化工学报 ›› 2017, Vol. 68 ›› Issue (8): 3250-3257.DOI: 10.11949/j.issn.0438-1157.20170035

• 能源和环境工程 • 上一篇    下一篇

高含水菌渣流化床燃烧NOx、SO2排放特性

葛亚昕1,2, 张光义1, 崔丽杰2, 高士秋1   

  1. 1 中国科学院过程工程研究所多相复杂系统国家重点实验室, 北京 100190;
    2 中国科学院大学化学与化工学院, 北京 100049
  • 收稿日期:2017-01-09 修回日期:2017-05-02 出版日期:2017-08-05 发布日期:2017-08-05
  • 通讯作者: 张光义
  • 基金资助:

    政府间国际科技合作项目(2016YFE0118000)。

Characteristics of NOx and SO2 emission from combustion of antibiotic mycelial residue with high water content in fluidized bed reactor

GE Yaxin1,2, ZHANG Guangyi1, CUI Lijie2, GAO Shiqiu1   

  1. 1 State Key Laboratory of Multi-phase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
    2 School of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
  • Received:2017-01-09 Revised:2017-05-02 Online:2017-08-05 Published:2017-08-05
  • Supported by:

    supported by the China-Japanese Research Cooperative Program-China (2016YFE0118000).

摘要:

采用流化床反应器,研究了高含水抗生素菌渣直接燃烧的NOx、SO2排放特性。结果表明,增加过量空气系数,NOx排放浓度升高,SO2排放浓度降低;升高燃烧温度,NOx及SO2排放浓度均升高;随着燃料含水率的增加,NOx及SO2排放浓度均呈现先降低后升高的趋势。空气分级燃烧能有效降低NOx排放,二次风率增加,NOx排放浓度显著降低;当二次风率为3/7时,NOx排放浓度较传统燃烧降低50%。添加CaCO3进行炉内脱硫,实验结果显示:随钙硫摩尔比(Ca/S)增加,SO2排放浓度下降,当Ca/S 3时,SO2排放浓度降低到25 mg·m-3以下,脱硫效率超过99%。

关键词: 抗生素菌渣, 流化床, 燃烧, 高含水, NOx排放, SO2排放, 空气分级, 脱硫

Abstract:

The characteristics of NOx and SO2 emission from combustion of antibiotic mycelial residue with high water content in a fluidized bed reactor were studied. The results showed that with the increase in excess air ratio, the NOx emission concentration increased while the SO2 emission concentration decreased. Enhancing the combustion temperature led to the increases in both the NOx and SO2 emission concentrations. With increasing fuel moisture content, both the NOx and SO2 emission concentrations first decreased and then increased. The air-staging combustion enabled good control of NOx emission. The NOx emission concentration was significantly lower with increasing the secondary air ratio. At the secondary air ratio 3/7, the air-staging combustion cut the NOx emission amount off by more than 50% compared to the traditional combustion. Desulfurization by adding CaCO3 into the furnace indicated that the SO2 emission concentration decreased with increasing molar ratio of calcium to sulfur (Ca/S), and when Ca/S 3, the SO2 emission concentration decreased to below 25 mg·m-3 and the sulfur removal efficiency surpassed 99%.

Key words: antibiotic mycelia residue, fluidized-bed, combustion, high water content, NOx emission, SO2 emission, air-staging, desulfurization

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