Ru/γ-Fe2O3-Al2O3 catalyst for selective hydrogenation of benzene in magnetically stabilized bed

doi:10.3969/j.issn.0438-1157.2013.05.018

CIESC Journal ›› 2013, Vol. 64 ›› Issue (5): 1629-1634.DOI: 10.3969/j.issn.0438-1157.2013.05.018

Previous Articles Next Articles

Ru/γ-Fe₂O₃-Al₂O₃ catalyst for selective hydrogenation of benzene in magnetically stabilized bed

FU Qingtao^1,2, LIU Chenguang², YU Lianqing³

1. Key Laboratory of Resources and Environmental Analytical Chemistry in Universities of Shandong, Linyi University, Linyi 276000, Shandong, China;
2. School of Chemical Engineering, China University of Petroleum(East China), Qingdao 266580, Shandong, China;
3. School of Science, China University of Petroleum(East China), Qingdao 266580, Shandong, China

Received:2012-07-20 Revised:2013-02-05 Online:2013-05-05 Published:2013-05-05
Supported by:
supported by the National Natural Science Foundation of China(20806093).

Ru/γ-Fe₂O₃-Al₂O₃催化剂在磁稳定床中苯选择性加氢性能

付庆涛^1,2, 刘晨光², 于濂清³

1. 临沂大学山东省高校资源与环境分析化学重点实验室, 山东临沂 276000;
2. 中国石油大学化学工程学院, 山东青岛 266580;
3. 中国石油大学理学院, 山东青岛 266580

通讯作者: 付庆涛
作者简介:付庆涛(1983-),男,博士,讲师。
基金资助:
国家自然科学基金项目(20806093)。

Abstract

Abstract: Ru-based magnetic(Ru/γ-Fe₂O₃-SiO₂-γ-Al₂O₃)egg-shell catalysts were prepared by the impregnation method.A magnetically stabilized bed(MSB)unit was designed and used to characterize selective hydrogenation of benzene.The effects of catalyst preparation parameters and reaction conditions on selective hydrogenation of benzene were investigated.The results showed that the state of chain operation in MSB increased the selectivity for cyclohexene obviously, which verified that the magnetic ruthenium-based catalysts and magnetically stabilized bed had a good prospect of industrial applications.

Key words: benzene, selectivity, magnetically stabilized bed, Ru/γ-Fe₂O₃-γ-Al₂O₃

摘要： 设计建造了磁稳定床加氢实验装置,以磁性氧化铝为载体,通过浸渍法制备了蛋壳型钌基磁性Ru/γ-Fe₂O₃-γ-Al₂O₃微球催化剂,详细考察了磁性催化剂的制备参数、磁稳定床的操作参数对苯选择性加氢的影响。结果表明磁稳定床的链式操作状态提高了环己烯的选择性,证实了所研制的蛋壳型钌基磁性微球催化剂适用于磁稳定床中苯的选择性加氢工艺,具有较好的应用前景。

关键词: 苯, 选择性, 磁稳定床, Ru/γ-Fe₂O₃-γ-Al₂O₃

CLC Number:

O643.32

FU Qingtao, LIU Chenguang, YU Lianqing. Ru/γ-Fe₂O₃-Al₂O₃ catalyst for selective hydrogenation of benzene in magnetically stabilized bed[J]. CIESC Journal, 2013, 64(5): 1629-1634.

付庆涛, 刘晨光, 于濂清. Ru/γ-Fe₂O₃-Al₂O₃催化剂在磁稳定床中苯选择性加氢性能[J]. 化工学报, 2013, 64(5): 1629-1634.

References 14

[1]	Sun H J, Pan Y J, Wang H X, et al.Selective hydrogenation of benzene to cyclohexene over a Ru-Zn catalyst with diethanolamine as an additive[J].Chinese Journal of Catalysis, 2012, 33(4/5/6):610-620
[2]	Wang W T, Liu H Z, Wu T B, et al.Ru catalyst supported on bentonite for partial hydrogenation of benzene to cyclohexene[J].Journal of Molecular Catalysis A:Chemical, 2012, 355:174-179
[3]	Zanutelo C, Landers R, Alves Carvalho W, et al.Carbon support treatment effect on Ru/C catalyst performance for benzene partial hydrogenation[J].Applied Catalysis A:General, 2011, 409/410:174-180
[4]	Liu H Z, Liang S G, Wang W T, et al.The partial hydrogenation of benzene to cyclohexene over Ru-Cu catalyst supported on ZnO[J].Journal of Molecular Catalysis A:Chemical, 2011, 341(1/2):35-41
[5]	Sun H J, Guo W, Zhou X L, et al.Progress in Ru-based amorphous alloy catalysts for selective hydrogenation of benzene to cyclohexene[J].Chinese Journal of Catalysis, 2011, 32(1):1-16
[6]	Sun H J, Zhang X D, Chen Z H, et al.Monolayer dispersed Ru-Zn catalyst and its performance in the selective hydrogenation of benzene to cyclohexene[J].Chinese Journal of Catalysis, 2011,32(1):224-230
[7]	Zhou X L, Sun H J, Guo W, et al.Selective hydrogenation of benzene to cyclohexene on Ru-based catalysts promoted with Mn and Zn[J].Journal of Natural Gas Chemistry, 2011, 20(1):53-59
[8]	Liu Z Y, Sun H J, Wang D B, et al.Selective hydrogenation of benzene to cyclohexene over Ru-Zn catalyst with nanosized zirconia as dispersant[J].Chinese Journal of Catalysis, 2010,31(2):150-152
[9]	Liu J L, Zhu Y, Liu J, et al.Discrimination of the roles of CdSO4 and ZnSO4 in liquid phase hydrogenation of benzene to cyclohexene original research article[J].Journal of Catalysis, 2009, 268(1):100-105
[10]	Xue W, Song Y, Wang Y J, et al.Effect of hydrazine hydrate on the Ru-Zn/SiO2 catalysts performance for partial hydrogenation of benzene[J].Catalysis Communications, 2009, 11(1):29-33
[11]	Zhao Y J, Zhou J, Zhang J G, et al.Liquid-phase selective hydrogenation of benzene to cyclohexene on Ru/Al2O3-ZrO2/cordierite monolithic catalysts[J].Journal of Molecular Catalysis A:Chemical, 2009, 309(1/2):35-39
[12]	Long S, Zhang A Q, Liu H F.Fabrication of a Pt nano-cluster/photosensitive polyimide hybrid membrane reactor and its partial hydrogenation of benzene[J].Chinese Journal of Catalysis, 2009, 30( 4):276-278
[13]	Liu J L, Zhu L J, Pei Y, et al.Ce-promoted Ru/SBA-15 catalysts prepared by a "two solvents" impregnation method for selective hydrogenation of benzene to cyclohexene[J].Applied Catalysis A:General, 2009, 353(2):282-287
[14]	Lu S L, William W L, Jeffery P B, et al.Low temperature hydrogenation of benzene and cyclohexene:a comparative study between γ-Al2O3 supported PtCo and PtNi bimetallic catalysts[J].Journal of Catalysis, 2008, 259(2):260-268

[1]	Yang WANG, Yongqiang DAI, Wei ZENG. Study of the enhanced thermoelectric properties of ionic hydrogel materials by 2,5-dihydroxybenzenesulfonate [J]. CIESC Journal, 2023, 74(9): 3946-3955.
[2]	Hao GU, Fujian ZHANG, Zhen LIU, Wenxuan ZHOU, Peng ZHANG, Zhongqiang ZHANG. Desalination performance and mechanism of porous graphene membrane in temporal dimension under mechanical-electrical coupling [J]. CIESC Journal, 2023, 74(5): 2067-2074.
[3]	Zheng ZHANG, Yongping HE, Haidong SUN, Rongzi ZHANG, Zhengping SUN, Jinlan CHEN, Yixuan ZHENG, Xiao DU, Xiaogang HAO. Electrochemically switched ion exchange device with serpentine flow field for selective extraction of lithium [J]. CIESC Journal, 2023, 74(5): 2022-2033.
[4]	Mujin LI, Song HU, Depan SHI, Peng ZHAO, Rui GAO, Jinlong LI. A process for offgas absorption and purification of 1,2-butylene oxide [J]. CIESC Journal, 2023, 74(4): 1607-1618.
[5]	Zijian WANG, Ming KE, Jiahan LI, Shuting LI, Jinru SUN, Yanbing TONG, Zhiping ZHAO, Jiaying LIU, Lu REN. Progress in preparation and application of short b-axis ZSM-5 molecular sieve [J]. CIESC Journal, 2023, 74(4): 1457-1473.
[6]	Muzi LI, Guowei JIA, Yanlong ZHAO, Xin ZHANG, Jianrong LI. The progress of metal-organic frameworks for non-CO₂ greenhouse gases capture [J]. CIESC Journal, 2023, 74(1): 365-379.
[7]	Junying YAN, Huangying WANG, Ruirui LI, Rong FU, Chenxiao JIANG, Yaoming WANG, Tongwen XU. Selective electrodialysis: opportunities and challenges [J]. CIESC Journal, 2023, 74(1): 224-236.
[8]	Houchuan YU, Teng REN, Ning ZHANG, Xiaobin JIANG, Yan DAI, Xiaopeng ZHANG, Junjiang BAO, Gaohong HE. Advances in two-dimensional graphene oxide membrane for ion selective transport [J]. CIESC Journal, 2023, 74(1): 303-312.
[9]	Jiaming WANG, Xuehua RUAN, Gaohong HE. Research progress of membrane separation materials for different industrial CO₂-containing mixtures [J]. CIESC Journal, 2022, 73(8): 3417-3432.
[10]	Hongxin YANG, Xingya LI, Liang GE, Tongwen XU. Preparation of mono-/divalent anion permselective membranes with piperidinium-type long side-chain [J]. CIESC Journal, 2022, 73(8): 3739-3748.
[11]	Dan GUO, Yujie FANG, Yihan XU, Zhiyuan LI, Shouying HUANG, Shengping WANG, Xinbin MA. Research progress of the catalytic conversion of ethane and carbon dioxide [J]. CIESC Journal, 2022, 73(8): 3406-3416.
[12]	Chenyu SU, Ying YANG, Xingfu SONG. Selective electro-oxidation of bromide ion in potassium-extracted brine from rock salt mines [J]. CIESC Journal, 2022, 73(7): 3007-3017.
[13]	Jiangwei ZHU, Pengfei MA, Xiao DU, Yanyan YANG, Xiaogang HAO, Shanxia LUO. Specific electronically controlled separation of phosphate anions based on variable valence NiFe-LDH/rGO [J]. CIESC Journal, 2022, 73(7): 3057-3067.
[14]	Yanran ZHU, Liang GE, Xingya LI, Tongwen XU. Construction and application of three-phase ionic exchange membranes [J]. CIESC Journal, 2022, 73(6): 2397-2414.
[15]	Shanshan YANG, Yuyang YAO, Yundi DONG, Zhipeng XU, Shangshang GAO, Huimin RUAN, Jiangnan SHEN. Preparation and performance of ion exchange membrane with K⁺ selectivity based on dibenzo-18-crown-6 modification [J]. CIESC Journal, 2022, 73(4): 1781-1793.

Ru/γ-Fe₂O₃-Al₂O₃ catalyst for selective hydrogenation of benzene in magnetically stabilized bed

Ru/γ-Fe₂O₃-Al₂O₃催化剂在磁稳定床中苯选择性加氢性能

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References 14

Related Articles 15

Recommended Articles

Metrics

Comments