化工学报 ›› 2010, Vol. 61 ›› Issue (11): 2939-2943.

• 能源和环境工程 • 上一篇    下一篇

甲醇为碳源时C/N对反硝化过程中亚硝酸盐积累的影响

曹相生,付昆明,钱栋,朱兆亮,孟雪征   

  1. 北京工业大学建工学院,水质科学与水环境恢复工程北京市重点实验室;北京建筑工程学院环境与能源工程学院,城市雨水系统与水环境省部共建教育部重点实验室;山东建筑大学市政与环境工程学院
  • 出版日期:2010-11-05 发布日期:2010-11-05

Effect of C/N ratio on nitrite accumulation in dentrifying process with methanol as carbon source

CAO Xiangsheng, FU Kunming, QIAN Dong, ZHU Zhaoliang, MENG Xuezheng   

  • Online:2010-11-05 Published:2010-11-05

摘要:

如何获得稳定的NO-2-N作为厌氧氨氧化细菌的电子受体是城镇污水通过厌氧氨氧化途径脱氮的瓶颈问题。为此考虑利用反硝化途径获取稳定的NO-2-N。以甲醇为碳源,采用小试装置的SBR反应器,通过控制进水C/N(COD与NO-3-N质量浓度比)的策略,研究了反硝化过程中的NO-2-N积累的状况。试验结果表明以甲醇为碳源且投加量不足时(C/N<3.2),反硝化过程中和反硝化结束后会产生稳定的NO-2-N积累;在C/N不足的前提下,NO-2-N积累量随甲醇投加量的增加而增加;进水

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Abstract:

How to get stable and sufficient nitrite as an electronic acceptor of anammox bacteria is a bottleneck of nitrogen removal in treatment of municipal wastewater by anaerobic ammonium oxidation reaction processes. Therefore, denitrification processes was considered as an alternative to obtain stable nitrite. The nitrite accumulation during denitrification processes was studied in a bench-scale sequencing batch reactor with methanol as carbon source by controlling initial C/N (COD/NO-3-N) ratios in influent. The results showed that, the shortage of methanol feed(C/N ratios<3.2) during denitrification process would lead to stable nitrite accumulation that increases with raising of methanol feed(C/N ratios increasing).Nitrite accumulation rate (accumulated nitrite/initial nitrate×100%) is about 25% at C/N ratios 2.4—3.2, only 5.6% at C/N ratio 0.8. The reduction rate of NO-2-N and NO-3-N goes up with the concentration of COD when C/N ratios<1, and is not affected by COD concentration when C/N ratios≥1.

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