
修回:2026-08-17,
纸质出版:2026-09-25
移动端阅览
程浩冉, 李崇华, 徐兴堂, 冯杰, 李文英. 能-质耦合视角下煤基甲醇系统碳氢元素匹配研究进展[J]. 化工学报, 2026, 77(9): 4961-4982
CHENG Haoran, LI Chonghua, XU Xingtang, FENG Jie, LI Wenying. Research progress on carbon-hydrogen element matching in coal-based methanol system from the perspective of energy-mass coupling[J]. CIESC Journal, 2026, 77(9): 4961-4982
程浩冉, 李崇华, 徐兴堂, 冯杰, 李文英. 能-质耦合视角下煤基甲醇系统碳氢元素匹配研究进展[J]. 化工学报, 2026, 77(9): 4961-4982 DOI: 10.11949/0438-1157.20260521.
CHENG Haoran, LI Chonghua, XU Xingtang, FENG Jie, LI Wenying. Research progress on carbon-hydrogen element matching in coal-based methanol system from the perspective of energy-mass coupling[J]. CIESC Journal, 2026, 77(9): 4961-4982 DOI: 10.11949/0438-1157.20260521.
煤基甲醇是我国煤化工产业的重要方向,但由于煤富碳贫氢、甲醇富氢贫碳,传统工艺长期存在能效低、碳排放强度高等问题,制约了产业的低碳化转型。本文围绕煤基甲醇系统碳氢元素匹配这一关键科学与工程问题,系统梳理了相关技术路径及研究进展,分析了水煤气变换氢碳比调节、煤与生物质共气化等典型传统改进路径的机制与局限性,并重点从能-质耦合视角综述了基于碳元素去向重构、引入清洁氢源以及基于能量梯级利用的三类结构性变革路径,总结了其技术原理、耦合特征及研究现状。同时,归纳了多目标优化与全生命周期评价在煤基甲醇系统优化与工艺评价中的应用进展与不足。最后,从能-质耦合机制解析、多源系统集成以及优化与评价方法完善三方面展望了未来发展方向。
Coal-based methanol is an important development direction in China’s coal chemical industry. However
because coal is carbon-rich and hydrogen-deficient whereas methanol is hydrogen-rich and carbon-deficien
t
conventional processes have long been constrained by low energy efficiency and high carbon emission intensity
thereby hindering the low-carbon transition of the industry. Focusing on carbon-hydrogen element matching in coal-based methanol systems
this review systematically summarizes the relevant technological pathways and recent research progress. This review first analyzes the mechanisms and limitations of conventional improvement routes
including the adjustment of the hydrogen-carbon ratio
via
the water-gas shift reaction
coal and biomass co-gasification
and sorption-enhanced water-gas shift for hydrogen production. From the perspective of energy-mass coupling
the review further summarizes three categories of system reconfiguration pathways that break through the traditional coal gasification framework: coal-based methanol integrated with CO
2
hydrogenation to methanol pathways based on carbon flow reconfiguration
coal-based methanol coupled with hydrogen production from water electrolysis pathways based on clean hydrogen supplementation
as well as the coal-based methanol and power polygeneration pathway based on cascade energy utilization. The technical principles
energy-mass coupling characteristics
and current research status of these three pathway categories are discussed. Meanwhile
the progress and limitations of multi-objective optimization and life cycle assessment in coal-based methanol system optimization and process evaluation are summarized. Finally
future research directions are proposed in three aspects: deepening the analysis of energy-mass coupling mechanisms
advancing multi-source system integration
and improving optimization and evaluation methodologies.
王文洋 , 陈沐新 , 沈玉华 , 等 . 甲醇工艺碳-本协同评估与经济绿色标准构建 [J ] . 化工学报 , 2026 , 77 ( 6 ): 3571 - 3590 .
Wang W Y , Chen M X , Shen Y H , et al . Synergistic “carbon-cost” assessment of methanol processes and standard construction for “economic green methanol” [J ] . CIESC Journal , 2026 , 77 ( 6 ): 3571 - 3590 .
Wang Z H , Liu T Y , He Y L , et al . Synergistic optimization of renewable energy-driven methanol synthesis: coupling alkaline water electrolysis and CO 2 hydrogenation with full-chain performance analysis [J ] . Sustainable Energy Technologies and Assessments , 2026 , 86 : 104855 .
Cabrera-Gallardo D , Baena-Moreno F M , Rodríguez-Galán M , et al . A review of recent advances on the path towards a greener methanol industry [J ] . Gas Science and Engineering , 2026 , 149 : 205881 .
Förtsch D . On the basic effects on the gas composition governed by the water-gas shift equilibrium [J ] . Energy , 2020 , 205 : 117883 .
Yang G Q , Yang J C , Hu U , et al . Emission pathways and reduction strategies of greenhouse gases in coal chemical industry: a review [J ] . Journal of Environmental Chemical Engineering , 2025 , 13 ( 3 ): 116208 .
Liu J , Zhuang Y , Wang C , et al . Life cycle carbon footprint assessment of coal-to-SNG/methanol polygeneration process [J ] . Science of the Total Environment , 2024 , 908 : 168409 .
Lee Y L , Kim K J , Hong G R , et al . Target-oriented water-gas shift reactions with customized reaction conditions and catalysts [J ] . Chemical Engineering Journal , 2023 , 458 : 141422 .
Chen Y Y , Wang J , Yang S L , et al . Eulerian-Lagrangian simulation of biomass and coal co-gasification process of a fluidized gasifier [J ] . Chemical Engineering Journal , 2026 , 535 : 175229 .
Castro J , Leaver J , Pang S S . Kinetic modeling of the CaO-based sorption-enhanced water gas shift processing of biomass gasification producer gas [J ] . Biomass Conversion and Biorefinery , 2025 , 15 ( 13 ): 20207 - 20220 .
Francis A , Ramyashree M S , Priya S S , et al . Carbon dioxide hydrogenation to methanol: process simulation and optimization studies [J ] . International Journal of Hydrogen Energy , 2022 , 47 ( 86 ): 36418 - 36432 .
Wang D L , Li J W , Meng W L , et al . A near-zero carbon emission methanol production through CO 2 hydrogenation integrated with renewable hydrogen: process analysis, modification and evaluation [J ] . Journal of Cleaner Production , 2023 , 412 : 137388 .
Ye J J , Zhang Y Q , Hao Y S , et al . Configuration optimization and techno-economic analysis of integrated energy production unit of methane and methanol [J ] . Sustainable Energy Technologies and Assessments , 2024 , 69 : 103902 .
Meng W L , Wang D L , Zhou H R , et al . Design and analysis for chemical process electrification based on renewable electricity: coal-to-methanol process as a case study [J ] . Energy Conversion and Management , 2023 , 292 : 117424 .
Xin T T , Xu C , Liu Y H , et al . Thermodynamic analysis of a novel zero carbon emission coal-based polygeneration system incorporating methanol synthesis and Allam power cycle [J ] . Energy Conversion and Management , 2021 , 244 : 114441 .
Zamfirescu C , Naterer G F . Thermodynamic analysis of a copper-chlorine cycle integrated with carbon capture and methanol synthesis for industrial waste heat recovery and power generation [J ] . Fuel , 2026 , 416 : 138449 .
Wang Z H , He N , Chen Q C , et al . Co-generation of methanol and electricity using integrated concentrated solar power, calcium looping, and methane bi-reforming: energy, exergy and economic analyses [J ] . Energy Conversion and Management , 2025 , 327 : 119585 .
Nouri A , Tohidi F , Chitsaz A . Integration of biomass gasification and MEA-based CO 2 capture for sustainable power and methanol production: energy, exergy, and economic analysis and optimization [J ] . Energy , 2025 , 319 : 135062 .
杨珂宣 . 基于物质能量耦合的典型化工生产全流程降碳减污协同优化 [D ] . 杭州 : 浙江大学 , 2025 .
Yang K X . Collaborative optimization of carbon and pollution reduction in the whole process of typical chemical industry based on mass-energy coupling [D ] . Hangzhou : Zhejiang University , 2025 .
Zhao Y J , Liu Q , Wang J C , et al . Substances and energy metabolism of green hydrogen-assisted/coal-methanol-olefin-polyolefin system using ecological network methodology [J ] . Chemical Engineering Science , 2024 , 283 : 119385 .
Dai M , Yang H , Wang J , et al . Energetic, economic and environmental (3E) optimization of hydrogen production process from coal-biomass co-gasification based on a novel method of ordering preference targeting at bi-ideal average solutions (OPTBIAS) [J ] . Computers & Chemical Engineering , 2023 , 169 : 108084 .
Qin Z , Tang Y T , Zhang Z X , et al . Techno-economic-environmental analysis of coal-based methanol and power poly-generation system integrated with biomass co-gasification and solar based hydrogen addition [J ] . Energy Conversion and Management , 2021 , 228 : 113646 .
Zhao Y J , Liu Q , Duan Y Y , et al . A multi-dimensional feasibility analysis of coal to methanol assisted by green hydrogen from a life cycle viewpoint [J ] . Energy Conversion and Management , 2022 , 268 : 115992 .
Cao X Y , Han Y F , Peng C , et al . A review on the water-gas shift reaction over nickel-based catalysts [J ] . ChemCatChem , 2022 , 14 ( 16 ): e202200190 .
Moreira M N , Ribeiro A M , Cunha A F , et al . Copper based materials for water-gas shift equilibrium displacement [J ] . Applied Catalysis B: Environmental , 2016 , 189 : 199 - 209 .
Polo-Garzon F , Fung V , Nguyen L , et al . Elucidation of the reaction mechanism for high-temperature water gas shift over an industrial-type copper-chromium-iron oxide catalyst [J ] . Journal of the American Chemical Society , 2019 , 141 ( 19 ): 7990 - 7999 .
Patel R , Varatharajan P , Zhang Q , et al . Catalysts in the water-gas shift reaction: a comparative review of industrial and academic contributions [J ] . Carbon Capture Science & Technology , 2025 , 15 : 100388 .
Baraj E , Ciahotný K , Hlinčík T . The water gas shift reaction: catalysts and reaction mechanism [J ] . Fuel , 2021 , 288 : 119817 .
尹番 . 水煤气变换反应金属催化剂结构调控及其催化机理的理论与实验研究 [D ] . 北京 : 北京化工大学 , 2022 .
Yin P . Theoretical and experimental studies on structural regulation of metal-based catalysts and the catalytic mechanism for water-gas shift reaction [D ] . Beijing : Beijing University of Chemical Technology , 2022 .
Zhou L M , Liu Y Y , Liu S L , et al . For more and purer hydrogen-the progress and challenges in water gas shift reaction [J ] . Journal of Energy Chemistry , 2023 , 83 : 363 - 396 .
Zhu M H , Wachs I E . Resolving the reaction mechanism for H 2 formation from high-temperature water-gas shift by chromium-iron oxide catalysts [J ] . ACS Catalysis , 2016 , 6 ( 5 ): 2827 - 2830 .
Jain R , Maric R . Synthesis of nano-Pt onto ceria support as catalyst for water-gas shift reaction by reactive spray deposition technology [J ] . Applied Catalysis A: General , 2014 , 475 : 461 - 468 .
Chen Y , Ma Y , Liao C , et al . A confinement-stabilized Cu 0 -Cu + redox pair on silica and its catalytic role in the water-gas shift reaction [J ] . Journal of Materials Chemistry A , 2025 , 13 ( 35 ): 29079 - 29091 .
Fajín J L C , Cordeiro M N D S . Insights into the catalytic activity of trimetallic Al/Zn/Cu surfaces for the water gas shift reaction [J ] . Applied Surface Science , 2021 , 542 : 148589 .
Dehimi L , Alioui O , Benguerba Y , et al . Hydrogen production by the water-gas shift reaction: a comprehensive review on catalysts, kinetics, and reaction mechanism [J ] . Fuel Processing Technology , 2025 , 267 : 108163 .
Li S , Jin H G , Gao L , et al . Energy and exergy analyses of an integrated gasification combined cycle power plant with CO 2 capture using hot potassium carbonate solvent [J ] . Environmental Science & Technology , 2014 , 48 ( 24 ): 14814 - 14821 .
Chen Q Q , Lv M , Gu Y , et al . Hybrid energy system for a coal-based chemical industry [J ] . Joule , 2018 , 2 ( 4 ): 607 - 620 .
Liu N , Dou C , Yang X , et al . Effects of pretreatment procedure, compositional feature and reaction condition on the devolatilization characteristics of biomass during pyrolysis process: a review [J ] . Journal of the Energy Institute , 2025 , 118 : 101943 .
Hu J H , Qi N X , Yang H P , et al . Investigation on steam co-gasification of torrefied biomass and coal: thermal behavior, reactivity, product characteristic and synergy [J ] . Energy , 2024 , 313 : 133914 .
陈锐 , 徐帅杰 , 孟庆延 , 等 . 生物质气化气催化提质研究进展 [J ] . 洁净煤技术 , 2026 , 32 ( 1 ): 377 - 402 .
Chen R , Xu S J , Meng Q Y , et al . Research progress on catalytic upgrading of biomass producer gas [J ] . Clean Coal Technology , 2026 , 32 ( 1 ): 377 - 402 .
Mallick D , Mahanta P , Moholkar V S . Co-gasification of coal and biomass blends: chemistry and engineering [J ] . Fuel , 2017 , 204 : 106 - 128 .
Zhang J Z , Zhang K , Huang J G , et al . Synergistic effect and volatile emission characteristics during co-combustion of biomass and low-rank coal [J ] . Energy , 2024 , 289 : 130015 .
Tian B , Zhao W Y , Guo Q J , et al . A comprehensive understanding of synergetic effect and volatile interaction mechanisms during co-pyrolysis of rice husk and different rank coals [J ] . Energy , 2022 , 254 : 124388 .
Guo Q Q , Liu S , Liu H T , et al . Study on the synergistic mechanism of co-gasification of biochar and coal [J ] . Journal of the Energy Institute , 2026 , 124 : 102416 .
Li X , Zhang R M , Yao Q , et al . Catalytic effects of key compositions in biomass ashes on coal gasification reactivity and structural evolution characteristic during gasification process [J ] . Journal of Cleaner Production , 2025 , 499 : 145197 .
Zhao Y , Guo S , Shao C Y , et al . Combined impacts of intrinsic alkali and alkaline earth metals and chemical structure on reactivity of low-rank coal char: new explanation for the role of water-soluble AAEMs during pyrolysis and gasification [J ] . Fuel , 2021 , 305 : 121405 .
Yu J Q , Xia W D , Areeprasert C , et al . Catalytic effects of inherent AAEM on char gasification: a mechanism study using in-situ Raman [J ] . Energy , 2022 , 238 : 122074 .
张金鹏 , 屈婷 , 荆洁颖 , 等 . 吸附强化水气变换制氢复合催化剂研究进展 [J ] . 化工进展 , 2024 , 43 ( 5 ): 2629 - 2644 .
Zhang J P , Qu T , Jing J Y , et al . Composite catalyst of sorption enhanced water gas shift for hydrogen production: a review [J ] . Chemical Industry and Engineering Progress , 2024 , 43 ( 5 ): 2629 - 2644 .
Xin K , Boon J , van Dijk H A J , et al . Stability of potassium-promoted hydrotalcites for CO 2 capture over numerous repetitive adsorption and desorption cycles [J ] . Frontiers in Chemical Engineering , 2024 , 6 : 1272152 .
Sikarwar V S , Pfeifer C , Ronsse F , et al . Progress in in - situ CO 2 -sorption for enhanced hydrogen production [J ] . Progress in Energy and Combustion Science , 2022 , 91 : 101008 .
Gao W L , Zhou T T , Gao Y S , et al . Enhanced water gas shift processes for carbon dioxide capture and hydrogen production [J ] . Applied Energy , 2019 , 254 : 113700 .
Dunstan M T , Donat F , Bork A H , et al . CO 2 capture at medium to high temperature using solid oxide-based sorbents: fundamental aspects, mechanistic insights, and recent advances [J ] . Chemical Reviews , 2021 , 121 ( 20 ): 12681 - 12745 .
Shahid M Z , Farooqi A S , Hossain M M , et al . Effects of CaO/MgO compositions on the performances of sorption enhanced water gas shift reaction: a thermodynamic analysis [J ] . Chemical Engineering and Processing-Process Intensification , 2025 , 212 : 110287 .
荆洁颖 , 屈婷 , 陶威 , 等 . CO 2 原位捕集强化水气变换制氢研究进展 [J ] . 煤炭学报 , 2023 , 48 ( 2 ): 986 - 995 .
Jing J Y , Qu T , Tao W , et al . An overview on CO 2 sorption enhanced water gas shift for hydrogen production [J ] . Journal of China Coal Society , 2023 , 48 ( 2 ): 986 - 995 .
Gao W L , Zhou T T , Gao Y S , et al . Molten salts-modified MgO-based adsorbents for intermediate-temperature CO 2 capture: a review [J ] . Journal of Energy Chemistry , 2017 , 26 ( 5 ): 830 - 838 .
Dou B L , Wang C , Song Y C , et al . Solid sorbents for in - situ CO 2 removal during sorption-enhanced steam reforming process: a review [J ] . Renewable and Sustainable Energy Reviews , 2016 , 53 : 536 - 546 .
Pieterse J A Z , Booneveld S , Elzinga G D , et al . Cyclic stability of a bifunctional catalyst in the sorption-enhanced reverse water-gas shift reaction [J ] . Catalysts , 2025 , 15 ( 5 ): 480 .
Zhang C X , Li Y J , Deng Y M , et al . Hollow submicrospherical Ni/Co-promoted CaO/Ca 12 Al 14 O 33 for H 2 production from sorption-enhanced water-gas shift with in situ CO 2 conversion via CH 4 reforming of CaCO 3 [J ] . ACS Catalysis , 2025 , 15 ( 5 ): 4208 - 4228 .
Ren M H , Zhang Y M , Wang X , et al . Catalytic hydrogenation of CO 2 to methanol: a review [J ] . Catalysts , 2022 , 12 ( 4 ): 403 .
Cao M Y , Chen Y L , Liu B , et al . CO 2 hydrogenation to methanol on efficient Pd modified α-MoC 1- x catalysts [J ] . Fuel , 2024 , 375 : 132587 .
Bahruji H , Bowker M , Hutchings G , et al . Pd/ZnO catalysts for direct CO 2 hydrogenation to methanol [J ] . Journal of Catalysis , 2016 , 343 : 133 - 146 .
Hu J T , Yu L , Deng J , et al . Sulfur vacancy-rich MoS 2 as a catalyst for the hydrogenation of CO 2 to methanol [J ] . Nature Catalysis , 2021 , 4 ( 3 ): 242 - 250 .
何聂燕 , 李学琴 , 刘鹏 , 等 . 二氧化碳加氢合成甲醇技术现状及催化剂研究进展 [J ] . 洁净煤技术 , 2025 , 31 ( 2 ): 198 - 206 .
He N Y , Li X Q , Liu P , et al . Technical status of carbon dioxide hydrogenation to methanol and research progress of catalysts [J ] . Clean Coal Technology , 2025 , 31 ( 2 ): 198 - 206 .
Li M M , Tsang S C E . Bimetallic catalysts for green methanol production via CO 2 and renewable hydrogen: a mini-review and prospects [J ] . Catalysis Science & Technology , 2018 , 8 ( 14 ): 3450 - 3464 .
Zada H , Yu J F , Fang C Y , et al . Disentangling the activity-selectivity trade-off in CO 2 hydrogenation to methanol [J ] . Chem , 2026 : 102942 .
符祝富 , 赵欣悦 , 陈禹年 , 等 . 尖晶石催化二氧化碳加氢制甲醇研究进展 [J ] . 洁净煤技术 , 2026 , 32 ( 2 ): 119 - 136 .
Fu Z F , Zhao X Y , Chen Y N , et al . Research progress on spinel-catalyzed CO 2 hydrogenation to methanol [J ] . Clean Coal Technology , 2026 , 32 ( 2 ): 119 - 136 .
Tang A R , Wu G J , Chai Y C , et al . CO 2 selective hydrogenation to methanol catalyzed by CuZn active sites confined in silicalite-1 zeolite [J ] . ACS Catalysis , 2025 , 15 ( 23 ): 19984 - 19993 .
Zhou Z X , Gao P . Direct carbon dioxide hydrogenation to produce bulk chemicals and liquid fuels via heterogeneous catalysis [J ] . Chinese Journal of Catalysis , 2022 , 43 ( 8 ): 2045 - 2056 .
Gao P , Zhong L S , Han B X , et al . Green carbon science: keeping the pace in practice [J ] . Angewandte Chemie International Edition , 2022 , 61 ( 46 ): e202210095 .
杨嘉聪 , 程光旭 , 贾彤华 , 等 . 煤制甲醇与绿氢高效耦合新工艺模拟及技术经济分析 [J ] . 化工进展 , 2025 , 44 ( 8 ): 4657 - 4668 .
Yang J C , Cheng G X , Jia T H , et al . Simulation and techno-economic analysis of new efficient coupling processes between coal to methanol and green hydrogen [J ] . Chemical Industry and Engineering Progress , 2025 , 44 ( 8 ): 4657 - 4668 .
Chen W J , Xu X T , Cheng H R , et al . Sustainable methanol production processes from coal and biomass: low CO 2 emissions and high efficiency [J ] . Energy , 2025 , 330 : 136978 .
Hu C L , Zhang L , Gong J L . Recent progress made in the mechanism comprehension and design of electrocatalysts for alkaline water splitting [J ] . Energy & Environmental Science , 2019 , 12 ( 9 ): 2620 - 2645 .
Yu M Q , Budiyanto E , Tüysüz H . Principles of water electrolysis and recent progress in cobalt-, nickel-, and iron-based oxides for the oxygen evolution reaction [J ] . Angewandte Chemie-International Edition , 2022 , 61 : e202103824 .
Tüysüz H . Alkaline water electrolysis for green hydrogen production [J ] . Accounts of Chemical Research , 2024 , 57 ( 4 ): 558 - 567 .
Li Q H , Chen W X , Xiao H , et al . Fe isolated single atoms on S, N codoped carbon by copolymer pyrolysis strategy for highly efficient oxygen reduction reaction [J ] . Advanced Materials , 2018 , 30 ( 25 ): e1800588 .
Peng J , Chen Y H , Wang K , et al . High-performance Ru-based electrocatalyst composed of Ru nanoparticles and Ru single atoms for hydrogen evolution reaction in alkaline solution [J ] . International Journal of Hydrogen Energy , 2020 , 45 ( 38 ): 18840 - 18849 .
Tian X Y , Zhao P C , Sheng W C . Hydrogen evolution and oxidation: mechanistic studies and material advances [J ] . Advanced Materials , 2019 , 31 ( 31 ): e1808066 .
Wang Z , Zuo P J , Fan L Q , et al . Facile electrospinning preparation of phosphorus and nitrogen dual-doped cobalt-based carbon nanofibers as bifunctional electrocatalyst [J ] . Journal of Power Sources , 2016 , 311 : 68 - 80 .
南洋 . 面向电解水制氢的高效碳基催化剂构筑及性能调控 [D ] . 北京 : 北京化工大学 , 2024 .
Nan Y . Construction of efficient carbon-based catalysts and performance regulation for hydrogen evolution reaction [D ] . Beijing : Beijing University of Chemical Technology , 2024 .
宋英杰 . 电解水制氢耦合生物质分子氧化制高值化学品研究 [D ] . 北京 : 北京化工大学 , 2024 .
Song Y J . Electrochemical hydrogen production coupled with biomass molecules oxidation for value-added chemicals synthesis [D ] . Beijing : Beijing University of Chemical Technology , 2024 .
Li Z , Sun L M , Zhang Y , et al . Coupled and decoupled electrochemical water splitting for boosting hydrogen evolution: a review and perspective [J ] . Coordination Chemistry Reviews , 2024 , 510 : 215837 .
Zhu J H , Feng L Y , Yu C C , et al . Renewable methanol production from biomass gasification coupled with green hydrogen: process design and economic assessment [J ] . International Journal of Hydrogen Energy , 2025 , 191 : 151693 .
Li C , Liu S , Wang Y R , et al . Entire elevating temperature processes for green hydrogen coupled coal-to-methanol process: simulation and techno-economic evaluation [J ] . Energy , 2025 , 335 : 137779 .
Wei X , Ma X , Chen B , et al . Evaluating coal-based methanol production integrated with green hydrogen: regional insights from China’s energy transition [J/OL ] . Chinese Journal of Chemical Engineering , 2026 , https://doi.org/10.1016/j.cjche.2026.03.044 https://doi.org/10.1016/j.cjche.2026.03.044 .
Tariq G , Chen Z W , Zhao M . Techno-economic and life cycle assessment of integrated bio- and e-methanol production from biomass with carbon capture and utilization [J ] . Chemical Engineering Journal , 2025 , 515 : 163850 .
Liu S , Song X H , Jiang D L , et al . To convert or not to convert: a comparative techno-economic analysis on CO 2 -to-methanol and CO 2 -EOR [J ] . Applied Energy , 2025 , 388 : 125698 .
Douglas C M , Lai H X , Ostadi M , et al . Techno-economic analysis and life-cycle assessment of methanol synthesis plants using renewable hydrogen and carbon dioxide feedstocks [J ] . Energy Conversion and Management , 2026 , 347 : 120374 .
张钟 , 李胜 . 基于煤与生物质互补气化技术的新型制氢系统的技术经济与环境评估 [J ] . 洁净煤技术 , 2024 , 30 ( 12 ): 105 - 117 .
Zhang Z , Li S . Techno-economic and environmental assessment of a novel hydrogen production system based on complementary coal and biomass gasification technology [J ] . Clean Coal Technology , 2024 , 30 ( 12 ): 105 - 117 .
周怀荣 , 伊嘉伟 , 曹阿波 , 等 . 共电解耦合CO 2 间接加氢制甲醇工艺集成设计与性能评价 [J ] . 化工学报 , 2025 , 76 ( 9 ): 4586 - 4600 .
Zhou H R , Yi J W , Cao A B , et al . Integrated design and performance evaluation of co-electrolysis coupled CO 2 indirect hydrogenation methanol synthesis process [J ] . CIESC Journal , 2025 , 76 ( 9 ): 4586 - 4600 .
Palys M J , Daoutidis P . Economically optimal CO 2 utilization via flexible chemical production facilities [J ] . Sustainability Science and Technology , 2025 , 2 ( 4 ): 044001 .
吴子波 , 吴路平 , 林必华 , 等 . 适应可再生电力不稳定性的组合态柔性制甲醇技术探讨 [J ] . 低碳化学与化工 , 2025 , 50 ( 10 ): 65 - 74 .
Wu Z B , Wu L P , Lin B H , et al . Discussion on multi-mode flexible methanol production technology adapted to volatility of renewable electricity [J ] . Low-Carbon Chemistry and Chemical Engineering , 2025 , 50 ( 10 ): 65 - 74 .
冀晓洲 . 化工-动力多联产系统节能机制与特性研究 [D ] . 北京 : 中国科学院大学 , 2016 .
Ji X Z . The energy saving mechanism and characterization study on coal poly-generation systems [D ] . Beijing : University of Chinese Academy of Sciences , 2016 .
高林 . 煤基化工-动力多联产系统开拓研究 [D ] . 北京 : 中国科学院工程热物理研究所 , 2005 .
Gao L . Investigation of coal-based polygeneration systems for production of power and liquid fuel [D ] . Beijing : Institute of Engineering Thermophysics, Chinese Academy of Sciences , 2005 .
林汝谋 , 金红光 , 高林 . 化工动力多联产系统及其集成优化机理 [J ] . 热能动力工程 , 2006 , 21 ( 4 ): 331 - 337 .
Lin R M , Jin H G , Gao L . Chemical engineering power polygeneration system and its integrated optimization mechanism [J ] . Journal of Engineering for Thermal Energy and Power , 2006 , 21 ( 4 ): 331 - 337 .
李胜 . CO 2 捕集能耗最小化机理及煤制天然气动力多联产系统 [D ] . 北京 : 中国科学院大学 , 2012 .
Li S . The mechanism of minimal energy penalty for CO 2 capture and the study on coal-based polygeneration system for cogenerating substitute natural gas and power [D ] . Beijing : University of Chinese Academy of Sciences , 2012 .
黄宏 , 杨思宇 . 一种低能耗捕集CO 2 煤基甲醇和电力联产过程设计 [J ] . 化工学报 , 2017 , 68 ( 10 ): 3860 - 3869 .
Huang H , Yang S Y . Design of a coal based methanol and power polygeneration process with low energy consumption for CO 2 capture [J ] . CIESC Journal , 2017 , 68 ( 10 ): 3860 - 3869 .
Kler A M , Tyurina E A , Mednikov A S . A plant for methanol and electricity production: technical-economic analysis [J ] . Energy , 2018 , 165 : 890 - 899 .
Zhang J Y , Yang Z W , Ma L W , et al . Exergy analysis of coal-based series polygeneration systems for methanol and electricity co-production [J ] . Molecules , 2021 , 26 ( 21 ): 6673 .
Ye C , Wang Q H , Zheng Y Q , et al . Techno-economic analysis of methanol and electricity poly-generation system based on coal partial gasification [J ] . Energy , 2019 , 185 : 624 - 632 .
Lu R R , Zhu H Y , Wang A R , et al . A coal-based polygeneration system of synthetic natural gas, methanol and ethylene glycol: process modeling and techno-economic evaluation [J ] . Separation and Purification Technology , 2023 , 320 : 124122 .
Wu Z C , Zhang Z Y , Xu G , et al . Thermodynamic and economic analysis of a new methanol synthesis system coupled with a biomass integrated gasification combined cycle [J ] . Energy , 2024 , 300 : 131647 .
Zhang D Q , Duan R H , Li H W , et al . Optimal design, thermodynamic, cost and CO 2 emission analyses of coal-to-methanol process integrated with chemical looping air separation and hydrogen technology [J ] . Energy , 2020 , 203 : 117876 .
Yang Q C , Li X F , Yang Q , et al . Opportunities for CO 2 utilization in coal to green fuel process: opti mal design and performance evaluation [J ] . ACS Sustainable Chemistry & Engineering , 2020 , 8 ( 3 ): 1329 - 1342 .
孟文亮 , 李贵贤 , 周怀荣 , 等 . 绿氢重构的粉煤气化煤制甲醇近零碳排放工艺研究 [J ] . 化工学报 , 2022 , 73 ( 4 ): 1714 - 1723 .
Meng W L , Li G X , Zhou H R , et al . A novel coal to methanol process with near zero CO 2 emission by pulverized coal gasification integrated green hydrogen [J ] . CIESC Journal , 2022 , 73 ( 4 ): 1714 - 1723 .
Liu L L , Li S H , Zhuang Y , et al . Exploring biomass addition in methanol production: a life cycle analysis of efficiency and environmental impacts [J ] . Journal of Cleaner Production , 2024 , 468 : 143072 .
Wang D L , Meng W L , Zhou H R , et al . Green hydrogen coupling with CO 2 utilization of coal-to-methanol for high methanol productivity and low CO 2 emission [J ] . Energy , 2021 , 231 : 120970 .
Zhang J P , Li Z W , Zhang Z H , et al . Techno-economic analysis of integrating a CO 2 hydrogenation-to-methanol unit with a coal-to-methanol process for CO 2 reduction [J ] . ACS Sustainable Chemistry & Engineering , 2020 , 8 ( 49 ): 18062 - 18070 .
Wang J Y , Chen R K , Li S J , et al . Integrating indirect CO 2 hydrogenation with coal-based chemical industry: energetic and environmental assessment of a novel low-carbon methanol strategy [J ] . Energy , 2025 , 333 : 137352 .
吴云波 , 张军军 , 牛高 . 面向碳减排的绿氢耦合煤化工制甲醇工艺研究 [J ] . 山西化工 , 2026 , 46 ( 2 ): 285 - 287 .
Wu Y B , Zhang J J , Niu G . Research on the green hydrogen coupled coal chemical process for producing methanol for carbon reduction [J ] . Shanxi Chemical Industry , 2026 , 46 ( 2 ): 285 - 287 .
Liu Z L , Shi K N , Yang S Y , et al . A novel process design and techno-economic analysis for coal-based polygeneration process of synthetic natural gas, methanol and power [J ] . Journal of Cleaner Production , 2022 , 349 : 131388 .
Buchner G A , Stepputat K J , Zimmermann A W , et al . Specifying technology readiness levels for the chemical industry [J ] . Industrial & Engineering Chemistry Research , 2019 , 58 ( 17 ): 6957 - 6969 .
黄磊 . 以煤气化为基础合成甲醇系统的参数分析及优化 [D ] . 郑州 : 郑州大学 , 2012 .
Huang L . Parameters analysis and optimization of methanol synthesized system based on coal gasification [D ] . Zhengzhou : Zhengzhou University , 2012 .
Hoseiny S , Zare Z , Mirvakili A , et al . Simulation-based optimization of operating parameters for methanol synthesis process: application of response surface methodology for statistical analysis [J ] . Journal of Natural Gas Science and Engineering , 2016 , 34 : 439 - 448 .
Li S H , Sun X J , Liu L L , et al . A full process optimization of methanol production integrated with co-generation based on the co-gasification of biomass and coal [J ] . Energy , 2023 , 267 : 126566 .
Wang D L , Meng W L , Zhou H R , et al . Novel coal-to-methanol process with near-zero carbon emission: pulverized coal gasification-integrated green hydrogen process [J ] . Journal of Cleaner Production , 2022 , 339 : 130500 .
李乔同 . 煤/生物质共气化过程中物料对合成气组成的调变 [D ] . 太原 : 太原理工大学 , 2019 .
Li Q T . Modulation of composition of syngas by material in biomass/coal co-gasification process [D ] . Taiyuan : Taiyuan University of Technology , 2019 .
Liu M Q , Tong X Y , Ling B Q , et al . System integration, optimization, exergy and CO 2 emissions analysis of petroleum coke/coal gasification-assisted coking dry gas chemical looping reforming for methanol production [J ] . Fuel , 2025 , 392 : 134876 .
Arshad S A , Ali U N , Ali Ammar Taqvi S , et al . Towards sustainable methanol production: energy, exergy, economics, and environmental evaluation of Thar coal gasification [J/OL ] . Environment, Development and Sustainability , 2025 , https://doi.org/10.1007/s10668-025-06451-6 https://doi.org/10.1007/s10668-025-06451-6 .
Li M X , Zhuang Y , Zhang L , et al . Conceptual design and techno-economic analysis for a coal-to-SNG/methanol polygeneration process in series and parallel reactors with integration of waste heat recovery [J ] . Energy Conversion and Management , 2020 , 214 : 112890 .
Chen J J , Yang S Y , Qian Y . A novel path for carbon-rich resource utilization with lower emission and higher efficiency: an integrated process of coal gasification and coking to methanol production [J ] . Energy , 2019 , 177 : 304 - 318 .
Wang Y L , Li G X , Liu Z Q , et al . Techno-economic analysis of biomass-to-hydrogen process in comparison with coal-to-hydrogen process [J ] . Energy , 2019 , 185 : 1063 - 1075 .
王健 . 二氧化碳捕集耦合绿氢合成甲醇系统集成与技术经济评价 [D ] . 兰州 : 兰州理工大学 , 2023 .
Wang J . Carbon dioxide capture coupled with green hydrogen synthesis of methanol system integration and techno-economic evaluation [D ] . Lanzhou : Lanzhou University of Technology , 2023 .
黄敬智 , 肖宁 , 黄夏楠 , 等 . 电氢耦合综合能源系统: 韧性量化与多目标优化 [J ] . 洁净煤技术 , 2024 , 30 ( 12 ): 147 - 160 .
Huang J Z , Xiao N , Huang X N , et al . Electricity-hydrogen coupled integrated energy system: resilience quantification and multi-objective optimization [J ] . Clean Coal Technology , 2024 , 30 ( 12 ): 147 - 160 .
Talbi E G . Metaheuristics for variable-size mixed optimization problems: a unified taxonomy and survey [J ] . swarm and Evolutionary Computation , 2024 , 89 : 101642 .
Manson J A , Chamberlain T W , Bourne R A . MVMOO: mixed variable multi-objective optimisation [J ] . Journal of Global Optimization , 2021 , 80 ( 4 ): 865 - 886 .
Yu K J , While L , Reynolds M , et al . Multiobjective optimization of ethylene cracking furnace system using self-adaptive multiobjective teaching-learning-based optimization [J ] . Energy , 2018 , 148 : 469 - 481 .
Wang X T , Wei M Y , Wang J D , et al . Optimal scheduling of energy systems for gas-to-methanol processes using operating zone models and entropy weights [J ] . Entropy , 2025 , 27 ( 3 ): 324 .
Argoubi M , Mili K . Multi-objective optimization framework for sustainable olive oil supply chains: integrating environmental compliance with economic performance [J ] . Frontiers in Sustainability , 2026 , 6 : 1711821 .
Liu X S . A study on coupled regulation of process parameters in transnational electrolyte factories based on multi-objective optimization algorithms—a case study of the Houston factory [J ] . Journal of Progress in Engineering and Physical Science , 2025 , 4 ( 6 ): 5 - 14 .
Vatandoost M , Golabchi M , Ekhlassi A , et al . Ranking and sorting the Pareto front in optimal shell structure design [J ] . Frontiers of Architectural Research , 2026 , 15 ( 2 ): 705 - 728 .
Pandey S , Srivastava V C , Kumar V . Comparative assessment of different grades of coal for methanol production: simulation, optimization, environmental and economic analysis [J ] . Energy , 2023 , 284 : 129146 .
Li W J , Zhang Q , Feng X . High-value-added byproduct resource recycling feedback driving synergistic optimization of chemical process systems toward resource utilization efficiency improvement [J ] . Industrial & Engineering Chemistry Research , 2026 , 65 ( 10 ): 5531 - 5546 .
Peters J , Buchholz D , Passerini S , et al . Life cycle assessment of sodium-ion batteries [J ] . Energy & Environmental Science , 2016 , 9 ( 5 ): 1744 - 1751 .
Rodríguez-Gómez A , Castro M P , Sáez C , et al . Life cycle assessment and life cycle costing of the electrochemical production of peroxosulfates [J ] . Chemical Engineering Journal , 2025 , 513 : 162381 .
Peters J F . Best practices for life cycle assessment of batteries [J ] . Nature Sustainability , 2023 , 6 ( 6 ): 614 - 616 .
Li C H , Bai H T , Lu Y Y , et al . Life-cycle assessment for coal-based methanol production in China [J ] . Journal of Cleaner Production , 2018 , 188 : 1004 - 1017 .
杜家益 , 吉炎 , 袁银男 , 等 . 煤基甲醇和天然气基甲醇燃料的生命周期影响评价 [J ] . 可再生能源 , 2012 , 30 ( 8 ): 78 - 82 .
Du J Y , Ji Y , Yuan Y N , et al . Life cycle impact assessment of coal-based methanol and natural gas-based methanol fuel [J ] . Renewable Energy Resources , 2012 , 30 ( 8 ): 78 - 82 .
Li J Y , Ma X X , Liu H , et al . Life cycle assessment and economic analysis of methanol production from coke oven gas compared with coal and natural gas routes [J ] . Journal of Cleaner Production , 2018 , 185 : 299 - 308 .
叶毓琛 . 典型煤化工技术全生命周期评价 [D ] . 北京 : 华北电力大学 , 2014 .
Ye Y C . Life cycle assessment of typical coal chemical technology [D ] . Beijing : North China Electric Power University , 2014 .
Liu Y G , Li G X , Chen Z R , et al . Comprehensive analysis of environmental impacts and energy consumption of biomass-to-methanol and coal-to-methanol via life cycle assessment [J ] . Energy , 2020 , 204 : 117961 .
Galusnyak S C , Petrescu L , Chisalita D A , et al . Life cycle assessment of methanol production and conversion into various chemical intermediates and products [J ] . Energy , 2022 , 259 : 124784 .
Lueddeckens S , Saling P , Guenther E . Temporal issues in life cycle assessment—a systematic review [J ] . The International Journal of Life Cycle Assessment , 2020 , 25 ( 8 ): 1385 - 1401 .
Bixler T S , Houle J , Ballestero T , et al . A dynamic life cycle assessment of green infrastructures [J ] . Science of the Total Environment , 2019 , 692 : 1146 - 1154 .
Su S , Li X D , Zhu C , et al . Dynamic life cycle assessment: a review of research for temporal variations in life cycle assessment studies [J ] . Environmental Engineering Science , 2021 , 38 ( 11 ): 1013 - 1026 .
Sohn J , Kalbar P , Goldstein B , et al . Defining temporally dynamic life cycle assessment: a review [J ] . Integrated Environmental Assessment and Management , 2020 , 16 ( 3 ): 314 - 323 .
Tiruta-Barna L , Pigné Y , Navarrete Gutiérrez T , et al . Framework and computational tool for the consideration of time dependency in life cycle inventory: proof of concept [J ] . Journal of Cleaner Production , 2016 , 116 : 198 - 206 .
Pigné Y , Gutiérrez T N , Gibon T , et al . A tool to operationalize dynamic LCA, including time differentiation on the complete background database [J ] . The International Journal of Life Cycle Assessment , 2020 , 25 ( 2 ): 267 - 279 .
Beloin-Saint-Pierre D , Albers A , Hélias A , et al . Addressing temporal considerations in life cycle assessment [J ] . Science of the Total Environment , 2020 , 743 : 140700 .
Gaikwad A , Schlüter S . Dynamic life cycle assessment of integrated production of steel and methanol [J ] . Chemie Ingenieur Technik , 2024 , 96 ( 9 ): 1177 - 1186 .
Chen Y J , Li J J , Wang Y R , et al . Significant reduction of life cycle carbon-energy-water footprint in the coal-to-methanol industry driven by technological advancements and scale expansion [J ] . Sustainable Energy Technologies and Assessments , 2026 , 87 : 104924 .
Slavkovic K , Stephan A . Dynamic life cycle assessment of buildings and building stocks—a review [J ] . Renewable and Sustainable Energy Reviews , 2025 , 212 : 115262 .
Vyrkou A , Aryblia M , Savvakis N , et al . Dynamic vs real time life cycle assessment [J ] . Cleaner Environmental Systems , 2025 , 18 : 100296 .
Andersen C E , Sørensen C G , Jensen O M , et al . Turning dynamic LCA principles into practice [J ] . Journal of Physics: Conference Series , 2023 , 2600 ( 15 ): 152025 .
Bahmutsky S , Turner I , Arulnathan V , et al . Advancing life cycle assessment through data science: a critical review of algorithms, tools, and data challenges [J ] . Sustainable Production and Consumption , 2025 , 61 : 25 - 36 .
Lan K . Some modeling challenges in dynamic life cycle assessment [J ] . BioResources , 2024 , 19 ( 3 ): 4040 - 4042 .
Wang Z R , Dai B Q , Shi J , et al . Thermodynamic modelling and techno-economic analysis of the coal-to-methanol conversion process [J ] . International Communications in Heat and Mass Transfer , 2026 , 178 : 111772 .
Zhou L , Duan M S , Yu Y D . Exergy and economic analyses of indirect coal-to-liquid technology coupling carbon capture and storage [J ] . Journal of Cleaner Production , 2018 , 174 : 87 - 95 .
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