光电化学水分解制氢研究进展：从光电极设计到规模化探索

宁艳馨; 曲修杰; 曾雯娅; 程道建; 潘金波

doi:10.11949/0438-1157.20251375

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光电化学水分解制氢研究进展：从光电极设计到规模化探索

综述与专论 | 更新时间：2026-08-13

- 光电化学水分解制氢研究进展：从光电极设计到规模化探索
- Research progress on photoelectrochemical water splitting for hydrogen production: from photoelectrodes design to scaling-up exploration
- 化工学报 2026年77卷第6期页码：2937-2956
- 作者机构：
  
  北京化工大学化学工程学院，有机无机复合材料全国重点实验室，氢能材料智能设计与制造北京市重点实验室，北京 100029
- 作者简介：
  
  宁艳馨（1999—），女，硕士研究生，12739809241@qq.com
  潘金波（1990—），男，博士，副教授，2024500128@buct.edu.cn
- 基金信息：
  
  国家自然科学基金项目(22308379);中央高校基本科研业务费专项资金资助(buctrc202538)
- DOI：10.11949/0438-1157.20251375
  中图分类号： TQ 028.8
- 收稿：2025-12-05，
  
  修回：2026-03-05，
  
  网络首发：2026-07-29，
  
  纸质出版：2026-06-25
- 稿件说明：
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宁艳馨, 曲修杰, 曾雯娅, 程道建, 潘金波. 光电化学水分解制氢研究进展：从光电极设计到规模化探索[J]. 化工学报, 2026, 77(6): 2937-2956

NING Yanxin, QU Xiujie, ZENG Wenya, CHENG Daojian, PAN Jinbo. Research progress on photoelectrochemical water splitting for hydrogen production: from photoelectrodes design to scaling-up exploration[J]. CIESC Journal, 2026, 77(6): 2937-2956
宁艳馨, 曲修杰, 曾雯娅, 程道建, 潘金波. 光电化学水分解制氢研究进展：从光电极设计到规模化探索[J]. 化工学报, 2026, 77(6): 2937-2956 DOI： 10.11949/0438-1157.20251375.

NING Yanxin, QU Xiujie, ZENG Wenya, CHENG Daojian, PAN Jinbo. Research progress on photoelectrochemical water splitting for hydrogen production: from photoelectrodes design to scaling-up exploration[J]. CIESC Journal, 2026, 77(6): 2937-2956 DOI： 10.11949/0438-1157.20251375.

摘要

光电化学水分解制氢技术是极具前景的太阳能转化与储存策略。光电极材料的设计、制备及规模化探索受到了广泛关注，并且取得了巨大进展。针对光电极存在的缺陷（包括载流子分离效率低、表面反应迟缓、长期稳定性差、水吸附与氧脱附能力不足等），研究者开展了光电极结构化设计，缺陷调控，异质结构建等研究。光电极的规模化制备存在挑战，研究者采用原位燃烧、喷雾解热、连续离子层吸附反应法等新技术，可控制备了平米级的光电极，并设计了光伏-光电催化装置。深入探讨了当前光电化学水分解技术在光电极设计、规模化制备以及长时间运行的进展和技术瓶颈，并对未来研究方向提出了展望，可为大规模光电催化能源转化研究提供理论依据和技术参考。

Abstract

Photoelectrochemical water splitting for hydrogen production is a highly promising strategy for solar energy conversion and storage. The design

fabrication

and scaling-up exploration of photoelectrode materials have attracted extensive attention and achieved significant progress. To address the inherent limitations of photoelectrodes (such as low carrier separation efficiency

sluggish surface reaction kinetics

poor long-term stability

and insufficient water adsorption/oxygen desorption capabilities)

researchers have conducted studies on structured design

defect regulation

and construction of heterojunctions. Despite challenges in scaling up fabrication

novel techniques

including in situ combustion

spray pyrolysis

and the successive ionic layer adsorption and reaction method

have enabled the controlled preparation of square-meter-scale photoelectrodes and the design of integrated photovoltaic-photoelectrochemical devices. This paper delves into the current progress and technological bottlenecks of photoelectrochemical water splitting technology in photoelectrode design

large-scale preparation

and long-term operation. It also proposes prospects for future research

providing theoretical basis and technical reference for large-scale photoelectrocatalytic energy conversion research.

关键词

Keywords

references

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调兵山市华电清洁能源有限公司 . 辽宁华电调兵山 45 万千瓦风电制氢耦合绿色甲醇一体化示范项目220 kV 输电线路工程建设项目环境影响报告表(生态影响类) [EB/OL ] . [ 2026-03-14 ] . http://www.tieling.gov.cn/tieling/zwgk/zfxxgk/fdzdgknr/zdmsxx/hjbh/jsxmhjspqkgs/2025111710321956871/2025111710273734459.pdf http://www.tieling.gov.cn/tieling/zwgk/zfxxgk/fdzdgknr/zdmsxx/hjbh/jsxmhjspqkgs/2025111710321956871/2025111710273734459.pdf .

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自然资源部中国土地市场网 . 辽宁华电(调兵山)绿色氢能示范项目土地挂牌出让公示 [EB/OL ] . [ 2026-03-14 ] . https://landchina.mnr.gov.cn/land/jggg/gpcr1/202508/t20250826_9965284.htm https://landchina.mnr.gov.cn/land/jggg/gpcr1/202508/t20250826_9965284.htm .

China Land Market Network, Ministry of Natural Resources . Public notice on land listing and transfer of Liaoning Huadian (Diaobingshan) green hydrogen energy demonstration project [EB/OL ] . [ 2026-03-14 ] . https://landchina.mnr.gov.cn/land/jggg/gpcr1/202508/t20250826_9965284.htm https://landchina.mnr.gov.cn/land/jggg/gpcr1/202508/t20250826_9965284.htm .

调兵山市采购与招标网 . 辽宁华电调兵山 45 万千瓦风电制氢耦合绿色甲醇一体化示范项目厂前区设计优化技术服务预成交公示 [EB/OL ] . [ 2026-03-14 ] . https://m.chinabidding.cn/dwzbcg_933/zbsx/ https://m.chinabidding.cn/dwzbcg_933/zbsx/ .

Diaobingshan Government Procurement and Tendering Network . Pre-transaction public notice of pre-plant area design optimization technical service for Liaoning Huadian Diaobingshan 450 MW wind power hydrogen production coupled green methanol integration demonstration project [EB/OL ] . [ 2026-03-14 ] . https://m.chinabidding.cn/dwzbcg_933/zbsx/ https://m.chinabidding.cn/dwzbcg_933/zbsx/ .

四川省公共资源交易信息中心 . 攀枝花市光解水制氢项目用地挂牌出让公告及成交公示 [EB/OL ] . [ 2026-03-14 ] . https://ggzyjy.sc.gov.cn/jyxx/002004/002004001/20251208/5DCBC0DD-4863-4A50-BA13-A0A2D09B9F8B.html https://ggzyjy.sc.gov.cn/jyxx/002004/002004001/20251208/5DCBC0DD-4863-4A50-BA13-A0A2D09B9F8B.html .

Sichuan Provincial Public Resources Trading Information Center . Public notice and transaction result of land listing and transfer for Panzhihua photolysis water hydrogen production project [EB/OL ] . [ 2026-03-14 ] . https://ggzyjy.sc.gov.cn/jyxx/002004/002004001/20251208/5DCBC0DD-4863-4A50-BA13-A0A2D09B9F8B.html https://ggzyjy.sc.gov.cn/jyxx/002004/002004001/20251208/5DCBC0DD-4863-4A50-BA13-A0A2D09B9F8B.html .

中国石油天然气集团有限公司 . 中国石油成功研制国内首套解耦型平方米级光电制氢装置 [EB/OL ] . [ 2026-03-14 ] . https://www.cnpc.com.cn/cnpc/jtxw/202510/f6482f712fa4472f964069e0edf13ace.shtml https://www.cnpc.com.cn/cnpc/jtxw/202510/f6482f712fa4472f964069e0edf13ace.shtml .

China National Petroleum Corporation . CNPC successfully develops China's first decoupled square-meter scale photovoltaic hydrogen production device [EB/OL ] . [ 2026-03-14 ] . https://www.cnpc.com.cn/cnpc/jtxw/202510/f6482f712fa4472f964069e0edf13ace.shtml https://www.cnpc.com.cn/cnpc/jtxw/202510/f6482f712fa4472f964069e0edf13ace.shtml .

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