基于硫化物全固态锂离子电池混合正极的研究进展

杨立鹏; 顾宇阳; 田十宇; 杨晓光

doi:10.11949/0438-1157.20251089

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基于硫化物全固态锂离子电池混合正极的研究进展

综述与专论 | 更新时间：2026-05-27

- 基于硫化物全固态锂离子电池混合正极的研究进展
- Recent advances in composite cathodes for sulfide-based all-solid-state lithium-ion batteries
- 化工学报 2026年77卷第4期页码：1621-1649
- 作者机构：
  
  1.北京理工大学电动车辆国家工程研究中心，北京 100081
  2.北京理工大学深圳汽车研究院，广东深圳 518118
- 作者简介：
  
  杨立鹏（1990—），男，博士研究生，lpyang@bit.edu.cn
  杨晓光（1987—），男，博士，教授，xgyang@bit.edu.cn
- 基金信息：
  
  国家自然科学基金项目(52277212);广东省基础与应用基础研究基金项目(2024A1515010264)
- DOI：10.11949/0438-1157.20251089
  中图分类号： TM 911
- 收稿：2025-09-30，
  
  修回：2025-12-18，
  
  纸质出版：2026-04-25
- 稿件说明：
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杨立鹏, 顾宇阳, 田十宇, 杨晓光. 基于硫化物全固态锂离子电池混合正极的研究进展[J]. 化工学报, 2026, 77(4): 1621-1649

YANG Lipeng, GU Yuyang, TIAN Shiyu, YANG Xiaoguang. Recent advances in composite cathodes for sulfide-based all-solid-state lithium-ion batteries[J]. CIESC Journal, 2026, 77(4): 1621-1649
杨立鹏, 顾宇阳, 田十宇, 杨晓光. 基于硫化物全固态锂离子电池混合正极的研究进展[J]. 化工学报, 2026, 77(4): 1621-1649 DOI： 10.11949/0438-1157.20251089.

YANG Lipeng, GU Yuyang, TIAN Shiyu, YANG Xiaoguang. Recent advances in composite cathodes for sulfide-based all-solid-state lithium-ion batteries[J]. CIESC Journal, 2026, 77(4): 1621-1649 DOI： 10.11949/0438-1157.20251089.

摘要

硫化物全固态电池（ASSBs）因其能量密度高、安全性好，而成为最具前景的下一代电池技术之一。然而其电化学性能仍不尽如人意，特别是在高压正极、高质量负载条件下，混合正极内部存在固-固界面副反应的问题，并引发包括空间电荷层、体积膨胀、电子/离子传输等一系列问题，进而影响全固态电池性能。本文概述了目前对硫化物电池混合正极改性的研究现状，总结了材料表面改性（界面工程）、电解质改性（材料工程）、电极掺杂改性（部件工程）以及电极结构工程的相关发展现状及应用优势，并为下一步基于硫化物电解质的全固态锂电池混合正极的研发方向提出了建议。

Abstract

All-solid-state sulfide batteries (ASSBs) have become one of the most promising next-generation battery technologies due to their high energy density and good safety. However

their electrochemical performance still falls short of expectations

particularly under high-voltage cathodes and high-mass-loading conditions. Issues such as side reactions at solid-solid interfaces within the composite cathode can lead to problems including space charge layer formation

volume expansion

and hindered electron/ion transport

thereby compromising the overall performance of ASSBs. This article provides an overview of the current research progress on modifying composite cathodes in sulfide-based ASSBs. It summarizes recent advances in material surface modification (interface engineering)

electrolyte optimization (material engineering)

electrode doping and modification (component engineering)

and electrode structural engineering

highlighting their respective advantages and applications. Furthermore

it offers guidance for future research directions in the development of composite cathodes for sulfide-based all-solid-state lithium batteries.

关键词

Keywords

references

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