CIESC Journal ›› 2014, Vol. 65 ›› Issue (7): 2645-2656.DOI: 10.3969/j.issn.0438-1157.2014.07.024

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Advances in catalytic oxidations catalyzed by carbon nanomaterials in liquid-phase

CAO Yonghai, LI Bo, YU Hao, PENG Feng, WANG Hongjuan   

  1. School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, Guangdong, China
  • Received:2014-03-18 Revised:2014-03-25 Online:2014-07-05 Published:2014-07-05
  • Supported by:

    supported by the National Natural Science Foundation of China (21133010, 21273079), the Guangdong Natural Science Funds for Distinguished Young Scholar (S20120011275), the Program for New Century Excellent Talents in University (NCET-12-0190) and the Fundamental Research Funds for the Central Universities of China (2014ZG0005).

纳米碳材料催化液相选择性氧化的研究进展

曹永海, 李博, 余皓, 彭峰, 王红娟   

  1. 华南理工大学化学与化工学院, 广东 广州 510640
  • 通讯作者: 余皓
  • 基金资助:

    国家自然科学基金项目(21133010,21273079);广东省自然科学杰出青年基金项目(S20120011275);教育部新世纪优秀人才支持计划项目(NCET-12-0190);中央高校基本科研业务费项目(2014ZG0005)。

Abstract: Recently emerged liquid-phase oxidation processes catalyzed by carbon nanomaterials as metal-free, low-cost catalysts, either for manufacture of chemicals or for elimination of organic pollutants are reviewed. Oxidations of hydrocarbon, alcohol, ketone, amine, etc. are involved, categorized by the oxidant used, such as O2, H2O2, tert-butyl hydroperoxide, graphite oxide. The reaction processes and catalytic mechanisms are discussed to elucidate the role of carbon nanomaterials as a new class of catalyst.

Key words: carbon nanomaterials, oxidation, liquid-phase, catalysis

摘要: 纳米碳材料是广受关注的高性能材料,其作为无金属催化剂的应用近年来受到了广泛关注。综述了碳材料在不同氧化剂(O2、H2O2、叔丁基过氧化氢、氧化石墨等)的作用下选择性催化氧化烃类、醇类、酮类、胺类等制备有机化学品和氧化降解有机污染物反应过程,着重阐述这些液相氧化反应体系的机理以及碳材料在其中所起的作用。

关键词: 纳米碳材料, 氧化, 液相, 催化

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