混合稠环芳烃加氢饱和催化剂设计策略及研究进展

齐皓烨; 田涛; 荆洁颖; 李文英

doi:10.11949/0438-1157.20251230

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混合稠环芳烃加氢饱和催化剂设计策略及研究进展

综述与专论 | 更新时间：2026-08-21

- 混合稠环芳烃加氢饱和催化剂设计策略及研究进展
- Catalyst design strategies and research progress for hydrogenation saturation of mixed polycyclic aromatic hydrocarbons
- 化工学报 2026年77卷第7期页码：3754-3769
- 作者机构：
  
  1.太原理工大学省部共建煤基能源清洁高效利用国家重点实验室，山西太原 030024
  2.太原理工大学化学与化工学院，山西太原 030024
  3.北京怀柔实验室，北京 101499
  4.怀柔实验室山西研究院，山西太原 030032
- 作者简介：
  
  齐皓烨（2002—），男，硕士研究生，2024521016@link.tyut.edu.cn
  荆洁颖（1985—），女，博士，教授，jingjieying@tyut.edu.cn
- 基金信息：
  
  国家自然科学基金项目(U24B6018;22038008);怀柔实验室项目(ZD2023012A)
- DOI：10.11949/0438-1157.20251230
  中图分类号： TQ 536
- 收稿：2025-11-06，
  
  修回：2025-12-22，
  
  网络首发：2026-08-20，
  
  纸质出版：2026-07-25
- 稿件说明：
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齐皓烨, 田涛, 荆洁颖, 李文英. 混合稠环芳烃加氢饱和催化剂设计策略及研究进展[J]. 化工学报, 2026, 77(7): 3754-3769

QI Haoye, TIAN Tao, JING Jieying, LI Wenying. Catalyst design strategies and research progress for hydrogenation saturation of mixed polycyclic aromatic hydrocarbons[J]. CIESC Journal, 2026, 77(7): 3754-3769
齐皓烨, 田涛, 荆洁颖, 李文英. 混合稠环芳烃加氢饱和催化剂设计策略及研究进展[J]. 化工学报, 2026, 77(7): 3754-3769 DOI： 10.11949/0438-1157.20251230.

QI Haoye, TIAN Tao, JING Jieying, LI Wenying. Catalyst design strategies and research progress for hydrogenation saturation of mixed polycyclic aromatic hydrocarbons[J]. CIESC Journal, 2026, 77(7): 3754-3769 DOI： 10.11949/0438-1157.20251230.

摘要

将煤焦油中的稠环芳烃催化加氢转化为高能量密度燃料是实现煤炭资源清洁高效利用的重要路径。然而，混合稠环芳烃在催化剂表面存在竞争吸附与动态演变行为，导致其高效转化面临挑战。因此，阐明混合体系中稠环芳烃间相互作用及其对加氢饱和过程的影响机制是开发高效催化剂的关键。系统综述了由竞争吸附和反应路径动态演变所引发的催化加氢难题，总结了针对这些问题的催化剂设计与调控策略，主要包括优化活性中心结构以缓解竞争吸附导致的局部反应环境偏离；调控载体性质以引导因反应路径动态变化而偏离的目标反应；构建开放的分级孔道结构并进行表面功能化修饰以改善大分子传质效率并抑制积炭失活，并对混合稠环芳烃加氢饱和催化剂的未来研究方向进行了展望。

Abstract

The catalytic hydrogenation of polycyclic aromatic hydrocarbons (PAHs) in coal tar to high-energy-density fuels is an important pathway for achieving clean and efficient utilization of coal resources. However

the efficient conversion of mixed PAHs is hindered by their competitive adsorption and dynamic evolution behavior on catalyst surfaces. A fundamental understanding of the interactions among PAHs in mixtures and their impact on the hydrogenation saturation process is essential for designing high-performance catalysts. This review systematically addresses key catalytic challenges stemming from competitive adsorption and evolving reaction pathways

and summarizes advanced strategies for catalyst design and optimization. These include tailoring active sites to mitigate local environment distortions caused by competitive adsorption

modifying support properties to steer target reactions amid dynamic pathway changes

constructing open hierarchical pore structures and performing surface functionalization to improve macromolecular mass transfer efficiency and inhibit carbon deposition deactivation. The future research directions for hydrogenation saturation catalysts of mixed polycyclic aromatic hydrocarbons are also discussed.

关键词

Keywords

references

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