电子效应精准调控的纳米金催化剂在低碳多元醇选择性氧化研究进展

赵明月; 孟凡宇; 闫昊; 冯翔; 刘熠斌; 陈小博; 杨朝合; 陈德

doi:10.11949/0438-1157.20251015

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电子效应精准调控的纳米金催化剂在低碳多元醇选择性氧化研究进展

综述与专论 | 更新时间：2026-06-18

- 电子效应精准调控的纳米金催化剂在低碳多元醇选择性氧化研究进展
- Progress in research of selective oxidation of low carbon polyols over nano-Au catalysts with precise electronic effect regulation
- 化工学报 2026年77卷第5期页码：2322-2337
- 作者机构：
  
  1.中国石油大学（华东）重质油全国重点实验室，山东青岛 266580
  2.挪威科技大学，挪威特隆赫姆 7491
- 作者简介：
  
  赵明月（1996—），女，博士研究生，2965155534@qq.com
  闫昊（1993—），男，博士，副教授，haoyan@upc.edu.cn
  冯翔（1988—），男，博士，教授，xiangfeng@upc.edu.cn
- 基金信息：
  
  国家自然科学基金项目(22108305);山东省自然科学基金(ZR2023YQ009);山东省泰山学者专项基金项目(tsqn202408101);中央高校基本科研业务费专项(25CX06002A)
- DOI：10.11949/0438-1157.20251015
  中图分类号： TQ 426;O 643.3
- 收稿：2025-09-09，
  
  修回：2025-10-29，
  
  纸质出版：2026-05-25
- 稿件说明：
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赵明月, 孟凡宇, 闫昊, 冯翔, 刘熠斌, 陈小博, 杨朝合, 陈德. 电子效应精准调控的纳米金催化剂在低碳多元醇选择性氧化研究进展[J]. 化工学报, 2026, 77(5): 2322-2337

ZHAO Mingyue, MENG Fanyu, YAN Hao, FENG Xiang, LIU Yibin, CHEN Xiaobo, YANG Chaohe, CHEN De. Progress in research of selective oxidation of low carbon polyols over nano-Au catalysts with precise electronic effect regulation[J]. CIESC Journal, 2026, 77(5): 2322-2337
赵明月, 孟凡宇, 闫昊, 冯翔, 刘熠斌, 陈小博, 杨朝合, 陈德. 电子效应精准调控的纳米金催化剂在低碳多元醇选择性氧化研究进展[J]. 化工学报, 2026, 77(5): 2322-2337 DOI： 10.11949/0438-1157.20251015.

ZHAO Mingyue, MENG Fanyu, YAN Hao, FENG Xiang, LIU Yibin, CHEN Xiaobo, YANG Chaohe, CHEN De. Progress in research of selective oxidation of low carbon polyols over nano-Au catalysts with precise electronic effect regulation[J]. CIESC Journal, 2026, 77(5): 2322-2337 DOI： 10.11949/0438-1157.20251015.

摘要

低碳多元醇（来源于石油、煤或生物质）的选择性氧化是制备乙醇酸、甘油酸等高附加值化学品的关键途径。开发以分子氧为氧化剂的高效绿色催化工艺，对实现多元醇高值化转化及促进高端化工产业链绿色升级具有重要意义，其核心在于开发高性能负载型催化剂。本文系统综述了以电子效应精准调控为核心的纳米金催化剂在伯羟基氧化制羧酸、仲羟基氧化制酮及C—C键断裂制短链酸三大路径的研究进展，重点分析载体工程与双金属协同策略如何通过调变金的电子结构解决羟基选择性活化、过度氧化抑制等关键问题，探讨了电子结构与催化性能之间构效关系及反应机理，并对未来催化剂设计方向与潜在应用前景进行了展望，为绿色催化工艺的开发提供理论依据与技术参考。

Abstract

Selective oxidation of low-carbon polyols (derived from petroleum

coal or biomass) is a key approach for preparing high-value chemicals such as glycolic acid and glyceric acid. The development of efficient and green catalytic processes using molecular oxygen as the oxidant is of great significance for achieving high-value conversion of polyols and promoting the green upgrading of the high-end chemical industry chain. The core lies in the development of high-performance supported catalysts. In this paper

recent advances regarding the nano-gold catalysts with precise electronic effect modulation as the core for conversion of primary hydroxyl groups to carboxylic acids

secondary hydroxyl groups to ketones

and C—C bond cleavage to short-chain acids. It focuses on how support engineering and bimetallic synergistic strategies can address key issues such as selective activation of hydroxyl groups and inhibition of excessive oxidation by modulating the electronic structure of gold. The structure-activity relationships between electronic properties and catalytic performance are discussed

along with associated reaction mechanisms. Future directions for catalyst design and potential applications are also prospected

offering theoretical and practical guidance for the development of sustainable catalytic processes.

关键词

Keywords

references

王雪鹏 . 草酸二甲酯加氢制备乙二醇催化剂稳定性研究 [D ] . 金华 : 浙江师范大学 , 2020 .

Wang X P . Study on stability of catalyst for hydrogenation of dimethyl oxalate to ethylene glycol [D ] . Jinhua : Zhejiang Normal University , 2020 .

Taniguchi I , Yoshida S , Hiraga K , et al . Biodegradation of PET: current status and application aspects [J ] . ACS Catalysis , 2019 , 9 ( 5 ): 4089 - 4105 .

Yue H R , Zhao Y J , Ma X B , et al . Ethylene glycol: properties, synthesis, and applications [J ] . Chemical Society Reviews , 2012 , 41 ( 11 ): 4218 - 4244 .

Xia R , Chen Y Q , Chang Y X , et al . Electrosynthesis of ethylene glycol from ethylene coupled with CO 2 capture [J ] . Nature Catalysis , 2025 , 8 ( 8 ): 833 - 842 .

Sun Y L , Chai G L . Direct synthesis of ethylene glycol from syngas [J ] . ChemistrySelect , 2022 , 7 ( 6 ): e202103642 .

Fan L , Zhao Y L , Chen L , et al . Selective production of ethylene glycol at high rate via cascade catalysis [J ] . Nature Catalysis , 2023 , 6 ( 7 ): 585 - 595 .

Zhu Z Y , Li W W , Wang D , et al . Constructing a new pathway for ethylene glycol biosynthesis and its coenzyme reuse mechanism [J ] . Fermentation , 2024 , 10 ( 11 ): 558 .

竺方欢 , 岑雪聪 , 陈振 . 微生物合成二元醇研究进展 [J ] . 合成生物学 , 2024 , 5 ( 6 ): 1367 - 1385 .

Zhu F H , Cen X C , Chen Z . Research progress of diols production by microbes [J ] . Synthetic Biology Journal , 2024 , 5 ( 6 ): 1367 - 1385 .

季旭 . 磷酸转酮酶定向进化及3-羟基丙酸生产应用 [D ] . 北京 : 北京化工大学 , 2021 .

Ji X . Directed evolution of phosphoketolase and applications of 3-hydroxypropionic acid production [D ] . Beijing : Beijing University of Chemical Technology , 2021 .

吴云 . 不同预处理方式对生物基多元醇制备的影响 [D ] . 马鞍山 : 安徽工业大学 , 2019 .

Wu Y . Effect of different pretreatment methods on preparation of bio-based polyols [D ] . Ma'anshan : Anhui University of Technology , 2019 .

Yan H , Yao S , Liang W , et al . Ni-Co oxide catalysts with lattice distortions for enhanced oxidation of glycerol to glyceric acid [J ] . Journal of Catalysis , 2020 , 381 : 248 - 260 .

Yan H , Yao S , Yin B , et al . Synergistic effects of bimetallic PtRu/MCM-41 nanocatalysts for glycerol oxidation in base-free medium: structure and electronic coupling dependent activity [J ] . Applied Catalysis B: Environmental , 2019 , 259 : 118070 .

Yan H , Qin H , Feng X , et al . Synergistic Pt/MgO/SBA-15 nanocatalysts for glycerol oxidation in base-free medium: catalyst design and mechanistic study [J ] . Journal of Catalysis , 2019 , 370 : 434 - 446 .

Yan H , Yao S , Zhao S M , et al . Insight into the basic strength-dependent catalytic performance in aqueous phase oxidation of glycerol to glyceric acid [J ] . Chemical Engineering Science , 2021 , 230 : 116191 .

Yan H , Yao S , Wang J Y , et al . Engineering Pt-Mn 2 O 3 interface to boost selective oxidation of ethylene glycol to glycolic acid [J ] . Applied Catalysis B: Environmental , 2021 , 284 : 119803 .

Yan H , Shen Q , Sun Y H , et al . Tailoring facets of α-Mn 2 O 3 microcrystalline catalysts for enhanced selective oxidation of glycerol to glycolic acid [J ] . ACS Catalysis , 2021 , 11 ( 11 ): 6371 - 6383 .

Yan H , Zhao M Y , Feng X , et al . <math id="M2"><mi mathvariant="normal">P</mi><msubsup><mrow><mi mathvariant="normal">O</mi></mrow><mrow><mn mathvariant="normal">4</mn></mrow><mrow><mn mathvariant="normal">3</mn><mtext> </mtext><mo>-</mo></mrow></msubsup></math> https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=110718100&type= https://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=110718122&type= 5.50333309 3.13266683 coordinated robust single-atom platinum catalyst for selective polyol oxidation [J ] . Angewandte Chemie International Edition , 2022 , 61 ( 21 ): e202116059 .

Zhao M Y , Yan H , Lu R L , et al . Insight into the selective oxidation mechanism of glycerol to 1, 3-dihydroxyacetone over AuCu–ZnO interface [J ] . AIChE Journal , 2022 , 68 ( 11 ): e17833 .

Yan H , Li J , Rao Z Q , et al . Fully exposed Pt n cluster catalysts enable cascade oxidation of polyol to dicarboxylic acid [J ] . Nature Communications , 2025 , 16 : 7030 .

Song Z N , Yan H , Yuan J C , et al . Engineering a coordinatively unsaturated Au-O-Ti 3+ structure toward unprecedented H 2 efficiency for low-temperature propene epoxidation with H 2 and O 2 [J ] . Engineering , 2023 , 9 ( 6 ): 144 - 156 .

Zhang Y S , Liu J X , Qian K , et al . Structure sensitivity of Au-TiO 2 strong metal-support interactions [J ] . Angewandte Chemie International Edition , 2021 , 60 ( 21 ): 12074 - 12081 .

Guo Z L , Jing G H , Tolba S A , et al . Design and construction of an O-Au-O coordination environment in Au single atom-doped Ti 4+ defected TiO 2 for an enhanced oxidative ability of lattice oxygen for Hg 0 oxidation [J ] . Chemical Engineering Journal , 2023 , 451: 138895..

Wang L , Xu W D , Yuan Z R , et al . Tannic acid assisted construction of Au-Ti integrated catalyst regulating the local environment of framework Ti toward propylene epoxidation under H 2 /O 2 [J ] . Molecular Catalysis , 2023 , 545 : 113206 .

Li Y C , Li X S , Zhu B , et al . Boosting low-temperature water gas shift reaction over Au/TiO 2 nanocatalyst activated by oxygen plasma [J ] . Chemical Engineering Journal , 2022 , 430 : 133013 .

Yao S Y , Zhang X , Zhou W , et al . Atomic-layered Au clusters on α-MoC as catalysts for the low-temperature water-gas shift reaction [J ] . Science , 2017 , 357 ( 6349 ): 389 - 393 .

Meng Y , Zou S H , Zhou Y H , et al . Activating molecular oxygen by Au/ZnO to selectively oxidize glycerol to dihydroxyacetone [J ] . Catalysis Science & Technology , 2018 , 8 ( 10 ): 2524 - 2528 .

陶伟 . Au/HAP、CuPd、CuPdAu纳米金属催化剂催化氧化1, 2-丙二醇制备乳酸研究 [D ] . 镇江 : 江苏大学 , 2021 .

Tao W . Study on the catalytic oxidation of 1, 2-propan diol tolactic acid over Au/HAP, CuPd and CuPdAu nano-metal catalysts [D ] . Zhenjiang : Jiangsu University , 2021 .

Redina E A , Kapustin G I , Tkachenko O P , et al . Effect of ultra-low amount of gold in oxide-supported bimetallic Au-Fe and Au-Cu catalysts on liquid-phase aerobic glycerol oxidation in water [J ] . Catalysis Science & Technology , 2021 , 11 ( 17 ): 5881 - 5897 .

Jouve A , Nagy G , Somodi F , et al . Gold-silver catalysts: effect of catalyst structure on the selectivity of glycerol oxidation [J ] . Journal of Catalysis , 2018 , 368 : 324 - 335 .

Pan Y N , Wu G D , He Y F , et al . Identification of the Au/ZnO interface as the specific active site for the selective oxidation of the secondary alcohol group in glycerol [J ] . Journal of Catalysis , 2019 , 369 : 222 - 232 .

Yan H , Qin H S , Liang W , et al . Enhanced performance of bimetallic PtCo/MCM-41 catalysts for glycerol oxidation in base-free medium [J ] . Catalysis Science & Technology , 2019 , 9 ( 18 ): 4909 - 4919 .

Xiong L Q , Yu Z N , Cao H C , et al . Converting glycerol into valuable trioses by Cu δ + -single-atom-decorated WO 3 under visible light [J ] . Angewandte Chemie International Edition , 2024 , 63 ( 12 ): e202318461 .

于志奕 , 方俊彦 , 陈文尧 , 等 . Pt-Bi界面结构调控及其催化甘油选择性氧化反应性能 [J ] . 化工学报 , 2024 , 75 ( 10 ): 3568 - 3578 .

Yu Z Y , Fang J Y , Chen W Y , et al . Regulation of Pt-Bi interfaces for selective catalytic oxidation of glycerol [J ] . CIESC Journal , 2024 , 75 ( 10 ): 3568 - 3578 .

de Nazaré de Oliveira A , Melchiorre M , Farias da Costa A A , et al . Glycerol: a green solvent for synthetic chemistry [J ] . Sustainable Chemistry and Pharmacy , 2024 , 41 : 101656 .

Ke J W , Chi M F , Zhao J K , et al . Dynamically reversible interconversion of molecular catalysts for efficient electrooxidation of propylene into propylene glycol [J ] . Journal of the American Chemical Society , 2023 , 145 ( 16 ): 9104 - 9111 .

Liu X C , Wang T , Zhang Z M , et al . Reaction mechanism and selectivity tuning of propene oxidation at the electrochemical interface [J ] . Journal of the American Chemical Society , 2022 , 144 ( 45 ): 20895 - 20902 .

李庆远 , 王超 , 许世佩 , 等 . PBS前体1, 4-丁二醇合成的反应工艺和催化剂研究进展 [J ] . 化工进展 , 2022 , 41 ( 11 ): 5771 - 5782 .

Li Q Y , Wang C , Xu S P , et al . Research progress on reaction process and catalysts for PBS precursor of 1, 4-butanediol synthesis [J ] . Chemical Industry and Engineering Progress , 2022 , 41 ( 11 ): 5771 - 5782 .

Zhu Y , Yang J M , Mei F , et al . Bio-based 1, 4-butanediol and tetrahydrofuran synthesis: perspective [J ] . Green Chemistry , 2022 , 24 ( 17 ): 6450 - 6466 .

Liu Y F , Wang W , Zeng A P . Biosynthesizing structurally diverse diols via a general route combining oxidative and reductive formations of OH-groups [J ] . Nature Communications , 2022 , 13 : 1595 .

Torbina V V , Nedoseykina N S , Ivanchikova I D , et al . Propylene glycol oxidation with hydrogen peroxide over Zr-containing metal-organic framework UiO-66 [J ] . Catalysis Today , 2019 , 333 : 47 - 53 .

Lin H , Xu J Y , Sun W L , et al . Efficient 1-hydroxy-2-butanone production from 1, 2-butanediol by whole cells of engineered E. coli [J ] . Catalysts , 2021 , 11 ( 10 ): 1184 .

Wang H Y , Zhu C H , Liu Q Y , et al . Selective conversion of cellulose to hydroxyacetone and 1-hydroxy-2-butanone with Sn-Ni bimetallic catalysts [J ] . ChemSusChem , 2019 , 12 ( 10 ): 2154 - 2160 .

Cai T , Sun H B , Qiao J , et al . Cell-free chemoenzymatic starch synthesis from carbon dioxide [J ] . Science , 2021 , 373 ( 6562 ): 1523 - 1527 .

Zhan T , Liu W B , Teng J J , et al . Selective oxidation of glycerol to tartronic acid over Pt/N-doped mesoporous carbon with extra framework magnesium catalysts under base-free conditions [J ] . Chemical Communications , 2019 , 55 ( 18 ): 2620 - 2623 .

Zhang H , Zhang R Z , Zhang W D , et al . Base-free selective oxidation of 5-hydroxymethylfurfural over Pt nanoparticles on surface Nb-enriched Co-Nb oxide [J ] . Applied Catalysis B: Environmental , 2023 , 330 : 122670 .

Dou J , Zhang B W , Liu H , et al . Carbon supported Pt 9 Sn 1 nanoparticles as an efficient nanocatalyst for glycerol oxidation [J ] . Applied Catalysis B: Environmental , 2016 , 180 : 78 - 85 .

Kaminski P , Ziolek M , van Bokhoven J A . Mesoporous cerium-zirconium oxides modified with gold and copper-synthesis, characterization and performance in selective oxidation of glycerol [J ] . RSC Advances , 2017 , 7 ( 13 ): 7801 - 7819 .

Davis S E , Ide M S , Davis R J . Selective oxidation of alcohols and aldehydes over supported metal nanoparticles [J ] . Green Chemistry , 2013 , 15 ( 1 ): 17 - 45 .

Han Z Y , Xie R F , Song Y H , et al . Efficient and stable platinum nanocatalysts supported over Ca-doped ZnAl 2 O 4 spinels for base-free selective oxidation of glycerol to glyceric acid [J ] . Molecular Catalysis , 2019 , 477 : 110559 .

Xu S G , Xiao Y , Zhang W Y , et al . Relay catalysis of copper-magnesium catalyst on efficient valorization of glycerol to glycolic acid [J ] . Chemical Engineering Journal , 2022 , 428 : 132555 .

Xiao Y H , Wang M R , Liu D , et al . Selective photoelectrochemical oxidation of glycerol to glyceric acid on (002) facets exposed WO 3 nanosheets [J ] . Angewandte Chemie International Edition , 2024 , 63 ( 11 ): e202319685 .

Pakrieva E , Kolobova E , German D , et al . Glycerol oxidation over supported gold catalysts: the combined effect of Au particle size and basicity of support [J ] . Processes , 2020 , 8 ( 9 ): 1016 .

Martínez Q H , Neira J A , Amaya Á A , et al . Selective oxidation of glycerol mediated by surface plasmon of gold nanoparticles deposited on titanium dioxide nanowires [J ] . Chemosphere , 2024 , 364 : 142995 .

Villa A , Dimitratos N , Chan-Thaw C E , et al . Glycerol oxidation using gold-containing catalysts [J ] . Accounts of Chemical Research , 2015 , 48 ( 5 ): 1403 - 1412 .

Villa A , Campisi S , Mohammed K M H , et al . Tailoring the selectivity of glycerol oxidation by tuning the acid-base properties of Au catalysts [J ] . Catalysis Science & Technology , 2015 , 5 ( 2 ): 1126 - 1132 .

Zhang X Y , Yang P F , Liu Y N , et al . Support morphology effect on the selective oxidation of glycerol over AuPt/CeO 2 catalysts [J ] . Journal of Catalysis , 2020 , 385 : 146 - 159 .

Xu C L , Du Y Q , Li C , et al . Insight into effect of acid/base nature of supports on selectivity of glycerol oxidation over supported Au-Pt bimetallic catalysts [J ] . Applied Catalysis B: Environmental , 2015 , 164 : 334 - 343 .

Shen L Q , Chen X Y , Chen X J , et al . The support influence of Au-based catalysts in glycerin selective oxidation to glyceric acid [J ] . Journal of Chemical Technology & Biotechnology , 2023 , 98 ( 1 ): 179 - 187 .

Evans C D , Bartley J K , Taylor S H , et al . Perovskite supported catalysts for the selective oxidation of glycerol to tartronic acid [J ] . Catalysis Letters , 2023 , 153 ( 7 ): 2026 - 2035 .

Jiang K H , Li Z Y , Zhang Z H , et al . Stable and active Au catalyst supported on CeMnO 3 perovskite for selective oxidation of glycerol [J ] . Inorganic Chemistry , 2023 , 62 ( 21 ): 8145 - 8157 .

Purushothaman R K P , van Haveren J , Mayoral A , et al . Exploratory catalyst screening studies on the base free conversion of glycerol to lactic acid and glyceric acid in water using bimetallic Au-Pt nanoparticles on acidic zeolites [J ] . Topics in Catalysis , 2014 , 57 ( 17 ): 1445 - 1453 .

Cherni D , Moussa N , Nsib M F , et al . Base-free glycerol oxidation over N-TiO 2 supported Au-Pt catalysts [J ] . Reaction Kinetics, Mechanisms and Catalysis , 2019 , 128 ( 2 ): 979 - 990 .

Ma H , Nie X , Cai J Y , et al . Au/Mg(OH) 2 : highly efficient for selective oxidation of 1, 2-propanediol to lactic acid with molecular oxygen [J ] . Science China Chemistry , 2010 , 53 ( 7 ): 1497 - 1501 .

Griffin M B , Rodriguez A A , Montemore M M , et al . The selective oxidation of ethylene glycol and 1, 2-propanediol on Au, Pd, and Au-Pd bimetallic catalysts [J ] . Journal of Catalysis , 2013 , 307 : 111 - 120 .

Kaskow I , Decyk P , Sobczak I . The effect of copper and silver on the properties of Au-ZnO catalyst and its activity in glycerol oxidation [J ] . Applied Surface Science , 2018 , 444 : 197 - 207 .

Tian J , Liu H , Li P , et al . Selective oxidation of 1,2-propanediol to lactic acid over Cu-modified Au/hydrotalcite catalysts [J ] . New Journal of Chemistry , 2020 , 44 ( 38 ): 16311 - 16319 .

Olmos C M , Chinchilla L E , Rodrigues E G , et al . Synergistic effect of bimetallic Au-Pd supported on ceria-zirconia mixed oxide catalysts for selective oxidation of glycerol [J ] . Applied Catalysis B: Environmental , 2016 , 197 : 222 - 235 .

Chinchilla L E , Olmos C M , Villa A , et al . Ru-modified Au catalysts supported on ceria-zirconia for the selective oxidation of glycerol [J ] . Catalysis Today , 2015 , 253 : 178 - 189 .

Zhao Z , Arentz J , Pretzer L A , et al . Volcano-shape glycerol oxidation activity of palladium-decorated gold nanoparticles [J ] . Chemical Science , 2014 , 5 ( 10 ): 3715 - 3728 .

Xue W P , Yin H B , Lu Z P , et al . Catalytic oxidation of 1, 2-propanediol over bimetallic Cu@Au core/shell nanoparticles [J ] . Catalysis Letters , 2016 , 146 ( 6 ): 1139 - 1152 .

Ketchie W C , Murayama M , Davis R J . Selective oxidation of glycerol over carbon-supported AuPd catalysts [J ] . Journal of Catalysis , 2007 , 250 ( 2 ): 264 - 273 .

Villa A , Veith G , Prati L . Selective oxidation of glycerol under acidic conditions using gold catalysts [J ] . Angewandte Chemie International Edition , 2010 , 49 ( 26 ): 4499 - 4502 .

Brett G L , He Q , Hammond C , et al . Selective oxidation of glycerol by highly active bimetallic catalysts at ambient temperature under base-free conditions [J ] . Angewandte Chemie International Edition , 2011 , 50 ( 43 ): 10136 - 10139 .

Hirasawa S , Watanabe H , Kizuka T , et al . Performance, structure and mechanism of Pd-Ag alloy catalyst for selective oxidation of glycerol to dihydroxyacetone [J ] . Journal of Catalysis , 2013 , 300 : 205 - 216 .

Liu S S , Sun K Q , Xu B Q . Specific selectivity of Au-catalyzed oxidation of glycerol and other C 3 -polyols in water without the presence of a base [J ] . ACS Catalysis , 2014 , 4 ( 7 ): 2226 - 2230 .

Cui L , Wang F , Zhang X L , et al . Plant-mediated biosynthesized Au/CuO catalysts for efficient glycerol oxidation to 1, 3-dihydroxyacetone: effect of biomass component on catalytic activity [J ] . New Journal of Chemistry , 2024 , 48 ( 45 ): 19206 - 19219 .

Yuan Z F , Gao Z K , Xu B Q . Acid-base property of the supporting material controls the selectivity of Au catalyst for glycerol oxidation in base-free water [J ] . Chinese Journal of Catalysis , 2015 , 36 ( 9 ): 1543 - 1551 .

Yuan Z , Wang Y M , Xie W D , et al . Manipulating the interfacial integration mode of a bio-templated porous ZSM-5 platform with an Au/CuZnO x catalyst for enhanced efficiency and recycling stability in glycerol conversion to 1, 3-dihydroxyacetone [J ] . Nanoscale , 2025 , 17 ( 9 ): 5259 - 5269 .

An Z , Ma H H , Han H B , et al . Insights into the multiple synergies of supports in the selective oxidation of glycerol to dihydroxyacetone: layered double hydroxide supported Au [J ] . ACS Catalysis , 2020 , 10 ( 21 ): 12437 - 12453 .

Xiong Z L , Zhang X L , Huang J L , et al . Flower-shaped zinc oxide nanostructures loaded with Au nanoparticles for efficient and highly stable production of dihydroxyacetone from glycerol oxidation [J ] . Advanced Sustainable Systems , 2025 , 9 ( 4 ): 2400947 .

Zhang X L , Liu H , Ke Y H , et al . Biomimetic flower-petal-architected Zn-based nanocatalysts for selective oxidation of glycerol to 1, 3-dihydroxyacetone [J ] . ACS Applied Nano Materials , 2025 , 8 ( 28 ): 14052 - 14064 .

Yan H , Zhao M Y , Cao Y Q , et al . Crystal-facet-dependent, electron sink effect for the enhanced selective oxidation of polyols at the secondary hydroxyl position [J ] . Journal of Catalysis , 2024 , 431 : 115401 .

Yin Y R , Tang T , Xu C L . Au/CuMgAl-hydrotalcite catalysts promoted by Cu + and basic sites for selective oxidation of glycerol to dihydroxyacetone [J ] . Gold Bulletin , 2017 , 50 ( 4 ): 319 - 326 .

Tan H , Yao C J , Zhan T , et al . Selective oxidation of glycerol to dihydroxyacetone over N-doped porous carbon stabilized Cu x O supported Au catalysts [J ] . Molecular Catalysis , 2020 , 498 : 111243 .

Wang Y X , Pu Y F , Yuan D P , et al . Selective oxidation of glycerol to dihydroxyacetone over Au/Cu x Zr 1- x O y catalysts in base-free conditions [J ] . ACS Applied Materials & Interfaces , 2019 , 11 ( 47 ): 44058 - 44068

Ke Y H , Qin H Y , Wang X , et al . Facile conversion of glycerol to 1, 3-dihydroxyacetone by using mesoporous CuO-SnO 2 composite oxide supported Au catalysts [J ] . Journal of Porous Materials , 2023 , 30 ( 3 ): 723 - 737 .

Ke Y H , Wang X , Qin H Y , et al . Cu-Al composite oxides: a highly efficient support for the selective oxidation of glycerol to 1, 3-dihydroxyacetone [J ] . New Journal of Chemistry , 2020 , 44 ( 42 ): 18173 - 18184 .

Villa A , Campisi S , Chan-Thaw C E , et al . Bismuth modified Au-Pt bimetallic catalysts for dihydroxyacetone production [J ] . Catalysis Today , 2015 , 249 : 103 - 108 .

Feng Y M , Bi Y P , Wang Y F , et al . Enhanced glycerol oxidation toward dihydroxyacetone over gold/palladium binary nanocatalysts by structure control [J ] . Chemistry-A European Journal , 2025 , 31 ( 23 ): e202500601

Zhao G Q , Wu G D , Liu Y N , et al . Preparation of AuPd/ZnO-CuO for the directional oxidation of glycerol to DHA [J ] . Catalysis Science & Technology , 2020 , 10 ( 18 ): 6223 - 6234 .

Ryabenkova Y , Miedziak P J , Dummer N F , et al . The selective oxidation of 1, 2-propanediol by supported gold-based nanoparticulate catalysts [J ] . Topics in Catalysis , 2012 , 55 ( 19 ): 1283 - 1288 .

Ryabenkova Y , Miedziak P J , Knight D W , et al . Heterogeneously catalyzed oxidation of butanediols in base free aqueous media [J ] . Tetrahedron , 2014 , 70 ( 36 ): 6055 - 6058 .

Sarangapany S , Mohanty K . Facile green synthesis of magnetically separable Au-Pt@TiO 2 nanocomposite for efficient catalytic reduction of organic pollutants and selective oxidation of glycerol [J ] . Journal of Alloys and Compounds , 2020 , 830 : 154636 .

Zaid S , Skrzyńska E , Addad A , et al . Development of silver based catalysts promoted by noble metal M (M=Au, Pd or Pt) for glycerol oxidation in liquid phase [J ] . Topics in Catalysis , 2017 , 60 ( 15 ): 1072 - 1081 .

Yan H , Liu B W , Zhou X , et al . Enhancing polyol/sugar cascade oxidation to formic acid with defect rich MnO 2 catalysts [J ] . Nature Communications , 2023 , 14 : 4509 .

Takagaki A , Tsuji A , Nishimura S , et al . Genesis of catalytically active gold nanoparticles supported on hydrotalcite for base-free selective oxidation of glycerol in water with molecular oxygen [J ] . Chemistry Letters , 2011 , 40 ( 2 ): 150 - 152 .

Bianchi C L , Canton P , Dimitratos N , et al . Selective oxidation of glycerol with oxygen using mono and bimetallic catalysts based on Au, Pd and Pt metals [J ] . Catalysis Today , 2005 , 102 : 203 - 212 .

Dimitratos N , Messi C , Porta F , et al . Investigation on the behaviour of Pt(0)/carbon and Pt(0),Au(0)/carbon catalysts employed in the oxidation of glycerol with molecular oxygen in water [J ] . Journal of Molecular Catalysis A: Chemical , 2006 , 256 ( 1/2 ): 21 - 28 .

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