Degradation of humic acid in water by single- and dual-frequency ultrasound methods

doi:10.3969/j.issn.0438-1157.2014.09.054

CIESC Journal ›› 2014, Vol. 65 ›› Issue (9): 3700-3704.DOI: 10.3969/j.issn.0438-1157.2014.09.054

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Degradation of humic acid in water by single- and dual-frequency ultrasound methods

ZHAO Li, YANG Yanling, LI Xing, ZHOU Zhiwei, ZHANG Yang, MA Changhong

Key Laboratory of Beijing for Water Quality Science and Water Environment Recovery Engineering, Beijing University of Technology, Beijing 100124, China

Received:2014-01-13 Revised:2014-03-17 Online:2014-09-05 Published:2014-09-05
Supported by:
supported by the National Natural Science Foundation of China (51278005), the Beijing Natural Science Foundation (8132007) and the Post-Graduate Sci-Tech Innovation Foundation (ykj-2012-8771).

单频和双频复合超声对水溶液中腐殖酸的降解

赵荔, 杨艳玲, 李星, 周志伟, 张洋, 马长红

北京工业大学北京市水质科学与水环境恢复工程重点实验室, 北京 100124

通讯作者: 杨艳玲
基金资助:
国家水体污染控制与治理科技重大专项（2012ZX07404-003）；国家自然科学基金项目（51278005）；北京市自然科学基金项目（8132007）；研究生科技基金（ykj-2012-8771）。

Abstract

Abstract: To understand the degradation of humic acid in simulated water a series of static experiments assisted with ultrasound were done at various energy density of ultrasound produced by both single-frequency (68 kHz, 80 kHz, 100 kHz, 125 kHz and 160 kHz) and dual-frequency (X-Y axial orthogonal 80/125 kHz and 80/160 kHz and X-X axis parallel 68/100 kHz and 125/160 kHz) ultrasound irradiation system. The degradation of dissolved organic carbon (DOC) and trihalomathame precursors (THMFP) were measured. The main results obtained are as follows: for the same energy density of sound, the degradation efficiency is better for low frequency (68 kHz and 80 kHz) than for high frequency ultrasound (100 kHz, 125 kHz, and 160 kHz), dual-frequency is superior to single-frequency, and X-Y axial orthogonal ultrasound excels X-X axis parallel. The best result for degradation of COD and THMFP is obtained in 25 min by using X-Y axial orthogonal combination of 80/160 kHz ultrasound, and is 32.6% and 66.6% respectively.

Key words: humic acid, degradation, single-frequency ultrasound, dual-frequency ultrasound, THMFP, aqueous solution

摘要： 针对模拟水样中的腐殖酸，采用静态实验研究了在低声能密度0.028 W·ml^-1条件下，单频超声（68、80、100、125和160 kHz）和双频复合超声（X-Y轴轴向正交超声：80/125 kHz和80/160 kHz；X-X轴轴向平行超声：68/100 kHz和125/160 kHz）在不同时间下对溶解性有机碳（DOC）和三卤甲烷前体物（THMFP）的去除效果。结果表明：在同一声能密度下，低频（68和80 kHz）对DOC和THMFP的去除效果比高频（100、125和160 kHz）下的去除效果好，双频复合超声的去除效果均优于单频超声，且X-Y轴轴向正交超声降解效能均优于X-X轴轴向平行超声。双频复合超声的X-Y轴轴向正交组合80/160 kHz超声25 min去除效果最好，其中DOC和THMFP去除率分别可达到32.6%和66.6%。

关键词: 腐殖酸, 降解, 单频超声, 双频复合超声, 三卤甲烷前体物, 水溶液

CLC Number:

ZHAO Li, YANG Yanling, LI Xing, ZHOU Zhiwei, ZHANG Yang, MA Changhong. Degradation of humic acid in water by single- and dual-frequency ultrasound methods[J]. CIESC Journal, 2014, 65(9): 3700-3704.

赵荔, 杨艳玲, 李星, 周志伟, 张洋, 马长红. 单频和双频复合超声对水溶液中腐殖酸的降解[J]. 化工学报, 2014, 65(9): 3700-3704.

References 21

[1]	Wu Jiann M, Huang H S, Livengood C D. Ultrasonic destruction of chlorinated compounds in aqueous solution [J]. Environmental Progress, 1992, 11 (3): 195-200
[2]	Du Guimin (杜桂敏), Zhao Ying (赵瀛), Yuan Peisheng (原培胜). Ultrasound and its application on water sewage [J]. Chemical Defense on Ships (船舰防化), 2008 (6): 26-30
[3]	Tang Yulin (唐玉霖), Gao Naiyun (高乃云), Pang Weihai (庞维海). Progress on research of ultrasonic technology for drinking water [J]. Water & Wastewater Engineering (给水排水), 2007, 33 (12): 113 -116
[4]	Zhu Hongtao (朱洪涛). The application of ultrasonic technique in wastewater treatment [J]. Industrial Safety and Environmental Protection (工业安全与环保), 2007, 33 (12): 13-16.
[5]	Matouq Mohammed A, Al-Anber Zaid A, Tagawa Tomohiko, Aljbour Salah, Al-Shannag Mohammad. Degradation of dissolved diazinon pesticide in water using the high frequency of ultrasound wave [J]. Ultrasonic Sonochemistry, 2008 (15): 869-870
[6]	Xu Xianwen, Shi Huixiang，Wang Dahui. Ozonation with ultrasonic enhancement of p-nitrophenol wastewater [J]. Journal of Zhejiang University Science, 2005, 6B (5): 319-323
[7]	Zhang Guangming (张光明), Wu Minsheng (吴敏生), Zhang Xihui (张锡辉). Study of 2-chlorobiphenyl and 4-chhlorobiphenyl sonication [J]. Environmental Chemistry (环境化学), 2004, 23 (3): 298-300
[8]	Liu Yan (刘岩), Wang Xuemei (王雪梅). Study on ultraviolet spectrum in the process of humic acid solution of sonochemical degradation [J]. Spectroscopy and Spectral Analysis (光谱学与光谱分析), 2003, 23 (5): 930-932
[9]	Liu Yan (刘岩). Study on ultrasound chemical degradation of humic acid in the water [J]. Journal of Qinghai Environment (青海环境), 1996, 6 (1): 43
[10]	Ding Rui (丁锐). Study on humic acid degradation process by ultrasound [J]. Journal of Qinghai University (青海大学学报), 2006, 24 (2): 20-22
[11]	Tatake Prashant A, Pandit Aniruddha B. Modelling and experimental investigation into cavity dynamics and cavitational yield: influence of dual frequency ultrasound sources [J]. Chemical Engineering Science, 2002, 57 (22/23): 4987-4995
[12]	Sivakumar Manickam, Tatake Prashant A, Pandit Aniruddha B. Kinetics of p-nitrophenol degradation: effect of reaction conditions and cavitational parameters for a multiple frequency system [J]. Chemical Engineering Journal, 2002, 85 (2/3): 327-338
[13]	Feng Ruo (冯若), Zhu Changping (朱昌平), Zhao Yiyun (赵逸云), Wang Shuangwei (王双维), Chen Zhaohua (陈兆华). Study on dual-frequency orthogonal irradiation of sonochemical effect [J]. Chinese Science Bulletin (科学通报), 1997, 42 (9): 925-928
[14]	Ben Yongguang (贲永光), Qiu Taiqiu (丘泰球), Li Kang (李康), Li Kunping (李坤平), Kong Fansheng (孔繁晟). Experimental research on cavitation effects of single-frequency ultrasound and dual-frequency ultrasound [J]. Technical Acoustics (声学技术), 2009, 28 (3): 257-260
[15]	Feng Ruo (冯若). Ultrasonic Manual (超声手册) [M]. Nanjing: Nanjing University Press, 2006: 16-27, 78-88, 150-160, 658-662, 706-720
[16]	Yan Zhigang (阎志刚), Cao Zhonghong (曹仲宏). Ozonization in drinking water treatment and relevant oxidization technigues [J]. Technology Information Development & Economy (科技情报开发与经济), 2004, 14 (1): 157
[17]	Guo Wenjuan (郭文娟), Zhang Guangming (张光明), Ma Jun (马军). Study of US/O3 removal of trace level organics in filtered water [J]. Journal of Harbin University of Commerce (哈尔滨商业大学学报), 2010, 26 (2): 149-151,160
[18]	Wang Lin (王琳), Wang Baozhen (王宝贞). Drinking Water Depth Treatment Technology (饮用水深度处理技术) [M]. Beijing: Chemical Industry Press, 2002: 109-111
[19]	Zhu Changping (朱昌平), Li Liangxue (李良学), Ran Rong (冉勇), Wei Lisheng (魏立升), Chen Zhaohua (陈兆华), Feng Ruo (冯若). The frequency effect of bifrequency irradiation for high sonochemical yield [J]. Applied Acoustics (应用声学), 1998 (1): 15-17
[20]	Zhao Deming (赵德明), Shi Huixiang (史慧祥), Wang Dahui (汪大翚). Degradation of phenol wastewater by dual-frequency ultrasound technology [J]. Journal of Chenical Industry and Engineering (China) (化工学报), 2003, 54 (4): 570-574
[21]	Shen Zhuangzhi (沈壮志), Cheng Jianzheng (程建政), Wu Shengju (吴胜举). Ultrasonic-induced degradation of pentachlorophenol [J]. Acta Chimica Sinica (化学学报), 2003, 61 (12): 2016-2019

Degradation of humic acid in water by single- and dual-frequency ultrasound methods

单频和双频复合超声对水溶液中腐殖酸的降解

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