多元表面活性剂复配的分子热力学模型研究

doi:10.11949/0438-1157.20200678

Abstract

Abstract:

Surfactants are widely used in the actual industrial production. Generally, it is a compound system of multiple surfactants to make use of the characteristics of different components, so that the compound system has better performance than a single surfactant. The compounding mechanism of multiple surfactants is still an interesting topic. In this paper, experimental and theoretical models are used to study the synergistic effect among the components of mixed surfactants. Firstly, based on Flory-Huggins theory, the molecular thermodynamic model of the multi-component surfactant system is derived. The interaction parameters of the two systems are correlated through the experimental data of the binary system. The critical micelle concentration (cmc) of the multi-component system and the phase composition of the mixed surfactant micelle can be predicted. The calculated results of the three-component surfactant system model are in good agreement with the experimental values.

Key words: surfactants, synergistic effect, molecular thermodynamics, critical micelle concentration(cmc), Flory-Huggins theory, phase equilibria, model

CLC Number:

TQ 013.1

Jin CHENG, Zhangyang CHEN, Yuming ZHANG, Qi DUAN, Cheng LIAN, Honglai LIU. Molecular thermodynamic model for compounding of multiple surfactants[J].CIESC Journal, 2020, 71(10): 4590-4600.

Figures/Tables 6

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Table 1

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x₃⁰	χ₂₃	平均值	误差(上)	误差(下)	x₂⁰	χ₂₄	平均值	误差(上)	误差(下)	x₃⁰	χ₃₄	平均值	误差(上)	误差(下)
0.2	-0.2382	-0.2245	0.0259	0.0141	0.2	-0.3767	-0.3695	0.0547	0.1116	0.2	-0.0036	-0.0466	0.043	0.1135
0.35	-0.2345				0.35	-0.4811				0.35	-0.0189
0.5	-0.2122				0.5	-0.3540				0.5	0.0092
0.65	-0.1986				0.65	-0.3207				0.65	-0.0591
0.8	-0.2386				0.8	-0.3148				0.8	-0.1601

Molecular thermodynamic model for compounding of multiple surfactants

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