中国石油大学(北京)重质油全国重点实验室,北京 102249
刘继坤(1999—),男,博士研究生,liuji_kun@163.com
韩晔华(1984—),女,博士,教授,hanyehua@cup.edu.cn
收稿:2025-09-15,
修回:2025-11-03,
纸质出版:2026-01-25
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刘继坤, 包若凝, 蓝兴英, 徐春明, 韩晔华. 微纳米气泡及其气-液界面特性[J]. 化工学报, 2026, 77(1): 1-15
LIU Jikun, BAO Ruoning, LAN Xingying, XU Chunming, HAN Yehua. Micro-nano bubble and its gas-liquid interface characteristics[J]. CIESC Journal, 2026, 77(1): 1-15
刘继坤, 包若凝, 蓝兴英, 徐春明, 韩晔华. 微纳米气泡及其气-液界面特性[J]. 化工学报, 2026, 77(1): 1-15 DOI: 10.11949/0438-1157.20251039.
LIU Jikun, BAO Ruoning, LAN Xingying, XU Chunming, HAN Yehua. Micro-nano bubble and its gas-liquid interface characteristics[J]. CIESC Journal, 2026, 77(1): 1-15 DOI: 10.11949/0438-1157.20251039.
微纳米气泡(micro-nano bubbles, MNBs)是指分散于水相、油相或固体基质中,特征尺寸处于微米级至纳米级范围的气泡。与毫米级气泡相比,微纳米气泡具有高比表面积、优异稳定性以及自发产生活性氧(ROS)等独特性质。高比表面积赋予了微纳米气泡体系极高的气-液界面密度,结合其优异稳定性可显著提高气-液传质效率,在化工过程强化、药物靶向输送及土壤修复等领域展现出巨大的应用潜力。微纳米气泡在气-液界面处自发产生的活性氧能够高效降解有机污染物,在废水处理领域展现出显著优势。此类活性氧还可进一步作为绿色合成反应中的活性中间体,在温和条件下实现多种高附加值化学品的高效合成。微纳米气泡从“强化传质”到“界面合成”的跨越,标志着该技术步入全新发展阶段。这一突破为开发清洁、绿色的化学工艺提供了新策略,具有重大的科学与工业价值。
Micro-nano bubbles (MNBs) are bubbles with characteristic sizes ranging from micrometers to nanometers
dispersed in aqueous
oil
or solid matrices. Compared to millimeter-scale bubbles
MNBs possess unique properties such as high specific surface area
exceptional stability
and the ability to spontaneously generate reactive oxygen species (ROS). The high specific surface area endows MNBs systems with an exceptionally dense gas-liquid interface. Combined with outstanding stability
this feature significantly enhances gas-liquid mass transfer efficiency
demonstrating immense application potential in chemical hydrogenation
targeted drug delivery
and soil remediation. Additionally
the spontaneously generated ROS at the gas-liquid interface of MNBs can efficiently degrade organic pollutants
offering considerable advantages in wastewater treatment. These reactive oxygen species can also serve as active intermediates in green synthesis reactions
enabling the efficient synthesis of various high-value-added chemicals under mild conditions. The significant leap of MNBs from "mass transfer enhancement" to "interfacial reaction synthesis" represents a new developmental stage for this technology
providing novel strategies for developing cleaner and greener chemical processes with substantial scientific and industrial value.
Wang Y W , Wang T X . Preparation method and application of nanobubbles: a review [J ] . Coatings , 2023 , 13 ( 9 ): 1510 .
Temesgen T , Bui T T , Han M , et al . Micro and nanobubble technologies as a new horizon for water-treatment techniques: a review [J ] . Advances in Colloid and Interface Science , 2017 , 246 : 40 - 51 .
Agarwal A , Ng W J , Liu Y . Principle and applications of microbubble and nanobubble technology for water treatment [J ] . Chemosphere , 2011 , 84 ( 9 ): 1175 - 1180 .
Takahashi M , Chiba K , Li P . Free-radical generation from collapsing microbubbles in the absence of a dynamic stimulus [J ] . The Journal of Physical Chemistry B , 2007 , 111 ( 6 ): 1343 - 1347 .
Swart B , Zhao Y B , Khaku M , et al . In situ characterisation of size distribution and rise velocity of microbubbles by high-speed photography [J ] . Chemical Engineering Science , 2020 , 225 : 115836 .
Tesař V . Microbubble smallness limited by conjunctions [J ] . Chemical Engineering Journal , 2013 , 231 : 526 - 536 .
Brittle S , Desai P , Ng W C , et al . Minimising microbubble size through oscillation frequency control [J ] . Chemical Engineering Research and Design , 2015 , 104 : 357 - 366 .
Tesař V . Mechanisms of fluidic microbubble generation (Part Ⅱ): Suppressing the conjunctions [J ] . Chemical Engineering Science , 2014 , 116 : 849 - 856 .
Achar J C , Nam G , Jung J , et al . Microbubble ozonation of the antioxidant butylated hydroxytoluene: degradation kinetics and toxicity reduction [J ] . Environmental Research , 2020 , 186 : 109496 .
Seddon J R T , Lohse D , Ducker W A , et al . A deliberation on nanobubbles at surfaces and in bulk [J ] . ChemPhysChem , 2012 , 13 ( 8 ): 2179 - 2187 .
Luo J , Xu W L , Li R . Collapse of cavitation bubbles near air bubbles [J ] . Journal of Hydrodynamics , 2020 , 32 ( 5 ): 929 - 941 .
Yasui K , Tuziuti T , Iida Y . Dependence of the characteristics of bubbles on types of sonochemical reactors [J ] . Ultrasonics Sonochemistry , 2005 , 12 ( 1 ): 43 - 51 .
Jia J G , Zhu Z X , Chen H , et al . Full life circle of micro-nano bubbles: generation, characterization and applications [J ] . Chemical Engineering Journal , 2023 , 471 : 144621 .
Li H Z , Hu L M , Xia Z R . Impact of groundwater salinity on bioremediation enhanced by micro-nano bubbles [J ] . Materials , 2013 , 6 ( 9 ): 3676 - 3687 .
Kim J Y , Song M G , Kim J D . Zeta potential of nanobubbles generated by ultrasonication in aqueous alkyl polyglycoside solutions [J ] . Journal of Colloid and Interface Science , 2000 , 223 ( 2 ): 285 - 291 .
Oeffinger B E , Wheatley M A . Development and characterization of a nano-scale contrast agent [J ] . Ultrasonics , 2004 , 42 ( 1 ): 343 - 347 .
Nazari S , Hassanzadeh A , He Y Q , et al . Recent developments in generation, detection and application of nanobubbles in flotation [J ] . Minerals , 2022 , 12 ( 4 ): 462 .
Daryabor M , Ahmadi A , Zilouei H . Solvent extraction of cadmium and zinc from sulphate solutions: comparison of mechanical agitation and ultrasonic irradiation [J ] . Ultrasonics Sonochemistry , 2017 , 34 : 931 - 937 .
Shams M , Dehghani M H , Nabizadeh R , et al . Adsorption of phosphorus from aqueous solution by cubic zeolitic imidazolate framework-8: modeling, mechanical agitation versus sonication [J ] . Journal of Molecular Liquids , 2016 , 224 : 151 - 157 .
Hettiarachchi K , Talu E , Longo M L , et al . On-chip generation of microbubbles as a practical technology for manufacturing contrast agents for ultrasonic imaging [J ] . Lab on a Chip , 2007 , 7 ( 4 ): 463 - 468 .
Pancholi K P , Farook U , Moaleji R , et al . Novel methods for preparing phospholipid coated microbubbles [J ] . European Biophysics Journal , 2008 , 37 ( 4 ): 515 - 520 .
Dollet B , van Hoeve W , Raven J P , et al . Role of the channel geometry on the bubble pinch-off in flow-focusing devices [J ] . Physical Review Letters , 2008 , 100 ( 3 ): 034504 .
Sattari A , Hanafizadeh P , Hoorfar M . Multiphase flow in microfluidics: from droplets and bubbles to the encapsulated structures [J ] . Advances in Colloid and Interface Science , 2020 , 282 : 102208 .
Huang J , Yao Z H . Influencing factors and size prediction of bubbles formed by flow focusing in a cross-channel [J ] . Chemical Engineering Science , 2022 , 248 : 117228 .
Zhan Q C , Shi X Q , Fan D , et al . Solvent mixing generating air bubbles as a template for polydopamine nanobowl fabrication: underlying mechanism, nanomotor assembly and application in cancer treatment [J ] . Chemical Engineering Journal , 2021 , 404 : 126443 .
Qiu J , Zou Z L , Wang S , et al . Formation and stability of bulk nanobubbles generated by ethanol-water exchange [J ] . ChemPhysChem , 2017 , 18 ( 10 ): 1345 - 1350 .
Tang J , Bai X , Huang H L , et al . Templating synthesis of oxime/amidoxime functionalized hollow nanospheres by air bubbles generated from "Ouzo-Like" effect for fast and massive uranium uptake [J ] . Separation and Purification Technology , 2023 , 306 : 122463 .
Bai X , Liu J X , Xu Y H , et al . CO 2 Pickering emulsion in water templated hollow porous sorbents for fast and highly selective uranium extraction [J ] . Chemical Engineering Journal , 2020 , 387 : 124096 .
Bai X , Wang Y , Li H , et al . Stalagmites in karst cave inspired construction: lotus root-type adsorbent with porous surface derived f rom CO 2 -in-water Pickering emulsion for selective and ultrafast uranium extraction [J ] . Journal of Hazardous Materials , 2021 , 419 : 126398 .
Zhu P W , Wang Y , Bai X , et al . CO 2 -in-water Pickering emulsion-assisted polymerization-induced self-assembly of raspberry-like sorbent microbeads for uranium adsorption [J ] . Separation and Purification Technology , 2021 , 279 : 119710 .
Xia Z R , Hu L M . Treatment of organics contaminated wastewater by ozone micro-nano-bubbles [J ] . Water , 2019 , 11 ( 1 ): 55 .
Xu Q Y , Nakajima M , Ichikawa S , et al . A comparative study of microbubble generation by mechanical agitation and sonication [J ] . Innovative Food Science & Emerging Technologies , 2008 , 9 ( 4 ): 489 - 494 .
Li Y F , Yang G Q , Yu S L , et al . In-situ investigation and modeling of electrochemical reactions with simultaneous oxygen and hydrogen microbubble evolutions in water electrolysis [J ] . International Journal of Hydrogen Energy , 2019 , 44 ( 52 ): 28283 - 28293 .
Chen Q J , Zhao J , Deng X L , et al . Single-entity electrochemistry of nano- and microbubbles in electrolytic gas evolution [J ] . The Journal of Physical Chemistry Letters , 2022 , 13 ( 26 ): 6153 - 6163 .
Xu Q , Liang L , Nie T F , et al . Effect of electrolyte pH on oxygen bubble behavior in photoelectrochemical water splitting [J ] . The Journal of Physical Chemistry C , 2023 , 127 ( 11 ): 5308 - 5320 .
Lu J S , Huang X J , Zhang Z Q , et al . Co-coagulation of micro-nano bubbles (MNBs) for enhanced drinking water treatment: a study on the efficiency and mechanism of a novel cleaning process [J ] . Water Research , 2022 , 226 : 119245 .
Asakuma Y , Munenaga T , Nakata R . Observation of bubble formation in water during microwave irradiation by dynamic light scattering [J ] . Heat and Mass Transfer , 2016 , 52 ( 9 ): 1833 - 1840 .
Hassan P A , Rana S , Verma G . Making sense of Brownian motion: colloid characterization by dynamic light scattering [J ] . Langmuir , 2015 , 31 ( 1 ): 3 - 12 .
Hao R , Fan Y S , Howard M D , et al . Imaging nanobubble nucleation and hydrogen spillover during electrocatalytic water splitting [J ] . PNAS , 2018 , 115 ( 23 ): 5878 - 5883 .
Karpitschka S , Dietrich E , Seddon J R T , et al . Nonintrusive optical visualization of surface nanobubbles [J ] . Physical Review Letters , 2012 , 109 ( 6 ): 066102 .
Midtvedt D , Eklund F , Olsén E , et al . Size and refractive index determination of subwavelength particles and air bubbles by holographic nanoparticle tracking analysis [J ] . Analytical Chemistry , 2020 , 92 ( 2 ): 1908 - 1915 .
Zhang W , Wang J F , Li B , et al . Experimental investigation on bubble coalescence regimes under non-uniform electric field [J ] . Chemical Engineering Journal , 2021 , 417 : 127982 .
Tanimura Y , Yoshida K , Watanabe Y . A study on cleaning ability of oscillating bubbles driven by low-frequency ultrasound [J ] . Japanese Journal of Applied Physics , 2010 , 49 ( 7S ): 07 HE20.
Oh S H , Kim J M . Generation and stability of bulk nanobubbles [J ] . Langmuir , 2017 , 33 ( 15 ): 3818 - 3823 .
Ohgaki K , Khanh N Q , Joden Y , et al . Physicochemical approach to nanobubble solutions [J ] . Chemical Engineering Science , 2010 , 65 ( 3 ): 1296 - 1300 .
Zhou L M , Wang X Y , Shin H J , et al . Ultrahigh density of gas molecules confined in surface nanobubbles in ambient water [J ] . Journal of the American Chemical Society , 2020 , 142 ( 12 ): 5583 - 5593 .
Ke S , Xiao W , Quan N N , et al . Formation and stability of bulk nanobubbles in different solutions [J ] . Langmuir , 2019 , 35 ( 15 ): 5250 - 5256 .
Popov E , He L L , Dominguez-Ontiveros E , et al . Detection of vapor nanobubbles by small angle neutron scattering (SANS) [J ] . Applied Physics Letters , 2018 , 112 ( 15 ): 153704 .
Zhou L M , Wang S , Zhang L J , et al . Generation and stability of bulk nanobubbles: a review and perspective [J ] . Current Opinion in Colloid & Interface Science , 2021 , 53 : 101439 .
Wei W , Chu F J , Chen G R , et al . Prebiotic formation of peptides through bubbling and arc plasma [J ] . Chemistry-A European Journal , 2024 , 30 ( 42 ): e202401809 .
Song X X , Wan Y Y , Yang Q , et al . Electrode fouling by gas bubbles enables catalyst-free hydrogen peroxide synthesis [J ] . Journal of the American Chemical Society , 2025 , 147 ( 26 ): 22864 - 22872 .
Zhang Z H , Wang S M , Cheng L N , et al . Micro-nano-bubble technology and its applications in food industry: a critical review [J ] . Food Reviews International , 2023 , 39 ( 7 ): 4213 - 4235 .
Jia M Y , Farid M U , Kharraz J A , et al . Nanobubbles in water and wastewater treatment systems: small bubbles making big difference [J ] . Water Research , 2023 , 245 : 120613 .
Zhang X H , Maeda N , Craig V S J . Physical properties of nanobubbles on hydrophobic surfaces in water and aqueous solutions [J ] . Langmuir , 2006 , 22 ( 11 ): 5025 - 5035 .
Sakr M , Mohamed M M , Maraqa M A , et al . A critical review of the recent developments in micro-nano bubbles applications for domestic and industrial wastewater treatment [J ] . Alexandria Engineering Journal , 2022 , 61 ( 8 ): 6591 - 6612 .
Li H Z , Hu L M , Song D J , et al . Characteristics of micro-nano bubbles and potential application in groundwater bioremediation [J ] . Water Environment Research , 2014 , 86 ( 9 ): 844 - 851 .
Li H Z , Hu L M , Song D J , et al . Subsurface transport behavior of micro-nano bubbles and potential applications for groundwater remediation [J ] . International Journal of Environmental Research and Public Health , 2014 , 11 ( 1 ): 473 - 486 .
Wang T Z , Yang C , Sun P Z , et al . Generation mechanism of hydroxyl free radicals in micro-nanobubbles water and its prospect in drinking water [J ] . Processes , 2024 , 12 ( 4 ): 683 .
Shen D S , Xie Z M , Shentu J , et al . Enhanced oxidation of aromatic hydrocarbons by ozone micro-nano bubble water: mechanism and influencing factors [J ] . Journal of Environmental Chemical Engineering , 2023 , 11 ( 3 ): 110281 .
Jin N , Zhang F H , Cui Y , et al . Environment-friendly surface cleaning using micro-nano bubbles [J ] . Particuology , 2022 , 66 : 1 - 9 .
Tan K A , Mohan Y , Liew K J , et al . Development of an effective cleaning method for metallic parts using microbubbles [J ] . Journal of Cleaner Production , 2020 , 261 : 121076 .
Jia W H , Ren S L , Hu B . Effect of water chemistry on zeta potential of air bubbles [J ] . International Journal of Electrochemical Science , 2013 , 8 ( 4 ): 5828 - 5837 .
Takahashi M . ζ potential of microbubbles in aqueous solutions: electrical properties of the gas-water interface [J ] . The Journal of Physical Chemistry B , 2005 , 109 ( 46 ): 21858 - 21864 .
Ushikubo F Y , Furukawa T , Nakagawa R , et al . Evidence of the existence and the stability of nano-bubbles in water [J ] . Colloids and Surfaces A: Physicochemical and Engineering Aspects , 2010 , 361 ( 1 ): 31 - 37 .
Nosaka Y , Nosaka A Y . Generation and detection of reactive oxygen species in photocatalysis [J ] . Chemical Reviews , 2017 , 117 ( 17 ): 11302 - 11336 .
Liu S , Oshita S , Kawabata S , et al . Identification of ROS produced by nanobubbles and their positive and negative effects on vegetable seed germination [J ] . Langmuir , 2016 , 32 ( 43 ): 11295 - 11302 .
Takahashi M , Shirai Y , Sugawa S . Free-radical generation from bulk nanobubbles in aqueous electrolyte solutions: ESR spin-trap observation of microbubble-treated water [J ] . Langmuir , 2021 , 37 ( 16 ): 5005 - 5011 .
Takahashi M , Chiba K , Li P . Formation of hydroxyl radicals by collapsing ozone microbubbles under strongly acidic conditions [J ] . The Journal of Physical Chemistry B , 2007 , 111 ( 39 ): 11443 - 11446 .
Nami-Ana S F , Mehrgardi M A , Mofidfar M , et al . Sustained regeneration of hydrogen peroxide at the water-gas interface of electrogenerated microbubbles on an electrode surface [J ] . Journal of the American Chemical Society , 2024 , 146 ( 46 ): 31945 - 31949 .
Takahashi M , Ishikawa H , Asano T , et al . Effect of microbubbles on ozonized water for photoresist removal [J ] . The Journal of Physical Chemistry C , 2012 , 116 ( 23 ): 12578 - 12583 .
Fan W , An W G , Huo M X , et al . Solubilization and stabilization for prolonged reactivity of ozone using micro-nano bubbles and ozone-saturated solvent: a promising enhancement for ozonation [J ] . Separation and Purification Technology , 2020 , 238 : 116484 .
Zeng W , Jia C , Luo H X , et al . Microbubble-dominated mass transfer intensification in the process of ammonia-based flue gas desulfurization [J ] . Industrial & Engineering Chemistry Research , 2020 , 59 ( 44 ): 19781 - 19792 .
Wang X Y , Zhu Y L , Shuai Y , et al . Bubble size "bimodal" distribution enhances mixing and mass transfer in slurry bubbling column reactor [J ] . Industrial & Engineering Chemistry Research , 2024 , 63 ( 16 ): 7401 - 7414 .
Yao Z P , Chen C X , Wang T , et al . Effects of gas distributor on hydrodynamics in gas-liquid bubble column by visual experiments and CFD simulations [J ] . Chemical Engineering Journal , 2025 , 504 : 158476 .
田洪舟 , 杨高东 , 杨国强 , 等 . 微界面强化重油浆态床低压加氢的传质基础 [J ] . 化工学报 , 2020 , 71 ( 11 ): 4927 - 4935 .
Tian H Z , Yang G D , Yang G Q , et al . Mass transfer basis of low-pressure hydrogenation for heavy oil in microinterface-intensified slurry-bed reactor [J ] . CIESC Journal , 2020 , 71 ( 11 ): 4927 - 4935 .
吴梦思 , 田洪舟 , 丁方园 , 等 . 微界面强化柴油加氢脱硫过程的模拟计算研究 [J ] . 南京大学学报(自然科学) , 2022 , 58 ( 4 ): 706 - 712 .
Wu M S , Tian H Z , Ding F Y , et al . Simulation study on micro-interface intensified diesel hydrodesulfurization process [J ] . Journal of Nanjing University (Natural Science) , 2022 , 58 ( 4 ): 706 - 712 .
Janajreh I , ElSamad T , Noorul Hussain M . Intensification of transesterification via sonication numerical simulation and sensitivity study [J ] . Applied Energy , 2017 , 185 : 2151 - 2159 .
张晓国 , 谢清峰 , 李思 , 等 . 喷气燃料FITS加氢技术的工业应用 [J ] . 炼油技术与工程 , 2017 ( 9 ): 21 - 24 .
Zhang X G , Xie Q F , Li S , et al . Commercial application of FITS hydrotreating technology for jet fuel [J ] . Petroleum Refinery Engineering , 2017 ( 9 ): 21 - 24 .
谢清峰 , 夏登刚 , 姚峰 , 等 . 重整生成油全馏分FITS加氢脱烯烃技术的应用 [J ] . 炼油技术与工程 , 2016 , 46 ( 1 ): 7 - 12 .
Xie Q F , Xia D G , Yao F , et al . Application of FITS hydrogenation process for olefin removal of full fraction of reformate [J ] . Petroleum Refinery Engineering , 2016 , 46 ( 1 ): 7 - 12 .
Li H , Zhang Y , Shu H , et al . Highlights in ultrasound-targeted microbubble destruction-mediated gene/drug delivery strategy for treatment of malignancies [J ] . International Journal of Pharmaceutics , 2022 , 613 : 121412 .
李兆军 , 杜浩 . 我国微细气泡技术发展综述 [J ] . 过程工程学报 , 2017 , 17 ( 4 ): 655 - 663 .
Li Z J , Du H . Review of the development of fine bubble technology in China [J ] . The Chinese Journal of Process Engineering , 2017 , 17 ( 4 ): 655 - 663 .
Matsumoto Y , Allen J S , Yoshizawa S , et al . Medical ultrasound with microbubbles [J ] . Experimental Thermal and Fluid Science , 2005 , 29 ( 3 ): 255 - 265 .
Zhang H G , Lyu T , Bi L , et al . Combating hypoxia/anoxia at sediment-water interfaces: a preliminary study of oxygen nanobubble modified clay materials [J ] . Science of the Total Environment , 2018 , 637 : 550 - 560 .
Hu L M , Xia Z R . Application of ozone micro-nano-bubbles to groundwater remediation [J ] . Journal of Hazardous Materials , 2018 , 342 : 446 - 453 .
Xia Z R , Hu L M . Remediation of organics contaminated groundwater by ozone micro-nano bubble [J ] . Japanese Geotechnical Society Special Publication , 2016 , 2 ( 57 ): 1978 - 1981 .
Li P , Takahashi M , Chiba K . Degradation of phenol by the collapse of microbubbles [J ] . Chemosphere , 2009 , 75 ( 10 ): 1371 - 1375 .
Wang X K , Wang J G , Guo P Q , et al . Chemical effect of swirling jet-induced cavitation: degradation of rhodamine B in aqueous solution [J ] . Ultrasonics Sonochemistry , 2008 , 15 ( 4 ): 357 - 363 .
Wang X K , Zhang Y . Degradation of alachlor in aqueous solution by using hydrodynamic cavitation [J ] . Journal of Hazardous Materials , 2009 , 161 ( 1 ): 202 - 207 .
Kim I , Huang C . Sonochemical degradation of polycyclic aromatic sulfur hydrocarbons (PASHs) in aqueous solutions exemplified by benzothiophene [J ] . Journal of the Chinese Institute of Engineers , 2005 , 28 ( 7 ): 1107 - 1118 .
Jabesa A , Ghosh P . Removal of diethyl phthalate from water by ozone microbubbles in a pilot plant [J ] . Journal of Environmental Management , 2016 , 180 : 476 - 484 .
Xing D , Yuan X , Liang C Y , et al . Spontaneous oxidation of I - in water microdroplets and its atmospheric implications [J ] . Chemical Communications , 2022 , 58 ( 89 ): 12447 - 12450 .
Jin S H , Zhu C H , Zhang J Z , et al . Single-electron-mediated redox processes at the air-water interface of water microdroplets [J ] . Scientia Sinica Chimica , 2024 , 54 ( 1 ): 59 - 72 .
Xing D , Meng Y F , Yuan X , et al . Capture of hydroxyl radicals by hydronium cations in water microdroplets [J ] . Angewandte Chemie International Edition , 2022 , 61 ( 33 ): e202207587 .
Gong K , Meng Y F , Zare R N , et al . Molecular mechanism for converting carbon dioxide surrounding water microdroplets containing 1, 2, 3-triazole to formic acid [J ] . Journal of the American Chemical Society , 2024 , 146 ( 12 ): 8576 - 8584 .
Chen H , Wang R J , Xu J H , et al . Spontaneous reduction by one electron on water microdroplets facilitates direct carboxylation with CO 2 [J ] . Journal of the American Chemical Society , 2023 , 145 ( 4 ): 2647 - 2652 .
Bose S , Mofidfar M , Zare R N . Direct conversion of N 2 and air to nitric acid in gas-water microbubbles [J ] . Journal of the American Chemical Society , 2024 , 146 ( 40 ): 27964 - 27971 .
Li J , Xu J H , Song Q Y , et al . Methane C(sp 3 )—H bond activation by water microbubbles [J ] . Chemical Science , 2024 , 15 ( 41 ): 17026 - 17031 .
Bose S , Mehrgardi M A , Zare R N . Selective photochemical conversion of carbon dioxide to formic acid at gas-water interface of microbubbles [J ] . Journal of the American Chemical Society , 2025 , 147 ( 31 ): 27449 - 27457 .
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