硫基光催化剂在高效光催化制氢中研究进展

张晨阳; 顾春鹏; 韩长存

doi:10.11949/0438-1157.20251084

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硫基光催化剂在高效光催化制氢中研究进展

综述与专论 | 更新时间：2026-06-18

- 硫基光催化剂在高效光催化制氢中研究进展
- Recent advances and perspectives on sulfide-based photocatalysts for hydrogen production
- 化工学报 2026年77卷第5期页码：2338-2358
- 作者机构：
  
  1.天津大学化工学院，天津 300354
  2.中国石油大学（北京）新能源与材料学院，北京 102249
  3.湖北工业大学理学院，湖北武汉 430068
- 作者简介：
  
  张晨阳（2004—），男，本科生，chenyang23579@tju.edu.cn
  顾春鹏（1984—），男，博士研究生，guchunpeng@student.cup.edu.cn
  韩长存（1986—），男，博士，副教授， hanchangcun@126.com
- 基金信息：
  
  国家自然科学基金项目(52103339)
- DOI：10.11949/0438-1157.20251084
  中图分类号： TQ 426.94
- 收稿：2025-09-28，
  
  修回：2025-11-26，
  
  纸质出版：2026-05-25
- 稿件说明：
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张晨阳, 顾春鹏, 韩长存. 硫基光催化剂在高效光催化制氢中研究进展[J]. 化工学报, 2026, 77(5): 2338-2358

ZHANG Chenyang, GU Chunpeng, HAN Changcun. Recent advances and perspectives on sulfide-based photocatalysts for hydrogen production[J]. CIESC Journal, 2026, 77(5): 2338-2358
张晨阳, 顾春鹏, 韩长存. 硫基光催化剂在高效光催化制氢中研究进展[J]. 化工学报, 2026, 77(5): 2338-2358 DOI： 10.11949/0438-1157.20251084.

ZHANG Chenyang, GU Chunpeng, HAN Changcun. Recent advances and perspectives on sulfide-based photocatalysts for hydrogen production[J]. CIESC Journal, 2026, 77(5): 2338-2358 DOI： 10.11949/0438-1157.20251084.

摘要

工业化的快速推进加剧了全球对能源消耗与碳排放的担忧，氢能因其燃烧产物仅为水、来源丰富且燃烧热值高成为绿色能源体系的关键组成部分。光催化分解水制氢作为一种极具潜力的氢能生产技术，其效率和实用性受可见光利用率低、光生电荷载流子快速复合等因素制约。硫基光催化剂凭借硫掺杂带来的优势，在光催化领域展现出显著潜力，可通过修饰材料能带结构来拓宽光响应范围、增强稳定性并抑制电荷复合。综述了硫基催化剂在光催化制氢中的最新研究进展，重点探讨了CdS、In

、ZnS、ZnIn

和CdZnS等典型硫基光催化剂的特性及改性策略，通过形貌工程、元素掺杂和负载助催化剂等手段，可有效提升光催化剂性能。本研究为开发高效、稳定的光催化制氢催化剂提供了理论基础，助力全球能源结构向绿色转型。

Abstract

The accelerated industrialization has intensified global co

ncerns over energy consumption and carbon emissions. Hydrogen energy

characterized by water-only combustion products

abundant availability

and high calorific value

constitutes a pivotal element in future energy systems. Photocatalytic water splitting represents a promising strategy for clean hydrogen production; however

its efficiency and practicality are limited by the constrained utilization of visible light and rapid recombination of photogenerated charges photocatalytic water splitting for hydrogen production is a highly promising hydrogen energy production technology

but its efficiency and practicality are limited by factors such as low visible light utilization and rapid recombination of photogenerated charge carriers. Sulfide-based catalysts leverage the advantages of sulfur doping to modify band structures

broadening the light response range

enhancing stability

and suppressing charge recombination. This review synthesizes recent advances in sulfide-based photocatalysts for hydrogen evolution

focusing on characteristic properties and modification approaches for representative systems including CdS

ZnS

ZnIn

and CdZnS. Performance enhancements are achieved through morphology engineering

elemental doping

and cocatalyst integration. Through the design of sulfur vacancies

the cyclic regeneration of sulfide-based materials is achieved

reducing reliance on precious metals

which aligns with the sustainability requirements for renewable materials. Collectively

this work establishes fundamental principles for developing efficient

stable photocatalytic systems

paving the way toward sustainable energy infrastructure transformation.

关键词

Keywords

references

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