化工学报 ›› 2018, Vol. 69 ›› Issue (6): 2353-2363.DOI: 10.11949/j.issn.0438-1157.20171596

• 综述与专论 • 上一篇    下一篇

臭氧氧化脱硝技术研究进展

纪瑞军1,2, 徐文青1, 王健1, 严超宇2, 朱廷钰1   

  1. 1. 中国科学院过程工程研究所湿法冶金清洁生产技术国家工程实验室, 北京 100190;
    2. 中国石油大学(北京)重质油国家重点实验室, 北京 102249
  • 收稿日期:2017-12-01 修回日期:2018-02-24 出版日期:2018-06-05 发布日期:2018-06-05
  • 通讯作者: 朱廷钰
  • 基金资助:

    国家重点研发计划项目(2017YFC0210601);北京市科技新星计划项目(Z181100006218057)。

Research progress of ozone oxidation denitrification technology

JI Ruijun1,2, XU Wenqing1, WANG Jian1, YAN Chaoyu2, ZHU Tingyu1   

  1. 1. National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
    2. State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, China
  • Received:2017-12-01 Revised:2018-02-24 Online:2018-06-05 Published:2018-06-05
  • Supported by:

    supported by the National Key R&D Program of China (2017YFC0210601) and the Beijing Nova Program (Z18100006218057).

摘要:

区别于还原法脱硝技术,臭氧氧化脱硝技术将NO氧化为易溶于水的NO2和N2O5等,结合后续吸收工艺进行脱硝。臭氧氧化脱硝技术已经广泛应用于催化裂化、工业锅炉烟气NOx排放控制。结合臭氧氧化技术的工艺特点及反应动力学,分析了复杂烟气组分中NO氧化的选择性,重点关注臭氧与NO摩尔比、反应温度和停留时间等关键工艺参数对氧化产物组成的影响。通过阐述湿法与半干法脱硫工艺中的硫硝协同吸收原理,分析吸收剂、吸收气体组成、添加剂等因素对吸收效率的影响。在此基础上,提出臭氧氧化脱硝技术研究中存在的不足以及此技术未来的发展前景。

关键词: 烟气, 氮氧化物, 氧化, 吸收, 脱硝

Abstract:

Ozone oxidation denitrification technology first oxidizes NO into water-soluble nitrogen oxides such as NO2 and N2O5, followed by absorption process for denitration, which is different from reduction denitration technologies. It has been widely used in NOx emission control of catalytic cracking and industrial boiler flue gases. The technological characteristics and reaction kinetics of ozone oxidation denitrification technology were discussed, the oxidation selectivities of NO in complex flue gases were analyzed, and the effects of ozone and NO molar ratio, reaction temperature and residence time on the composition of oxidation products were studied. After that, the influence of absorbents, absorption gas compositions and additives on absorption efficiencies was analyzed by elaborating the principle of synergistic absorption of sulfur dioxide and nitrogen oxides in both wet and semi dry desulfurization processes. Based on the above discussion, the deficiencies in the research of ozone oxidation denitration technology were put forward and the future development of this technology was proposed.

Key words: flue gas, NOx, oxidation, absorption, denitrification

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